JP2004501127A5 - - Google Patents
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- Publication number
- JP2004501127A5 JP2004501127A5 JP2002504203A JP2002504203A JP2004501127A5 JP 2004501127 A5 JP2004501127 A5 JP 2004501127A5 JP 2002504203 A JP2002504203 A JP 2002504203A JP 2002504203 A JP2002504203 A JP 2002504203A JP 2004501127 A5 JP2004501127 A5 JP 2004501127A5
- Authority
- JP
- Japan
- Prior art keywords
- stage
- oxygen
- volume
- olefin
- product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims 19
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 10
- 239000001301 oxygen Substances 0.000 claims 10
- 229910052760 oxygen Inorganic materials 0.000 claims 10
- 150000001336 alkenes Chemical class 0.000 claims 8
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 8
- 239000007789 gas Substances 0.000 claims 6
- 150000001735 carboxylic acids Chemical class 0.000 claims 5
- 238000006243 chemical reaction Methods 0.000 claims 5
- 239000003054 catalyst Substances 0.000 claims 4
- 239000011261 inert gas Substances 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 4
- 239000000126 substance Substances 0.000 claims 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 3
- 150000001299 aldehydes Chemical class 0.000 claims 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 3
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 claims 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims 2
- 229910052791 calcium Inorganic materials 0.000 claims 2
- 229910001882 dioxygen Inorganic materials 0.000 claims 2
- 229910052733 gallium Inorganic materials 0.000 claims 2
- 229910052758 niobium Inorganic materials 0.000 claims 2
- 229910052700 potassium Inorganic materials 0.000 claims 2
- 229910052710 silicon Inorganic materials 0.000 claims 2
- 229910052721 tungsten Inorganic materials 0.000 claims 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical group CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims 1
- STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- 229910052787 antimony Inorganic materials 0.000 claims 1
- 229910052786 argon Inorganic materials 0.000 claims 1
- 239000001569 carbon dioxide Substances 0.000 claims 1
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- -1 ethylene, propylene, isobutylene Chemical group 0.000 claims 1
- 229910052732 germanium Inorganic materials 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 229910052748 manganese Inorganic materials 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 229910052763 palladium Inorganic materials 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- 239000001294 propane Substances 0.000 claims 1
- 230000003134 recirculating effect Effects 0.000 claims 1
- 229910052703 rhodium Inorganic materials 0.000 claims 1
- 229910052720 vanadium Inorganic materials 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/602,784 US6441227B1 (en) | 2000-06-23 | 2000-06-23 | Two stage process for the production of unsaturated carboxylic acids by oxidation of lower unsaturated hydrocarbons |
| PCT/EP2001/006534 WO2001098247A2 (en) | 2000-06-23 | 2001-06-08 | Two stage process for the production of unsaturated carboxylic acids by oxidation of lower unsaturated hycrocarbons |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004501127A JP2004501127A (ja) | 2004-01-15 |
