JP2003514667A5 - - Google Patents
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- Publication number
- JP2003514667A5 JP2003514667A5 JP2001540216A JP2001540216A JP2003514667A5 JP 2003514667 A5 JP2003514667 A5 JP 2003514667A5 JP 2001540216 A JP2001540216 A JP 2001540216A JP 2001540216 A JP2001540216 A JP 2001540216A JP 2003514667 A5 JP2003514667 A5 JP 2003514667A5
- Authority
- JP
- Japan
- Prior art keywords
- zeolite
- olefin
- phosphorus
- weight
- selective
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000010457 zeolite Substances 0.000 description 46
- 229910021536 Zeolite Inorganic materials 0.000 description 37
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 37
- 150000001336 alkenes Chemical class 0.000 description 24
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 24
- 229910052698 phosphorus Inorganic materials 0.000 description 15
- 239000011574 phosphorus Substances 0.000 description 15
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 14
- 239000003054 catalyst Substances 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 14
- 239000000203 mixture Substances 0.000 description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- 238000004523 catalytic cracking Methods 0.000 description 6
- 238000011066 ex-situ storage Methods 0.000 description 6
- -1 hydrogen ions Chemical class 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 150000003009 phosphonic acids Chemical class 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 239000005696 Diammonium phosphate Substances 0.000 description 1
- QLZHNIAADXEJJP-UHFFFAOYSA-N Phenylphosphonic acid Chemical compound OP(O)(=O)C1=CC=CC=C1 QLZHNIAADXEJJP-UHFFFAOYSA-N 0.000 description 1
- 101710162453 Replication factor A Proteins 0.000 description 1
- 102100035729 Replication protein A 70 kDa DNA-binding subunit Human genes 0.000 description 1
- GJYJYFHBOBUTBY-UHFFFAOYSA-N alpha-camphorene Chemical compound CC(C)=CCCC(=C)C1CCC(CCC=C(C)C)=CC1 GJYJYFHBOBUTBY-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical compound [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 1
- OOSPDKSZPPFOBR-UHFFFAOYSA-N butyl dihydrogen phosphite Chemical compound CCCCOP(O)O OOSPDKSZPPFOBR-UHFFFAOYSA-N 0.000 description 1
- DLIJPAHLBJIQHE-UHFFFAOYSA-N butylphosphane Chemical compound CCCCP DLIJPAHLBJIQHE-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- DQTRYXANLKJLPK-UHFFFAOYSA-N chlorophosphonous acid Chemical compound OP(O)Cl DQTRYXANLKJLPK-UHFFFAOYSA-N 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 235000019838 diammonium phosphate Nutrition 0.000 description 1
- LXCYSACZTOKNNS-UHFFFAOYSA-N diethoxy(oxo)phosphanium Chemical compound CCO[P+](=O)OCC LXCYSACZTOKNNS-UHFFFAOYSA-N 0.000 description 1
- ZUKLAAHCPUBQLQ-UHFFFAOYSA-N diethylphosphinous acid Chemical compound CCP(O)CC ZUKLAAHCPUBQLQ-UHFFFAOYSA-N 0.000 description 1
- NFORZJQPTUSMRL-UHFFFAOYSA-N dipropan-2-yl hydrogen phosphite Chemical compound CC(C)OP(O)OC(C)C NFORZJQPTUSMRL-UHFFFAOYSA-N 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical group 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 235000019837 monoammonium phosphate Nutrition 0.000 description 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical group [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 1
