JP2003512515A - 重合触媒に適したカルベニウムカチオン性錯体 - Google Patents
重合触媒に適したカルベニウムカチオン性錯体Info
- Publication number
- JP2003512515A JP2003512515A JP2001533138A JP2001533138A JP2003512515A JP 2003512515 A JP2003512515 A JP 2003512515A JP 2001533138 A JP2001533138 A JP 2001533138A JP 2001533138 A JP2001533138 A JP 2001533138A JP 2003512515 A JP2003512515 A JP 2003512515A
- Authority
- JP
- Japan
- Prior art keywords
- group
- substituted
- polymerization
- anion
- ligand
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
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- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
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- 238000000149 argon plasma sintering Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 125000003828 azulenyl group Chemical group 0.000 description 1
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- 230000009286 beneficial effect Effects 0.000 description 1
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- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
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- 125000005517 carbenium group Chemical group 0.000 description 1
- 150000001722 carbon compounds Chemical class 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
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- 208000012839 conversion disease Diseases 0.000 description 1
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- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- RAABOESOVLLHRU-UHFFFAOYSA-N diazene Chemical compound N=N RAABOESOVLLHRU-UHFFFAOYSA-N 0.000 description 1
- 229910000071 diazene Inorganic materials 0.000 description 1
- 238000006471 dimerization reaction Methods 0.000 description 1
- ZTAIFKMKUQTCRI-UHFFFAOYSA-N dioxido-(2,3,4,5,6-pentafluorophenoxy)borane;diphenylmethylbenzene Chemical compound [O-]B([O-])OC1=C(F)C(F)=C(F)C(F)=C1F.C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1 ZTAIFKMKUQTCRI-UHFFFAOYSA-N 0.000 description 1
- IDAPTOGYAAQMGT-UHFFFAOYSA-N diphenylmethylbenzene borate Chemical compound [O-]B([O-])[O-].C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1 IDAPTOGYAAQMGT-UHFFFAOYSA-N 0.000 description 1
- 239000012039 electrophile Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000011066 ex-situ storage Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 230000008570 general process Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004795 grignard reagents Chemical class 0.000 description 1
- KNLGRGALOHHVOL-UHFFFAOYSA-N hafnium(4+);methanidylbenzene Chemical compound [Hf+4].[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1 KNLGRGALOHHVOL-UHFFFAOYSA-N 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000005913 hydroamination reaction Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000006459 hydrosilylation reaction Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 238000004811 liquid chromatography Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- QSLMQGXOMLSFAW-UHFFFAOYSA-N methanidylbenzene;zirconium(4+) Chemical compound [Zr+4].[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1.[CH2-]C1=CC=CC=C1 QSLMQGXOMLSFAW-UHFFFAOYSA-N 0.000 description 1
- 229940050176 methyl chloride Drugs 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- CWAIAZCEPCBUON-UHFFFAOYSA-N n-icosyl-n-methylicosan-1-amine Chemical class CCCCCCCCCCCCCCCCCCCCN(C)CCCCCCCCCCCCCCCCCCCC CWAIAZCEPCBUON-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical class C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 150000002848 norbornenes Chemical class 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 239000010502 orange oil Substances 0.000 description 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Chemical class C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000011112 process operation Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 238000001374 small-angle light scattering Methods 0.000 description 1
- 239000012453 solvate Substances 0.000 description 1
- 230000003335 steric effect Effects 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000003930 superacid Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- XBEXIHMRFRFRAM-UHFFFAOYSA-N tridodecylalumane Chemical compound CCCCCCCCCCCC[Al](CCCCCCCCCCCC)CCCCCCCCCCCC XBEXIHMRFRFRAM-UHFFFAOYSA-N 0.000 description 1
- LALRXNPLTWZJIJ-UHFFFAOYSA-N triethylborane Chemical compound CCB(CC)CC LALRXNPLTWZJIJ-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- OBAJXDYVZBHCGT-UHFFFAOYSA-N tris(pentafluorophenyl)borane Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F OBAJXDYVZBHCGT-UHFFFAOYSA-N 0.000 description 1
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/0805—Compounds with Si-C or Si-Si linkages comprising only Si, C or H atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/02—Boron compounds
