JP2000508713A - ダイアモンド類似ナノ複合材組成物 - Google Patents
ダイアモンド類似ナノ複合材組成物Info
- Publication number
- JP2000508713A JP2000508713A JP9537689A JP53768997A JP2000508713A JP 2000508713 A JP2000508713 A JP 2000508713A JP 9537689 A JP9537689 A JP 9537689A JP 53768997 A JP53768997 A JP 53768997A JP 2000508713 A JP2000508713 A JP 2000508713A
- Authority
- JP
- Japan
- Prior art keywords
- composition
- precursor
- atomic
- substrate
- plasma
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/50—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges
- C23C16/503—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating using electric discharges using dc or ac discharges
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C2206/00—Materials with ceramics, cermets, hard carbon or similar non-metallic hard materials as main constituents
- F16C2206/02—Carbon based material
- F16C2206/04—Diamond like carbon [DLC]
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C2240/00—Specified values or numerical ranges of parameters; Relations between them
- F16C2240/40—Linear dimensions, e.g. length, radius, thickness, gap
- F16C2240/60—Thickness, e.g. thickness of coatings
- F16C2240/64—Thickness, e.g. thickness of coatings in the nanometer range
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/30—Self-sustaining carbon mass or layer with impregnant or other layer
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1. H濃度がC濃度の40〜80%であるところのa-C:Hおよびa-Si:Oのネ ットワークを有しかつ、相対湿度90%までの空気中で又は水中で0.1より小さい 、鋼に対する摩擦係数を持つ改良されたダイアモンド類似ナノ複合材組成物。 2. 30〜70原子%のC、20〜40原子%のH、5〜15原子%のSi、お よび5〜15原子%のOを含む請求項1の組成物。 3. 45〜70原子%のC、20〜35原子%のH、5〜10原子%のSi、及 び5〜10原子%のOを含む請求項2の組成物。 4. 少なくとも一つの遷移金属でドープされている請求項1の組成物。 5. 該遷移金属がZr、Ti、またはWである請求項4の組成物。 6. 0.5〜5原子%の不活性気体を含む請求項1または4の組成物。 7. 気体が、Ar、Kr、またはNである請求項6の組成物。 8. ナノ陥入により測定して10〜21GPaの硬度を有する請求項1又は6の 組成物。 9. 請求項1の組成物の層で少なくとも部分的に覆われ、ここで該層の厚みが 0.01〜10μmであるところの基体。 10.請求項9に従う被覆された基体を減圧室内で製造する方法であって、 (a)該室内に、沈着されるべき元素C、H、SiおよびOを適当な割合で含 む液状有機前駆体を導入する、 (b)フィラメントを用い、50〜150Aのフィラメント電流、50〜3 00Vの負のフィラメントDCバイアス電圧及び0.1〜20Aのプラズマ電流に て、電子アシストされたDC放電により、導入された前駆体からプラズマを形成す る、そして (c)プラズマ内に形成されたイオンを引き付けるために200〜1200 Vの負のDCバイアスまたは負のRFセルフバイアス電圧がかけられている基体上に 組成物を沈積させる 工程を含む方法。 11.工程(a)において前駆体が導入の間に又は後に該室内で気化される請求項1 0の方法。 12.該前駆体が30〜150℃での加熱により気化される請求項11の方法。 13.工程(c)で電圧が250〜1000Vである請求項10の方法。 14.前駆体が有機シリコン化合物である請求項10の方法。 15.化合物がポリフェニルメチルシロキサンである請求項14の方法。 16.化合物がトリフェニルノナメチルペンタシロキ サンである請求項15の方法。 17.RF電圧の周期が30〜1000kHzである請求項10の方法。 18.沈積の間に不活性気体が、減圧室に導入され、イオン化され、そして成長 しているノナ複合材層のイオンボンバードメントによって取込まれる請求項10の 方法。 19.沈積プロセスの間、イオンスパッタリング又は熱的気化によって少なくと も一つの遷移金属が組成物層に共沈積される請求項10の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP96201070.8 | 1996-04-22 | ||
EP96201070 | 1996-04-22 | ||
PCT/EP1997/001878 WO1997040207A1 (en) | 1996-04-22 | 1997-04-11 | Diamond-like nanocomposite compositions |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2000508713A true JP2000508713A (ja) | 2000-07-11 |
JP2000508713A5 JP2000508713A5 (ja) | 2004-12-02 |
JP4439594B2 JP4439594B2 (ja) | 2010-03-24 |
Family
ID=8223897
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP53768997A Expired - Fee Related JP4439594B2 (ja) | 1996-04-22 | 1997-04-11 | ダイアモンド類似ナノ複合材組成物 |
Country Status (7)
Country | Link |
---|---|
US (1) | US6200675B1 (ja) |
