IT1254369B - PROCEDURE FOR THE PRODUCTION OF LEUCO DYES WITH SULFUR AND PRODUCT OBTAINED. - Google Patents
PROCEDURE FOR THE PRODUCTION OF LEUCO DYES WITH SULFUR AND PRODUCT OBTAINED.Info
- Publication number
- IT1254369B IT1254369B ITRM920384A ITRM920384A IT1254369B IT 1254369 B IT1254369 B IT 1254369B IT RM920384 A ITRM920384 A IT RM920384A IT RM920384 A ITRM920384 A IT RM920384A IT 1254369 B IT1254369 B IT 1254369B
- Authority
- IT
- Italy
- Prior art keywords
- sulfur
- procedure
- production
- product obtained
- dyes
- Prior art date
Links
- 239000000975 dye Substances 0.000 title abstract 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title abstract 2
- 229910052717 sulfur Inorganic materials 0.000 title abstract 2
- 239000011593 sulfur Substances 0.000 title abstract 2
- 239000000988 sulfur dye Substances 0.000 abstract 2
- 150000003568 thioethers Chemical class 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 1
- -1 alkali metal sulfite Chemical class 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 150000001728 carbonyl compounds Chemical class 0.000 abstract 1
- 238000001514 detection method Methods 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920001021 polysulfide Polymers 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/0077—Preparations with possibly reduced vat, sulfur or indigo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B49/00—Sulfur dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coloring (AREA)
- Removal Of Specific Substances (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Abstract
Mediante riduzione di un colorante allo zolfo (S) in mezzo acquoso con un composto carbonilico riducente, in presenza di idrossido di metallo alcalino e facoltativamente (bi)solfito di metallo alcalino, a temperature superiori a 60°C, nonché mediante essiccamento del miscuglio di reazione, si ottengono leuco coloranti allo zolfo (L) molto stabili i quali sono praticamente esenti da solfuri e da polisolfuri, sono prontamente e completamente solubili in acqua e sono utilizzabili per colorare o tingere substrati colorabili con coloranti allo zolfo, per cui si può efficientemente evitare il disturbo dello sviluppo di H2S oppure il disturbo del riscontro di solfuri inorganici.By reducing a sulfur dye (S) in an aqueous medium with a reducing carbonyl compound, in the presence of alkali metal hydroxide and optionally (bi) alkali metal sulfite, at temperatures above 60 ° C, as well as by drying the mixture of reaction, very stable sulfur (L) dyes are obtained which are practically free of sulphides and polysulphides, are readily and completely soluble in water and can be used to color or dye substrates that can be colored with sulfur dyes, so it can be efficiently avoid disturbance of H2S development or disturbance of the detection of inorganic sulphides.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB919111194A GB9111194D0 (en) | 1991-05-23 | 1991-05-23 | Improvements in or relating to organic compounds |
GB919111211A GB9111211D0 (en) | 1991-05-23 | 1991-05-23 | Improvements in or relating to organic compounds |
GB919124959A GB9124959D0 (en) | 1991-11-25 | 1991-11-25 | Improvements in or relating to organic compounds |
GB919124998A GB9124998D0 (en) | 1991-11-25 | 1991-11-25 | Improvements in or relating to organic compounds |
Publications (3)
Publication Number | Publication Date |
---|---|
ITRM920384A0 ITRM920384A0 (en) | 1992-05-22 |
ITRM920384A1 ITRM920384A1 (en) | 1993-11-22 |
IT1254369B true IT1254369B (en) | 1995-09-14 |
Family
ID=27450684
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ITRM920384A IT1254369B (en) | 1991-05-23 | 1992-05-22 | PROCEDURE FOR THE PRODUCTION OF LEUCO DYES WITH SULFUR AND PRODUCT OBTAINED. |
Country Status (10)
Country | Link |
---|---|