| JP2004501127A5 true JP2004501127A5 (enExample) | 2005-07-28 |
| JP4680473B2 JP4680473B2 (ja) | 2011-05-11 |
Family
ID=24412792
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002504203A Expired - Fee Related JP4680473B2 (ja) | 2000-06-23 | 2001-06-08 | 低級不飽和炭化水素の酸化による不飽和カルボン酸の生成のための二段階プロセス |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US6441227B1 (enExample) |
| EP (1) | EP1292559B1 (enExample) |
| JP (1) | JP4680473B2 (enExample) |
| KR (1) | KR100539573B1 (enExample) |
| AT (1) | ATE356791T1 (enExample) |
| DE (1) | DE60127254T2 (enExample) |
| ES (1) | ES2282277T3 (enExample) |
| GC (1) | GC0000289A (enExample) |
| TW (1) | TWI228503B (enExample) |
| WO (1) | WO2001098247A2 (enExample) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6337424B1 (en) * | 2000-04-28 | 2002-01-08 | Saudi Basic Industries Corporation | Catalysts oxidation of lower olefins to unsaturated aldehydes, methods of making and using the same |
| US6841699B2 (en) * | 2001-04-25 | 2005-01-11 | Rohm And Haas Company | Recalcined catalyst |
| US7294734B2 (en) * | 2003-05-02 | 2007-11-13 | Velocys, Inc. | Process for converting a hydrocarbon to an oxygenate or a nitrile |
| US7220390B2 (en) | 2003-05-16 | 2007-05-22 | Velocys, Inc. | Microchannel with internal fin support for catalyst or sorption medium |
| US8193387B2 (en) * | 2003-12-19 | 2012-06-05 | Saudi Basic Industries Corporation | Process for producing an unsaturated carboxylic acid from an alkane |
| US20050137422A1 (en) * | 2003-12-19 | 2005-06-23 | Saudi Basic Industries Corporation | Process for producing an unsaturated carboxylic acid from an alkane |
| US7553986B2 (en) | 2003-12-23 | 2009-06-30 | Rohm And Haas Company | Process for the selective (amm)oxidation of lower molecular weight alkanes and alkenes |
| DE102004008573A1 (de) * | 2004-02-19 | 2005-09-08 | Stockhausen Gmbh | Ein Verfahren zur Entfernung kohlenstoffhaltiger Rückstände in einem Reaktor |
| US8137961B2 (en) * | 2004-09-08 | 2012-03-20 | J.R. Simplot Company | Plant-specific genetic elements and transfer cassettes for plant transformation |
| TWI438187B (zh) * | 2005-02-28 | 2014-05-21 | Evonik Degussa Gmbh | 丙烯酸和基於可再生原料之吸水聚合物結構及二者之製備方法 |
| DE102006039205A1 (de) * | 2006-08-22 | 2008-03-20 | Stockhausen Gmbh | Auf nachwachsenden Rohstoffen basierende Acrylsäure und wasserabsorbierende Polymergebilde sowie Verfahren zu deren Herstellung mittels Dehydratisierung |
| CN100439313C (zh) * | 2006-10-27 | 2008-12-03 | 清华大学 | 一种丙烯氧化制备丙烯酸的多级流化床反应器及制备方法 |
| DE102008038273A1 (de) | 2008-08-18 | 2010-03-04 | Evonik Stockhausen Gmbh | Ein Verfahren zur Herstellung von Acrylsäure und daraus herstellbaren Verbindungen basierend auf Glycerin mit Wechselkatalysator |
| KR101086731B1 (ko) * | 2008-10-17 | 2011-11-25 | 금호석유화학 주식회사 | 1-부텐의 산화/탈수소화 반응에서 1,3-부타디엔 제조용 비스무스 몰리브덴 철 복합 산화물 촉매 및 제조방법 |
| JP5280239B2 (ja) * | 2009-02-09 | 2013-09-04 | 三菱レイヨン株式会社 | パラジウム含有触媒、その製造方法、およびα，β−不飽和カルボン酸の製造方法 |
| FR2976293B1 (fr) | 2011-06-10 | 2015-01-02 | Arkema France | Procede de synthese de composes hydrocarbones bi-fonctionnels a partir de biomasse |