EP (1) | EP0896640B1 (ja) |
JP (1) | JP4439594B2 (ja) |
AU (1) | AU2697797A (ja) |
DE (1) | DE69710324T2 (ja) |
TW (1) | TW420724B (ja) |
WO (1) | WO1997040207A1 (ja) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005314454A (ja) * | 2004-04-27 | 2005-11-10 | Toyota Central Res & Dev Lab Inc | 低摩擦摺動部材 |
JP2007513856A (ja) * | 2003-12-02 | 2007-05-31 | ナムローゼ・フェンノートシャップ・ベーカート・ソシエテ・アノニム | 積層構造物 |
WO2008056577A1 (fr) * | 2006-11-10 | 2008-05-15 | Sumitomo Electric Industries, Ltd. | Film de carbone hydrogéné contenant si-o, dispositif optique incluant celui-ci, et procédé de fabrication du film hydrogéné contenant si-o et du dispositif optique |
WO2014171294A1 (ja) * | 2013-04-15 | 2014-10-23 | 株式会社神戸製鋼所 | 非晶質炭素系皮膜およびその製造方法 |
KR101823159B1 (ko) | 2009-05-13 | 2018-01-29 | 에스아이오2 메디컬 프로덕츠, 인크. | 유기실리콘 전구체를 이용한 pecvd 코팅 |
Families Citing this family (51)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2171010T3 (es) | 1997-02-04 | 2002-08-16 | Bekaert Sa Nv | Revestimiento que comprende capas de composiciones de carbono tipo diamante y de nanocompuestos tipo diamante. |
EP0885983A1 (en) | 1997-06-19 | 1998-12-23 | N.V. Bekaert S.A. | Method for coating a substrate with a diamond like nanocomposite composition |
EP1083946B1 (en) * | 1998-06-03 | 2003-12-03 | Blue Medical Devices B.V. | Stents with a diamond like coating |
EP1123991A3 (en) | 2000-02-08 | 2002-11-13 | Asm Japan K.K. | Low dielectric constant materials and processes |
US6749813B1 (en) * | 2000-03-05 | 2004-06-15 | 3M Innovative Properties Company | Fluid handling devices with diamond-like films |
US6696157B1 (en) | 2000-03-05 | 2004-02-24 | 3M Innovative Properties Company | Diamond-like glass thin films |
US6795636B1 (en) | 2000-03-05 | 2004-09-21 | 3M Innovative Properties Company | Radiation-transmissive films on glass articles |
US6669996B2 (en) * | 2000-07-06 | 2003-12-30 | University Of Louisville | Method of synthesizing metal doped diamond-like carbon films |
US7300461B2 (en) | 2000-07-28 | 2007-11-27 | Blue Medical Devices B.V. | Intravascular stent with expandable coating |
US6905981B1 (en) | 2000-11-24 | 2005-06-14 | Asm Japan K.K. | Low-k dielectric materials and processes |
US7106939B2 (en) | 2001-09-19 | 2006-09-12 | 3M Innovative Properties Company | Optical and optoelectronic articles |
US6895855B2 (en) | 2001-10-01 | 2005-05-24 | The Timken Company | Hydraulic motors and pumps with engineered surfaces |
WO2004090361A2 (en) * | 2003-04-03 | 2004-10-21 | The Timken Company | Corrosion tolerant rolling element bearing |
CN101760286B (zh) * | 2003-08-06 | 2013-03-20 | 日产自动车株式会社 | 低摩擦滑动机构、低摩擦剂组合物以及减小摩擦的方法 |
US7824498B2 (en) * | 2004-02-24 | 2010-11-02 | Applied Materials, Inc. | Coating for reducing contamination of substrates during processing |
US7296965B2 (en) * | 2004-08-23 | 2007-11-20 | United Technologies Corporation | Cryogenic bearings |
JP2006138404A (ja) * | 2004-11-12 | 2006-06-01 | Kobe Steel Ltd | 水系環境下での耐摩耗性に優れた摺動部材 |
EP1726682A1 (en) * | 2005-05-26 | 2006-11-29 | NV Bekaert SA | Coating comprising layered structures of diamond like nanocomposite layers and diamond like carbon layers. |
WO2006134066A1 (en) * | 2005-06-13 | 2006-12-21 | Nv Bekaert Sa | Coated spinning ring |