JP (1) | JPH05140469A (en) |
AT (1) | AT403925B (en) |
BR (1) | BR9202015A (en) |
CH (1) | CH683775A5 (en) |
DE (1) | DE4215678A1 (en) |
ES (1) | ES2047448B1 (en) |
FR (1) | FR2676742B1 (en) |
GB (1) | GB2255981B (en) |
IT (1) | IT1254369B (en) |
TR (1) | TR26911A (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9224368D0 (en) * | 1992-11-20 | 1993-01-13 | Sandoz Ltd | Improvements in or relating to organic compounds |
US5302441A (en) * | 1991-11-15 | 1994-04-12 | The Mead Corporation | Postformable decorative laminating paper |
US5632782A (en) * | 1994-09-01 | 1997-05-27 | Clariant Finance (Bvi) Ltd. | Exhaust dyeing process for sulphur dyes |
GB9504888D0 (en) * | 1995-03-10 | 1995-04-26 | Sandoz Ltd | Improvements in or relating to oraganic compounds |
GB9504870D0 (en) * | 1995-03-10 | 1995-04-26 | Sandoz Ltd | Improvements in or relating to organic compounds |
TR199600348A2 (en) * | 1995-05-03 | 1996-11-21 | Clariant Int Ltd | Sulfur dyes, their manufacture and use. |
US20070012412A1 (en) * | 2005-07-15 | 2007-01-18 | Schweitzer-Mauduit International, Inc. | Laminate paper having increased pH stability and method of making same |
JP5308259B2 (en) * | 2009-07-14 | 2013-10-09 | 大王製紙株式会社 | Paperboard and manufacturing method thereof |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE459281A (en) * | ||||
DE198691C (en) * | ||||
DE200391C (en) * | ||||
DE251101C (en) * | ||||
FR301419A (en) * | ||||
FR698491A (en) * | 1929-04-15 | 1931-01-31 | Ici Ltd | Improvements in the production and manufacture of stable preparations of indigo-leucoic acid |
FR908875A (en) * | 1943-12-24 | 1946-04-22 | Ste Ind Chim Bale | Process for dyeing artificial fibers with sulfur dyes |
CA1081936A (en) * | 1975-11-19 | 1980-07-22 | Richard L. Doerr | Oxidation of vat and sulfur dyes with vanadate activated bromate or iodate in combination with a nitrate |
DE3532341A1 (en) * | 1985-09-11 | 1987-03-19 | Hoechst Ag | METHOD AND MEANS FOR ONE-BATH REOXIDATION AND SOAPING OF COLORINGS WITH COAT OR SULFUR COAT DYES |
ES2005094A6 (en) * | 1987-02-16 | 1989-03-01 | Cardoner Sa | Low sulphide content liq. compsn. of reduced sulphur dye - for dyeing and printing cotton etc., with high stability, good penetration and moderate substantivity |
FR2610942B1 (en) * | 1987-02-16 | 1991-12-13 | Sandoz Sa | LIQUID SULFUR DYE COMPOSITIONS AND THEIR PREPARATION |
US4917706B2 (en) * | 1988-02-01 | 1996-02-20 | Sandoz Ltd | Liquid compositions of prereduced sulfur dyes and production thereof |
-
1992
- 1992-05-13 DE DE4215678A patent/DE4215678A1/en not_active Withdrawn
- 1992-05-21 CH CH1640/92A patent/CH683775A5/en not_active IP Right Cessation
- 1992-05-21 FR FR9206352A patent/FR2676742B1/en not_active Expired - Lifetime
- 1992-05-22 IT ITRM920384A patent/IT1254369B/en active
- 1992-05-22 ES ES09201058A patent/ES2047448B1/en not_active Expired - Fee Related
- 1992-05-22 AT AT0105992A patent/AT403925B/en not_active IP Right Cessation
- 1992-05-22 GB GB9210931A patent/GB2255981B/en not_active Expired - Fee Related
- 1992-05-22 JP JP4130766A patent/JPH05140469A/en active Pending
- 1992-05-22 TR TR00449/92A patent/TR26911A/en unknown
- 1992-05-27 BR BR929202015A patent/BR9202015A/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
ES2047448A1 (en) | 1994-02-16 |
ITRM920384A0 (en) | 1992-05-22 |
JPH05140469A (en) | 1993-06-08 |
ES2047448B1 (en) | 1994-11-01 |
ITRM920384A1 (en) | 1993-11-22 |
CH683775A5 (en) | 1994-05-13 |
ATA105992A (en) | 1997-11-15 |
TR26911A (en) | 1994-08-22 |
BR9202015A (en) | 1993-11-30 |
FR2676742B1 (en) | 2000-09-15 |
GB2255981A (en) | 1992-11-25 |
DE4215678A1 (en) | 1992-11-26 |
FR2676742A1 (en) | 1992-11-27 |
GB2255981B (en) | 1995-02-01 |
GB9210931D0 (en) | 1992-07-08 |
AT403925B (en) | 1998-06-25 |
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