| KR102319012B1 (ko) * | 2018-11-13 | 2021-10-29 | 한화토탈 주식회사 | 포화탄화수소를 포함한 이소부텐을 이용한 메틸메타크릴레이트의 제조방법 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4380664A (en) * | 1973-06-11 | 1983-04-19 | Mitsubishi Rayon Company, Ltd. | Process for producing unsaturated aldehydes, and unsaturated fatty acids |
| US4111984A (en) * | 1973-06-11 | 1978-09-05 | Mitsubishi Rayon Co., Ltd. | Process for producing unsaturated aldehydes, and unsaturated fatty acids |
| US4217309A (en) * | 1978-06-12 | 1980-08-12 | Ube Industries, Ltd. | Process for producing methacrolein |
| JPS55102536A (en) | 1979-01-30 | 1980-08-05 | Mitsubishi Petrochem Co Ltd | Preparation of acrylic acid |
| US4321160A (en) * | 1979-12-27 | 1982-03-23 | Standard Oil Company | Method for the activation of phosphomolybdic acid based catalysts |
| JPS5913746A (ja) | 1982-07-16 | 1984-01-24 | Nippon Shokubai Kagaku Kogyo Co Ltd | アクリル酸の製造方法 |
| JPS59204164A (ja) * | 1983-05-06 | 1984-11-19 | Asahi Chem Ind Co Ltd | 不飽和ニトリルの製法 |
| CA1238053A (en) | 1983-12-07 | 1988-06-14 | Sun Refining And Marketing Company | INCREASED SELECTIVITIES IN THE OXIDATION OF OLEFINS TO .alpha.,.beta.-UNSATURATED CARBOXYLIC ACIDS |
| JPH0813777B2 (ja) * | 1986-12-11 | 1996-02-14 | 三菱化学株式会社 | アクリル酸の製造法 |
| US5218146A (en) * | 1987-05-27 | 1993-06-08 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Process for production of acrylic acid |
| AU606160B2 (en) | 1987-05-27 | 1991-01-31 | Nippon Shokubai Kagaku Kogyo Co. Ltd. | Process for production of acrylic acid |
| JPH07107016B2 (ja) | 1987-12-22 | 1995-11-15 | 株式会社日本触媒 | アクリル酸の製造方法 |
| JP2701065B2 (ja) * | 1989-03-23 | 1998-01-21 | 日東化学工業株式会社 | モリブデン―ビスマス含有複合酸化物触媒の製法 |
| KR100277241B1 (ko) | 1993-06-25 | 2001-02-01 | 고오사이 아끼오 | 불포화 알데하이드 및 불포화 카복실산의 제조방법 |
| DE19630832A1 (de) * | 1996-07-31 | 1998-02-05 | Hoechst Ag | Verfahren zur selektiven Herstellung von Essigsäure |
| JP3948798B2 (ja) | 1997-10-27 | 2007-07-25 | 株式会社日本触媒 | アクリル酸の製造方法 |
| US6114278A (en) * | 1998-11-16 | 2000-09-05 | Saudi Basic Industries Corporation | Catalysts for catalytic oxidation of propane to acrylic acid, methods of making and using the same |
| US6337424B1 (en) * | 2000-04-28 | 2002-01-08 | Saudi Basic Industries Corporation | Catalysts oxidation of lower olefins to unsaturated aldehydes, methods of making and using the same |
-
2000
- 2000-06-23 US US09/602,784 patent/US6441227B1/en not_active Expired - Lifetime
-
2001
- 2001-06-08 EP EP01957833A patent/EP1292559B1/en not_active Expired - Lifetime
- 2001-06-08 AT AT01957833T patent/ATE356791T1/de not_active IP Right Cessation
- 2001-06-08 DE DE60127254T patent/DE60127254T2/de not_active Expired - Lifetime
- 2001-06-08 KR KR10-2002-7017552A patent/KR100539573B1/ko not_active Expired - Fee Related
- 2001-06-08 JP JP2002504203A patent/JP4680473B2/ja not_active Expired - Fee Related
- 2001-06-08 ES ES01957833T patent/ES2282277T3/es not_active Expired - Lifetime
- 2001-06-08 WO PCT/EP2001/006534 patent/WO2001098247A2/en not_active Ceased
- 2001-06-16 GC GCP20011428 patent/GC0000289A/en active
- 2001-06-22 TW TW090115267A patent/TWI228503B/zh not_active IP Right Cessation
-
2002
- 2002-08-12 US US10/217,522 patent/US20020198406A1/en not_active Abandoned
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