JP2002514247A - オレフィンの重合法 - Google Patents

オレフィンの重合法

Info

Publication number
JP2002514247A
JP2002514247A JP53077198A JP53077198A JP2002514247A JP 2002514247 A JP2002514247 A JP 2002514247A JP 53077198 A JP53077198 A JP 53077198A JP 53077198 A JP53077198 A JP 53077198A JP 2002514247 A JP2002514247 A JP 2002514247A
Authority
JP
Japan
Prior art keywords
hydrogen
polymerization
group
transition metal
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP53077198A
Other languages
English (en)
Japanese (ja)
Other versions
JP2002514247A5 (enExample
Inventor
トル，マウリツ，フレデリック，ヘンドリック ファン
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Koninklijke DSM NV
Original Assignee
DSM NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from NL1004991A external-priority patent/NL1004991C2/nl
Application filed by DSM NV filed Critical DSM NV
Publication of JP2002514247A publication Critical patent/JP2002514247A/ja
Publication of JP2002514247A5 publication Critical patent/JP2002514247A5/ja
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/30—Germanium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61925—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP53077198A 1997-01-14 1997-12-15 オレフィンの重合法 Withdrawn JP2002514247A (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
NL1004991A NL1004991C2 (nl) 1997-01-14 1997-01-14 Toepassing van verbindingen die Si, Ge, Sn of Pb bevatten als cokatalysator bij de polymerisatie van olefinen.
US3816097P 1997-02-13 1997-02-13
US60/038,160 1997-02-13
US1004991 1997-02-13
PCT/NL1997/000696 WO1998030603A1 (en) 1997-01-14 1997-12-15 A process for polymerizing olefins

Publications (2)

Publication Number Publication Date
JP2002514247A true JP2002514247A (ja) 2002-05-14
JP2002514247A5 JP2002514247A5 (enExample) 2005-08-11

Family

ID=26642511

Family Applications (1)

Application Number Title Priority Date Filing Date
JP53077198A Withdrawn JP2002514247A (ja) 1997-01-14 1997-12-15 オレフィンの重合法

Country Status (10)

Country Link
US (1) US6218487B1 (enExample)
EP (1) EP0954540B1 (enExample)
JP (1) JP2002514247A (enExample)
CN (1) CN1248979A (enExample)
AT (1) ATE272078T1 (enExample)
AU (1) AU5347598A (enExample)
CA (1) CA2277886A1 (enExample)
DE (1) DE69730047T2 (enExample)
ES (1) ES2226005T3 (enExample)
WO (1) WO1998030603A1 (enExample)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2261292B1 (en) 2002-10-15 2014-07-23 ExxonMobil Chemical Patents Inc. Polyolefin adhesive compositions
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
AU2003294595A1 (en) * 2002-12-09 2004-06-30 Medtronic, Inc. Modular implantable medical device
US7119153B2 (en) * 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
US7399874B2 (en) 2004-10-29 2008-07-15 Exxonmobil Chemical Patents Inc. Catalyst compound containing divalent tridentate ligand
EP1803747A1 (en) 2005-12-30 2007-07-04 Borealis Technology Oy Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films
TW200932762A (en) 2007-10-22 2009-08-01 Univation Tech Llc Polyethylene compositions having improved properties
ES2408589T3 (es) 2008-12-18 2013-06-21 Univation Technologies, Llc Método para tratamiento de un lecho de siembra para una reacción de polimerización
IN2012DN03367A (enExample) 2009-10-19 2015-10-23 Sasol Technolgoy Pty Ltd
MY161173A (en) 2010-11-30 2017-04-14 Univation Tech Llc Processes for the polymerization of olefins with extracted metal carboxlate salts
SG190429A1 (en) 2010-11-30 2013-06-28 Univation Tech Llc Catalyst composition having improved flow characteristics and methods of making and using the same
CN103534279B (zh) 2011-05-13 2016-08-17 尤尼威蒂恩技术有限责任公司 喷雾干燥的催化剂组合物及使用其的聚合方法
BR112015016824B1 (pt) 2013-01-14 2020-10-06 Univation Technologies, Llc. Método para produzir um sistema catalítico e processo de polimerização
EP2951211B1 (en) 2013-01-30 2019-11-13 Univation Technologies, LLC Processes for making catalyst compositions having improved flow
DE102013016324A1 (de) * 2013-10-04 2015-04-09 Merck Patent Gmbh Perfluoralkylfluor- oder Perfluoralkylchlorgermanate
EP3126404B1 (en) 2014-04-02 2019-08-21 Univation Technologies, LLC Continuity compositions and olefin polymerisation method using the same
EP3268399B1 (en) 2015-03-10 2021-01-20 Univation Technologies, LLC Spray dried catalyst compositions, methods for preparation and use in olefin polymerization processes
SG11201708410UA (en) 2015-04-20 2017-11-29 Univation Tech Llc Bridged bi-aromatic ligands and olefin polymerization catalysts prepared therefrom
EP3286202B1 (en) 2015-04-20 2019-03-13 Univation Technologies, LLC Bridged bi-aromatic ligands and transition metal compounds prepared therefrom
WO2016176135A1 (en) 2015-04-27 2016-11-03 Univation Technologies, Llc Supported catalyst compositions having improved flow properties and preparation thereof
JP6914348B2 (ja) 2017-03-06 2021-08-04 ダブリュー・アール・グレース・アンド・カンパニー−コーンＷ Ｒ Ｇｒａｃｅ ＆ Ｃｏ−Ｃｏｎｎ オレフィン重合のためのチーグラー−ナッタ触媒調製用の電子供与体及び触媒系

