JP2004346276A - 熱可塑性樹脂用改質剤およびその製造方法、熱可塑性樹脂組成物 - Google Patents
熱可塑性樹脂用改質剤およびその製造方法、熱可塑性樹脂組成物 Download PDFInfo
- Publication number
- JP2004346276A JP2004346276A JP2003147745A JP2003147745A JP2004346276A JP 2004346276 A JP2004346276 A JP 2004346276A JP 2003147745 A JP2003147745 A JP 2003147745A JP 2003147745 A JP2003147745 A JP 2003147745A JP 2004346276 A JP2004346276 A JP 2004346276A
- Authority
- JP
- Japan
- Prior art keywords
- polytetrafluoroethylene
- thermoplastic resin
- thermoplastic
- particles
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920005992 thermoplastic resin Polymers 0.000 title claims abstract description 89
- 239000003607 modifier Substances 0.000 title claims abstract description 47
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 23
- 239000011342 resin composition Substances 0.000 title claims abstract description 22
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 102
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 99
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 99
- 239000002245 particle Substances 0.000 claims abstract description 98
- 229920001577 copolymer Polymers 0.000 claims abstract description 54
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 51
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 50
- 238000004220 aggregation Methods 0.000 claims abstract description 14
- 230000002776 aggregation Effects 0.000 claims abstract description 14
- 239000002904 solvent Substances 0.000 claims abstract description 13
- 238000006116 polymerization reaction Methods 0.000 claims description 19
- 238000002156 mixing Methods 0.000 claims description 16
- 230000004931 aggregating effect Effects 0.000 claims description 3
- 230000000704 physical effect Effects 0.000 abstract description 5
- 238000010586 diagram Methods 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 description 31
- 239000000843 powder Substances 0.000 description 22
- 238000000034 method Methods 0.000 description 21
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 19
- 238000006243 chemical reaction Methods 0.000 description 14
- 239000000203 mixture Substances 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 11
- 229910052757 nitrogen Inorganic materials 0.000 description 11
- 239000000178 monomer Substances 0.000 description 10
- 238000011156 evaluation Methods 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 239000003999 initiator Substances 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- 239000002002 slurry Substances 0.000 description 8
- 239000012153 distilled water Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 5
- 230000000903 blocking effect Effects 0.000 description 5
- 125000002091 cationic group Chemical group 0.000 description 5
- 239000003995 emulsifying agent Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000008188 pellet Substances 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 4
- 235000011092 calcium acetate Nutrition 0.000 description 4
- 239000001639 calcium acetate Substances 0.000 description 4
- 229960005147 calcium acetate Drugs 0.000 description 4
- 238000010556 emulsion polymerization method Methods 0.000 description 4
- 239000004816 latex Substances 0.000 description 4
- 229920000126 latex Polymers 0.000 description 4
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 230000001771 impaired effect Effects 0.000 description 3
- 230000000379 polymerizing effect Effects 0.000 description 3
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 3
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- 239000012874 anionic emulsifier Substances 0.000 description 2
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- CBECDWUDYQOTSW-UHFFFAOYSA-N 2-ethylbut-3-enal Chemical compound CCC(C=C)C=O CBECDWUDYQOTSW-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920006358 Fluon Polymers 0.000 description 1
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000004815 dispersion polymer Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Landscapes
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003147745A JP2004346276A (ja) | 2003-05-26 | 2003-05-26 | 熱可塑性樹脂用改質剤およびその製造方法、熱可塑性樹脂組成物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003147745A JP2004346276A (ja) | 2003-05-26 | 2003-05-26 | 熱可塑性樹脂用改質剤およびその製造方法、熱可塑性樹脂組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2004346276A true JP2004346276A (ja) | 2004-12-09 |
| JP2004346276A5 JP2004346276A5 (enExample) | 2006-07-13 |
Family
ID=33534193
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003147745A Pending JP2004346276A (ja) | 2003-05-26 | 2003-05-26 | 熱可塑性樹脂用改質剤およびその製造方法、熱可塑性樹脂組成物 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2004346276A (enExample) |
-
2003
- 2003-05-26 JP JP2003147745A patent/JP2004346276A/ja active Pending
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR0180714B1 (ko) | Pvc용 코어/셸 첨가제를 함유하는 강화 혼합물 및 이의 제조방법 | |
| JP4685878B2 (ja) | 難燃性ポリカーボネート樹脂組成物 | |
| CN106715575A (zh) | 热塑性树脂组合物及其制备方法 | |
| JP2005112907A (ja) | グラフト共重合体、耐衝撃改質剤、および熱可塑性樹脂組成物 | |
| JP5742994B1 (ja) | 熱可塑性樹脂組成物及び樹脂成形品 | |
| KR20200055786A (ko) | 일액형 중합체 개질제 | |
| KR101404942B1 (ko) | 투명도와 내충격 강도가 우수한 그라프트 공중합체 | |
| JP2003327770A (ja) | 溶融成形用共重合体組成物 | |
| JPS59230042A (ja) | 熱可塑性樹脂組成物 | |
| KR20090016457A (ko) | 열가소성 수지 조성물 및 그 제조 방법 | |
| KR101827613B1 (ko) | 고무변성 비닐계 그라프트 공중합체 및 이를 포함하는 열가소성 수지 조성물 | |
| JP3933277B2 (ja) | 熱可塑性樹脂組成物 | |
| JP2004346276A (ja) | 熱可塑性樹脂用改質剤およびその製造方法、熱可塑性樹脂組成物 | |
| JPH0346496B2 (enExample) | ||
| KR101540542B1 (ko) | 메틸메타크릴레이트-부타디엔-스티렌계 충격보강제 및 이를 포함하는 폴리카보네이트 수지 조성물 | |
| WO2002064678A1 (en) | Impact modifier for thermoplastic resin and resin composition containing the same | |
| JPH0791347B2 (ja) | 耐衝撃性樹脂の製造方法 | |
| JP2000204220A (ja) | メタクリル系樹脂用改質剤 | |
| JP2021066878A (ja) | 加工助剤および樹脂組成物 | |
| JPH0737554B2 (ja) | 耐衝撃性樹脂組成物 | |
| JP3771179B2 (ja) | 熱可塑性樹脂組成物 | |
| JP2692019B2 (ja) | メッキ性、耐衝撃性及び大型成形性に優れた熱可塑性樹脂組成物 | |
| JPS61106649A (ja) | フツ化ビニリデン樹脂組成物 | |
| JP2007106953A (ja) | ドリップ防止用粉体及び難燃樹脂組成物 | |
| JP2005089619A (ja) | 耐衝撃改質剤、および、熱可塑性樹脂組成物 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20060526 |
|
| A621 | Written request for application examination |
Effective date: 20060526 Free format text: JAPANESE INTERMEDIATE CODE: A621 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20081112 |
|
| A131 | Notification of reasons for refusal |
Effective date: 20081125 Free format text: JAPANESE INTERMEDIATE CODE: A131 |
|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20090121 |
|
| A131 | Notification of reasons for refusal |
Effective date: 20090728 Free format text: JAPANESE INTERMEDIATE CODE: A131 |
|
| A02 | Decision of refusal |
Effective date: 20091124 Free format text: JAPANESE INTERMEDIATE CODE: A02 |