US20070020451A1 (en) * | 2005-07-20 | 2007-01-25 | 3M Innovative Properties Company | Moisture barrier coatings |
CA2885593C (en) * | 2006-05-17 | 2018-03-06 | G & H Technologies Llc | Wear resistant coating |
US20080006819A1 (en) * | 2006-06-19 | 2008-01-10 | 3M Innovative Properties Company | Moisture barrier coatings for organic light emitting diode devices |
JP2010536183A (ja) * | 2007-08-23 | 2010-11-25 | サンーゴバン アブレイシブズ,インコーポレイティド | 次世代酸化物/金属cmp用の最適化されたcmpコンディショナー設計 |
JP5090389B2 (ja) * | 2009-02-26 | 2012-12-05 | オーエスジー株式会社 | Dlcコーティングルアー |
WO2010110834A1 (en) * | 2009-03-24 | 2010-09-30 | Saint-Gobain Abrasives, Inc. | Abrasive tool for use as a chemical mechanical planarization pad conditioner |
US7985188B2 (en) | 2009-05-13 | 2011-07-26 | Cv Holdings Llc | Vessel, coating, inspection and processing apparatus |
PT2251454E (pt) | 2009-05-13 | 2014-10-01 | Sio2 Medical Products Inc | Revestimento e inspeção de vaso |
CN102459693B (zh) * | 2009-05-13 | 2015-11-25 | Sio2医药产品公司 | 使用有机硅前体的pecvd涂层 |
MY155563A (en) * | 2009-06-02 | 2015-10-30 | Saint Gobain Abrasives Inc | Corrosion-resistant cmp conditioning tools and methods for making and using same |
US9458536B2 (en) | 2009-07-02 | 2016-10-04 | Sio2 Medical Products, Inc. | PECVD coating methods for capped syringes, cartridges and other articles |
CN102612734A (zh) | 2009-09-01 | 2012-07-25 | 圣戈班磨料磨具有限公司 | 化学机械抛光修整器 |
JP5628893B2 (ja) * | 2010-03-03 | 2014-11-19 | 太陽化学工業株式会社 | 非晶質炭素膜からなる層への固定化方法及び積層体 |
US11624115B2 (en) | 2010-05-12 | 2023-04-11 | Sio2 Medical Products, Inc. | Syringe with PECVD lubrication |
US9878101B2 (en) | 2010-11-12 | 2018-01-30 | Sio2 Medical Products, Inc. | Cyclic olefin polymer vessels and vessel coating methods |
US9272095B2 (en) | 2011-04-01 | 2016-03-01 | Sio2 Medical Products, Inc. | Vessels, contact surfaces, and coating and inspection apparatus and methods |
US11116695B2 (en) | 2011-11-11 | 2021-09-14 | Sio2 Medical Products, Inc. | Blood sample collection tube |
CA2855353C (en) | 2011-11-11 | 2021-01-19 | Sio2 Medical Products, Inc. | Passivation, ph protective or lubricity coating for pharmaceutical package, coating process and apparatus |
CA2887352A1 (en) | 2012-05-09 | 2013-11-14 | Sio2 Medical Products, Inc. | Saccharide protective coating for pharmaceutical package |
KR101439131B1 (ko) * | 2012-09-21 | 2014-09-11 | 현대자동차주식회사 | 흡배기 밸브용 코팅재 및 이의 제조방법 |
CN104854257B (zh) | 2012-11-01 | 2018-04-13 | Sio2医药产品公司 | 涂层检查方法 |
US9903782B2 (en) | 2012-11-16 | 2018-02-27 | Sio2 Medical Products, Inc. | Method and apparatus for detecting rapid barrier coating integrity characteristics |
US10201660B2 (en) | 2012-11-30 | 2019-02-12 | Sio2 Medical Products, Inc. | Controlling the uniformity of PECVD deposition on medical syringes, cartridges, and the like |
US9764093B2 (en) | 2012-11-30 | 2017-09-19 | Sio2 Medical Products, Inc. | Controlling the uniformity of PECVD deposition |
WO2014134577A1 (en) | 2013-03-01 | 2014-09-04 | Sio2 Medical Products, Inc. | Plasma or cvd pre-treatment for lubricated pharmaceutical package, coating process and apparatus |
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US9937099B2 (en) | 2013-03-11 | 2018-04-10 | Sio2 Medical Products, Inc. | Trilayer coated pharmaceutical packaging with low oxygen transmission rate |