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT544926A (enExample) 1954-08-16 Du Pont
US2992190A (en) 1957-09-13 1961-07-11 Du Pont Olefin polymerization catalyst
US3166547A (en) 1959-09-15 1965-01-19 Union Carbide Corp Polymerization of alpha-monoolefins in an aqueous diluent
NL286789A (enExample) * 1962-12-14
US3332927A (en) 1966-02-14 1967-07-25 Cabot Corp Process for polymerization
US4011385A (en) * 1975-05-12 1977-03-08 Arizona Chemical Company Polymerization of olefins
US4567155A (en) * 1984-09-24 1986-01-28 Standard Oil Company (Indiana) Olefin polymerization catalyst system producing polymer with low active chloride
US5424263A (en) * 1993-04-23 1995-06-13 Quantum Chemical Corporation Supported polymerization catalyst
JPH07109305A (ja) 1993-10-12 1995-04-25 Showa Denko Kk エチレン系重合体の製造方法
AU4146896A (en) 1994-10-31 1996-05-23 W.R. Grace & Co.-Conn. In situ dehydroxylation of supports and preparation of supported metallocene polyolefin catalysts
IT1277677B1 (it) 1995-12-21 1997-11-11 Enichem Spa Procedimento per la preparazione di polimeri vinilaromatici cristallini a struttura predominantemente sindiotattica

Also Published As

Publication number Publication date
ES2226005T3 (es) 2005-03-16
CA2277886A1 (en) 1998-07-16
CN1248979A (zh) 2000-03-29
AU5347598A (en) 1998-08-03
EP0954540A1 (en) 1999-11-10
ATE272078T1 (de) 2004-08-15
DE69730047D1 (de) 2004-09-02
US6218487B1 (en) 2001-04-17
EP0954540B1 (en) 2004-07-28
WO1998030603A1 (en) 1998-07-16
DE69730047T2 (de) 2005-07-21

Similar Documents

Publication Publication Date Title
JP2002514247A (ja) オレフィンの重合法
AU701588B2 (en) Substituted indenyl unbridged metallocenes
KR100282461B1 (ko) 메탈로센 및 이의 제조 방법
AU710813B2 (en) Supported catalyst containing tethered cation forming activator
EP0628577B2 (en) Silyl bridged metallocenes and use thereof
JP4689829B2 (ja) オレフィンの共重合用の架橋されたメタロセン
US5441920A (en) Silicon-bridged transition metal compounds
US6903229B2 (en) Metallocene compositions
KR0175921B1 (ko) 실리콘-가교결합 전이금속 화합물
US5120867A (en) Silicon-bridged transition metal compounds
JPH06157631A (ja) 触媒組成物及びポリオレフィン類の製造方法
JPH10139806A (ja) 担持された触媒システム、その調製方法、及びオレフィンを重合させるための前記触媒システムの使用
JPH10158269A (ja) 担持型化学化合物
JPH11514375A (ja) 容易に支持可能な金属錯体
JP2002514246A (ja) オレフィン重合法
US5936051A (en) Substituted metallocene catalyst for the (co)polymerization of olefins
US5856547A (en) Organo omega-alkenyl cyclopentacarbyl silane compounds
JPH06184216A (ja) α−オレフィン重合用触媒、その製法及びそれを用いる重合法
EP0889897B1 (en) Heterocyclic metal complexes and olefin polymerization process
US5726332A (en) Synthesis of novel organometallics and their use in olefin polymerization
US6537943B1 (en) Catalyst system composed of metallocenes comprising substituents containing fluorine
RU2156253C2 (ru) Каталитическая композиция, металлоценовый комплекс и способ полимеризации олефинов
JP4376456B2 (ja) 化合物
JPH04234405A (ja) オレフィン重合用触媒

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20041210

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20041210

A761 Written withdrawal of application

Free format text: JAPANESE INTERMEDIATE CODE: A761

Effective date: 20060510