- C07F5/022—Boron compounds without C-boron linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16094299P | 1999-10-22 | 1999-10-22 | |
| US16094199P | 1999-10-22 | 1999-10-22 | |
| US60/160,941 | 1999-10-22 | ||
| US60/160,942 | 1999-10-22 | ||
| PCT/US2000/029093 WO2001030785A1 (en) | 1999-10-22 | 2000-10-20 | Carbenium cationic complexes suitable for polymerization catalysts |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2003512515A true JP2003512515A (ja) | 2003-04-02 |
| JP2003512515A5 JP2003512515A5 (enExample) | 2007-12-20 |
Family
ID=26857361
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001533138A Withdrawn JP2003512515A (ja) | 1999-10-22 | 2000-10-20 | 重合触媒に適したカルベニウムカチオン性錯体 |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP1240170B1 (enExample) |
| JP (1) | JP2003512515A (enExample) |
| KR (1) | KR20020037387A (enExample) |
| CN (1) | CN1205214C (enExample) |
| AT (1) | ATE327241T1 (enExample) |
| BR (1) | BR0014798A (enExample) |
| CA (1) | CA2387874A1 (enExample) |
| DE (1) | DE60028242T2 (enExample) |
| ES (1) | ES2263497T3 (enExample) |
| MX (1) | MXPA02004002A (enExample) |
| WO (1) | WO2001030785A1 (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011148968A1 (ja) | 2010-05-25 | 2011-12-01 | 出光興産株式会社 | 触媒組成物及び当該触媒組成物を用いるオレフィン系重合体の製造方法 |
| WO2013161833A1 (ja) | 2012-04-26 | 2013-10-31 | 三井化学株式会社 | オレフィン重合体の製造方法 |
| JP2021519359A (ja) * | 2018-03-30 | 2021-08-10 | ダウ グローバル テクノロジーズ エルエルシー | オレフィン重合のための助触媒としての高溶解性アルキル置換ホウ酸カルベニウム |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6475946B1 (en) | 1999-10-22 | 2002-11-05 | Exxonmobil Chemical Patents Inc. | Olefin polymerization catalysis with aryl substituted carbenium cationic complexes |
| CN104672358B (zh) * | 2015-01-22 | 2016-10-19 | 大连理工大学 | 一种催化极性乙烯基单体聚合的催化体系 |
| KR20200138272A (ko) | 2018-03-30 | 2020-12-09 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 중합 활성화제 |
| KR102729476B1 (ko) | 2018-03-30 | 2024-11-14 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 중합 활성화제 |
| US12037440B2 (en) | 2018-03-30 | 2024-07-16 | Dow Global Technologies Llc | Highly soluble bis-borate as binuclear co-catalysts for olefin polymerization |
| ES2932265T3 (es) | 2018-03-30 | 2023-01-17 | Dow Global Technologies Llc | Activadores de polimerización de olefinas binucleares |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3189175B2 (ja) * | 1993-07-02 | 2001-07-16 | 出光興産株式会社 | 芳香族ビニル化合物共重合体の製造方法 |
| US5502017A (en) * | 1994-03-10 | 1996-03-26 | Northwestern University | Metallocene catalyst containing bulky organic group |
| EP1196464B9 (en) * | 1998-10-23 | 2005-03-23 | ExxonMobil Chemical Patents Inc. | Bridged metallocenes for olefin copolymerization |
| ID29343A (id) * | 1998-12-30 | 2001-08-23 | Bp Chemical Ltd | Proses untuk membuat katalis polimerisasi terdukung dengan menggunakan jumlah pelarut yang dikurangi dan proses polimerisasi |
-
2000
- 2000-10-20 JP JP2001533138A patent/JP2003512515A/ja not_active Withdrawn
- 2000-10-20 WO PCT/US2000/029093 patent/WO2001030785A1/en not_active Ceased
- 2000-10-20 DE DE60028242T patent/DE60028242T2/de not_active Expired - Fee Related
- 2000-10-20 KR KR1020027005119A patent/KR20020037387A/ko not_active Ceased
- 2000-10-20 BR BR0014798-2A patent/BR0014798A/pt not_active IP Right Cessation
- 2000-10-20 EP EP00972306A patent/EP1240170B1/en not_active Expired - Lifetime
- 2000-10-20 CA CA002387874A patent/CA2387874A1/en not_active Abandoned
- 2000-10-20 ES ES00972306T patent/ES2263497T3/es not_active Expired - Lifetime
- 2000-10-20 MX MXPA02004002A patent/MXPA02004002A/es unknown
- 2000-10-20 AT AT00972306T patent/ATE327241T1/de not_active IP Right Cessation
- 2000-10-20 CN CNB008145822A patent/CN1205214C/zh not_active Expired - Fee Related
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011148968A1 (ja) | 2010-05-25 | 2011-12-01 | 出光興産株式会社 | 触媒組成物及び当該触媒組成物を用いるオレフィン系重合体の製造方法 |
| WO2013161833A1 (ja) | 2012-04-26 | 2013-10-31 | 三井化学株式会社 | オレフィン重合体の製造方法 |
| KR20140138966A (ko) | 2012-04-26 | 2014-12-04 | 미쓰이 가가쿠 가부시키가이샤 | 올레핀 중합체의 제조 방법 |
| US9340628B2 (en) | 2012-04-26 | 2016-05-17 | Mitsui Chemicals, Inc. | Process for producing olefin polymer |
| JP2021519359A (ja) * | 2018-03-30 | 2021-08-10 | ダウ グローバル テクノロジーズ エルエルシー | オレフィン重合のための助触媒としての高溶解性アルキル置換ホウ酸カルベニウム |
| JP7495880B2 (ja) | 2018-03-30 | 2024-06-05 | ダウ グローバル テクノロジーズ エルエルシー | オレフィン重合のための助触媒としての高溶解性アルキル置換ホウ酸カルベニウム |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20020037387A (ko) | 2002-05-18 |
| MXPA02004002A (es) | 2003-03-27 |
| DE60028242T2 (de) | 2007-03-29 |
| EP1240170B1 (en) | 2006-05-24 |
| CN1205214C (zh) | 2005-06-08 |
| DE60028242D1 (de) | 2006-06-29 |
| ES2263497T3 (es) | 2006-12-16 |
| BR0014798A (pt) | 2002-06-11 |
| WO2001030785A1 (en) | 2001-05-03 |
| ATE327241T1 (de) | 2006-06-15 |
| CA2387874A1 (en) | 2001-05-03 |
| CN1382147A (zh) | 2002-11-27 |
| EP1240170A1 (en) | 2002-09-18 |
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