- 150000003003 phosphines Chemical class 0.000 description 1
- 125000005538 phosphinite group Chemical group 0.000 description 1
- RYIOLWQRQXDECZ-UHFFFAOYSA-N phosphinous acid Chemical compound PO RYIOLWQRQXDECZ-UHFFFAOYSA-N 0.000 description 1
- 150000008301 phosphite esters Chemical class 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical group OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- TUQOTMZNTHZOKS-UHFFFAOYSA-N tributylphosphine Chemical compound CCCCP(CCCC)CCCC TUQOTMZNTHZOKS-UHFFFAOYSA-N 0.000 description 1
- BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 1
- CYTQBVOFDCPGCX-UHFFFAOYSA-N trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16689699P | 1999-11-22 | 1999-11-22 | |
| US60/166,896 | 1999-11-22 | ||
| EP00200092.5 | 2000-01-12 | ||
| EP00200092A EP1116775A1 (en) | 2000-01-12 | 2000-01-12 | Catalyst composition with high efficiency for the production of light olefins |
| PCT/EP2000/011533 WO2001038460A1 (en) | 1999-11-22 | 2000-11-17 | Catalyst composition with high efficiency for the production of light olefins |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2003514667A JP2003514667A (ja) | 2003-04-22 |
| JP2003514667A5 true JP2003514667A5 (cg-RX-API-DMAC7.html) | 2006-02-23 |
| JP4494697B2 JP4494697B2 (ja) | 2010-06-30 |
Family
ID=8170902
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001540216A Expired - Lifetime JP4494697B2 (ja) | 1999-11-22 | 2000-11-17 | 軽質オレフィンの製造のための高効率を有する触媒組成物 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6566293B1 (cg-RX-API-DMAC7.html) |
| EP (2) | EP1116775A1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP4494697B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR100767958B1 (cg-RX-API-DMAC7.html) |
| CN (1) | CN1205307C (cg-RX-API-DMAC7.html) |
| AT (1) | ATE245687T1 (cg-RX-API-DMAC7.html) |
| BR (1) | BR0015726B1 (cg-RX-API-DMAC7.html) |
| CA (1) | CA2392232C (cg-RX-API-DMAC7.html) |
| DE (1) | DE60004102T2 (cg-RX-API-DMAC7.html) |
| ES (1) | ES2202210T3 (cg-RX-API-DMAC7.html) |
| WO (1) | WO2001038460A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (69)
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|---|---|---|---|---|
| ATE356102T1 (de) | 2001-07-02 | 2007-03-15 | Exxonmobil Chem Patents Inc | Inhibierung der katalysatorverkokung bei der herstellung eines olefins |
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| US6872680B2 (en) | 2002-03-20 | 2005-03-29 | Exxonmobil Chemical Patents Inc. | Molecular sieve catalyst composition, its making and use in conversion processes |
| US7271123B2 (en) | 2002-03-20 | 2007-09-18 | Exxonmobil Chemical Patents Inc. | Molecular sieve catalyst composition, its making and use in conversion process |
| CA2497309A1 (en) * | 2002-08-29 | 2004-03-11 | Albemarle Netherlands B.V. | Catalyst for the production of light olefins |
| FR2852864B1 (fr) * | 2003-03-24 | 2005-05-06 | Inst Francais Du Petrole | Catalyseur comprenant au moins une zeolithe choisie parmi zbm-30, zsm-48, eu-2 et eu-11 et au moins une zeolithe y et procede d'hydroconversion de charges hydrocarbonees utilisant un tel catalyseur |
| KR100523886B1 (ko) * | 2003-05-27 | 2005-10-26 | 엘지석유화학 주식회사 | 탄화수소 수증기 열분해 촉매, 그의 제조방법 및 이를이용한 경질 올레핀 제조방법 |
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| US7800088B2 (en) | 2003-06-26 | 2010-09-21 | Ncr Corporation | Security markers for identifying a source of a substance |