EP2971227B1 (en) | 2013-03-15 | 2017-11-15 | Si02 Medical Products, Inc. | Coating method. |
WO2014148479A1 (ja) * | 2013-03-19 | 2014-09-25 | 太陽化学工業株式会社 | 防汚用の非晶質炭素膜を備える構造体及び防汚用の非晶質炭素膜の形成方法 |
EP3693493A1 (en) | 2014-03-28 | 2020-08-12 | SiO2 Medical Products, Inc. | Antistatic coatings for plastic vessels |
CA3204930A1 (en) | 2015-08-18 | 2017-02-23 | Sio2 Medical Products, Inc. | Pharmaceutical and other packaging with low oxygen transmission rate |
US11639543B2 (en) | 2019-05-22 | 2023-05-02 | Thin Film Service, Inc. | Tetrahedral amorphous hydrogenated carbon and amorphous siloxane diamond-like nanocomposite |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5352493A (en) * | 1991-05-03 | 1994-10-04 | Veniamin Dorfman | Method for forming diamond-like nanocomposite or doped-diamond-like nanocomposite films |
-
1997
- 1997-04-11 WO PCT/EP1997/001878 patent/WO1997040207A1/en active IP Right Grant
- 1997-04-11 AU AU26977/97A patent/AU2697797A/en not_active Abandoned
- 1997-04-11 US US09/171,614 patent/US6200675B1/en not_active Expired - Lifetime
- 1997-04-11 JP JP53768997A patent/JP4439594B2/ja not_active Expired - Fee Related
- 1997-04-11 EP EP97920688A patent/EP0896640B1/en not_active Expired - Lifetime
- 1997-04-11 DE DE69710324T patent/DE69710324T2/de not_active Expired - Lifetime
- 1997-04-26 TW TW086105584A patent/TW420724B/zh not_active IP Right Cessation
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007513856A (ja) * | 2003-12-02 | 2007-05-31 | ナムローゼ・フェンノートシャップ・ベーカート・ソシエテ・アノニム | 積層構造物 |
US8518553B2 (en) | 2003-12-02 | 2013-08-27 | Sulzer Metaplas Gmbh | Layered structure |
JP2005314454A (ja) * | 2004-04-27 | 2005-11-10 | Toyota Central Res & Dev Lab Inc | 低摩擦摺動部材 |
WO2008056577A1 (fr) * | 2006-11-10 | 2008-05-15 | Sumitomo Electric Industries, Ltd. | Film de carbone hydrogéné contenant si-o, dispositif optique incluant celui-ci, et procédé de fabrication du film hydrogéné contenant si-o et du dispositif optique |
US8047653B2 (en) | 2006-11-10 | 2011-11-01 | Sumitomo Electric Industries, Ltd. | Si-O containing hydrogenated carbon film, optical device including the same, and method for manufacturing the Si-O containing hydrogenated carbon film and the optical device |
JP5293186B2 (ja) * | 2006-11-10 | 2013-09-18 | 住友電気工業株式会社 | Si−O含有水素化炭素膜とそれを含む光学デバイスおよびそれらの製造方法 |
KR101823159B1 (ko) | 2009-05-13 | 2018-01-29 | 에스아이오2 메디컬 프로덕츠, 인크. | 유기실리콘 전구체를 이용한 pecvd 코팅 |
KR20180011350A (ko) * | 2009-05-13 | 2018-01-31 | 에스아이오2 메디컬 프로덕츠, 인크. | 유기실리콘 전구체를 이용한 pecvd 코팅 |
KR102003651B1 (ko) | 2009-05-13 | 2019-07-24 | 에스아이오2 메디컬 프로덕츠, 인크. | 유기실리콘 전구체를 이용한 pecvd 코팅 |
WO2014171294A1 (ja) * | 2013-04-15 | 2014-10-23 | 株式会社神戸製鋼所 | 非晶質炭素系皮膜およびその製造方法 |
JP2014205894A (ja) * | 2013-04-15 | 2014-10-30 | 株式会社神戸製鋼所 | 非晶質炭素系皮膜およびその製造方法 |
Also Published As
Publication number | Publication date |
---|---|
US6200675B1 (en) | 2001-03-13 |
EP0896640A1 (en) | 1999-02-17 |
DE69710324T2 (de) | 2002-08-29 |
TW420724B (en) | 2001-02-01 |
AU2697797A (en) | 1997-11-12 |
EP0896640B1 (en) | 2002-02-06 |
DE69710324D1 (de) | 2002-03-21 |
WO1997040207A1 (en) | 1997-10-30 |
JP4439594B2 (ja) | 2010-03-24 |
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