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| WO2005123251A1 (en) * | 2004-06-09 | 2005-12-29 | Saudi Basic Industries Corporation | Fluoride-modified zeolite catalyst and method |
| KR100632563B1 (ko) * | 2004-09-10 | 2006-10-09 | 에스케이 주식회사 | 접촉 분해용 고체산 촉매 및 이를 이용하여 전범위납사로부터 경질 올레핀을 선택적으로 제조하는 공정 |
| AR052122A1 (es) | 2004-11-05 | 2007-03-07 | Grace W R & Co | Catalizadores para olefinas livianas y glp gas licuado de petroleo en unidades de craqueo catalitico fluidizado |
| KR101229756B1 (ko) | 2004-12-28 | 2013-02-06 | 차이나 페트로리움 앤드 케미컬 코포레이션 | 탄화수소 분해 촉매 및 탄화수소 분해 방법 |
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| BRPI0502015A (pt) * | 2005-06-01 | 2007-01-23 | Petroleo Brasileiro Sa | processo de craqueamento catalìtico seletivo da fração lìquida do gás natural a olefinas leves e outros produtos |
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| EP4275789A4 (en) * | 2021-01-11 | 2024-12-18 | China Petroleum & Chemical Corporation | CATALYTIC CRACKING AGENT CONTAINING PHOSPHORUS-MODIFIED MOLECULAR SIEVE, ITS PREPARATION METHOD, ITS PREPARATION SYSTEM AND ITS USE |
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| JP3560610B2 (ja) | 1992-12-11 | 2004-09-02 | モービル オイル コーポレーション | 接触クラッキング法及びそこで使用されるｚｓｍ−５触媒の製造法 |
| CN1034223C (zh) | 1993-03-29 | 1997-03-12 | 中国石油化工总公司 | 制取低碳烯烃的裂解催化剂 |
| CN1034586C (zh) * | 1993-11-05 | 1997-04-16 | 中国石油化工总公司 | 多产低碳烯烃的催化转化方法 |
| US5472594A (en) * | 1994-07-18 | 1995-12-05 | Texaco Inc. | FCC process for producing enhanced yields of C4 /C5 olefins |
| US5521133A (en) | 1994-11-29 | 1996-05-28 | Engelhard Corporation | Phosphorus bound porous microspheres |
| US5888378A (en) | 1997-03-18 | 1999-03-30 | Mobile Oil Corporation | Catalytic cracking process |
| EP0909582B1 (en) | 1997-10-15 | 2005-12-28 | China Petro-Chemical Corporation | Cracking catalytic for the production of light olefins and its preparation |
| US6080303A (en) * | 1998-03-11 | 2000-06-27 | Exxon Chemical Patents, Inc. | Zeolite catalyst activity enhancement by aluminum phosphate and phosphorus |
| US20020049133A1 (en) * | 1999-03-02 | 2002-04-25 | Michael S. Ziebarth | High zeolite content and attrition resistant catalyst, methods for preparing the same and catalyzed processes therewith |
-
2000
- 2000-01-12 EP EP00200092A patent/EP1116775A1/en not_active Withdrawn
- 2000-11-17 JP JP2001540216A patent/JP4494697B2/ja not_active Expired - Lifetime
- 2000-11-17 US US09/715,721 patent/US6566293B1/en not_active Expired - Lifetime
- 2000-11-17 AT AT00988730T patent/ATE245687T1/de not_active IP Right Cessation
- 2000-11-17 CA CA2392232A patent/CA2392232C/en not_active Expired - Lifetime
- 2000-11-17 KR KR1020027006467A patent/KR100767958B1/ko not_active Expired - Lifetime
- 2000-11-17 BR BRPI0015726-0A patent/BR0015726B1/pt not_active IP Right Cessation
- 2000-11-17 ES ES00988730T patent/ES2202210T3/es not_active Expired - Lifetime
- 2000-11-17 WO PCT/EP2000/011533 patent/WO2001038460A1/en not_active Ceased
- 2000-11-17 DE DE60004102T patent/DE60004102T2/de not_active Expired - Lifetime
- 2000-11-17 CN CNB008160678A patent/CN1205307C/zh not_active Expired - Lifetime
- 2000-11-17 EP EP00988730A patent/EP1242566B1/en not_active Expired - Lifetime
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