IN2012DN06460A - - Google Patents
Info
- Publication number
- IN2012DN06460A IN2012DN06460A IN6460DEN2012A IN2012DN06460A IN 2012DN06460 A IN2012DN06460 A IN 2012DN06460A IN 6460DEN2012 A IN6460DEN2012 A IN 6460DEN2012A IN 2012DN06460 A IN2012DN06460 A IN 2012DN06460A
- Authority
- IN
- India
- Prior art keywords
- catalyst
- formula
- group
- activating compound
- polymer
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 abstract 4
- 230000003213 activating effect Effects 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000003446 ligand Substances 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 abstract 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002829 nitrogen Chemical class 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 1
- 239000004711 α-olefin Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/04—Cp or analog not bridged to a non-Cp X ancillary anionic donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NLPCT/NL03/00503 | 2003-07-09 | ||
| PCT/NL2004/000458 WO2005005496A2 (en) | 2003-07-09 | 2004-06-29 | Process for the production of a polymer comprising monomeric units of ethylene, an a-olefin and a vinyl norbornene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| IN2012DN06460A true IN2012DN06460A (enExample) | 2015-10-09 |
Family
ID=34056976
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IN6460DEN2012 IN2012DN06460A (enExample) | 2003-07-09 | 2004-06-29 |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US7829645B2 (enExample) |
| EP (3) | EP3112385B1 (enExample) |
| JP (2) | JP5086637B2 (enExample) |
| KR (1) | KR20060054293A (enExample) |
| CN (1) | CN100528915C (enExample) |
| IN (1) | IN2012DN06460A (enExample) |
| WO (1) | WO2005005496A2 (enExample) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5086637B2 (ja) * | 2003-07-09 | 2012-11-28 | ランクセス エラストマーズ ビー．ブイ． | エチレン、α−オレフィン、およびビニルノルボルネンのモノマー単位を含むポリマーの製造方法 |
| JP2007063409A (ja) * | 2005-08-31 | 2007-03-15 | Asahi Kasei Chemicals Corp | 環状オレフィン系共重合体の製造方法 |
| GB0610667D0 (en) * | 2006-05-30 | 2006-07-05 | Nova Chem Int Sa | Supported polymerization catalysts |
| ATE531738T1 (de) * | 2007-02-08 | 2011-11-15 | Lanxess Elastomers Bv | Elastomerverbindung |
| WO2008148499A1 (en) * | 2007-06-06 | 2008-12-11 | Dsm Ip Assets B.V. | Imine catalyst |
| DE102007057854A1 (de) * | 2007-11-28 | 2009-06-04 | Philipps-Universität Marburg | Cyclopentadienylphosphazen-Komplexe (CpPN-Komplexe) von Metallen der 3. und 4. Gruppe und der Lanthanoide |
| EP2336205A1 (en) * | 2009-12-21 | 2011-06-22 | DSM IP Assets B.V. | TI catalyst system comprising substituted cyclopentadienyl, amidine and diene ligand |
| EP2336204A1 (en) * | 2009-12-21 | 2011-06-22 | DSM IP Assets B.V. | Borane activated ti catalyst system comprising amidine and diene ligand |
| CN102822180B (zh) * | 2010-02-19 | 2016-06-15 | 陶氏环球技术有限责任公司 | 金属配体配合物和催化剂 |
| DE102013205996A1 (de) * | 2013-04-04 | 2014-10-09 | Achim Methling Josef Ranftl GbR (vertretungsberechtigte Gesellschafter: Achim Methling, A-1110 Wien, Josef Ranftl, 82256 Fürstenfeldbruck) | Verfahren zum Abbau von synthetischen Polymeren und eine Vorrichtung zu dessen Durchführung |
| EP2818513B1 (en) * | 2013-06-25 | 2015-12-23 | Lanxess Elastomers B.V. | Oil extended ethylene-alpha-olefin-non-conjugated diene copolymer |
| IN2015DN02232A (enExample) | 2013-06-28 | 2015-08-21 | Lg Chemical Ltd | |
| WO2014209084A1 (ko) | 2013-06-28 | 2014-12-31 | 주식회사 엘지화학 | 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법 |
| KR101585204B1 (ko) | 2013-06-28 | 2016-01-13 | 주식회사 엘지화학 | 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법 |
| EP2883889A4 (en) | 2013-06-28 | 2016-06-01 | Lg Chemical Ltd | TERNARY ELASTIC COPOLYMER WITH A DIEN AND METHOD FOR THE PRODUCTION THEREOF |
| KR101585206B1 (ko) | 2013-07-22 | 2016-01-13 | 주식회사 엘지화학 | 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법 |
| EP2835381A1 (en) | 2013-08-09 | 2015-02-11 | Lanxess Elastomers B.V. | Functionalized olefinic copolymers |
| WO2015122495A1 (ja) | 2014-02-14 | 2015-08-20 | 三井化学株式会社 | エチレン・α－オレフィン・非共役ポリエン共重合体、その製造方法ならびに用途 |
| US9382361B2 (en) | 2014-03-21 | 2016-07-05 | Exxonmobil Chemical Patents Inc. | Process to produce ethylene propylene copolymers |
| JP6358852B2 (ja) * | 2014-05-23 | 2018-07-18 | ポリプラスチックス株式会社 | 環状オレフィン共重合体の製造方法 |
| US9441063B2 (en) * | 2014-10-09 | 2016-09-13 | Chevron Phillips Chemical Company Lp | Titanium phosphinimide and titanium iminoimidazolidide catalyst systems with activator-supports |
| US10800865B2 (en) | 2015-09-14 | 2020-10-13 | Exxonmobil Chemical Patents Inc. | Process for making branched EPDM and the EPDM therefrom |
| CN108191910B (zh) * | 2016-12-08 | 2020-11-10 | 中国石油化工股份有限公司 | 单茂金属化合物及制备方法和烯烃聚合用催化剂组合物及应用和制备丙烯均聚物的方法 |
| CN108864348B (zh) * | 2017-05-15 | 2021-02-05 | 中国石油化工股份有限公司 | 一种乙烯-α烯烃-非共轭二烯烃聚合物及其制备方法 |
| EP3409697A1 (en) | 2017-05-28 | 2018-12-05 | SABIC Global Technologies B.V. | Preparation of polymer dispersions |
| US11041034B2 (en) | 2018-02-09 | 2021-06-22 | Exxonmobil Chemical Patents Inc. | Ethylene-a-olefin-diene elastomers and methods of making them |
| KR102520290B1 (ko) | 2018-03-20 | 2023-04-10 | 미쓰이 가가쿠 가부시키가이샤 | 에틸렌·α-올레핀·비공액 폴리엔 공중합체, 그의 제조 방법 및 용도 |
| JP7587494B2 (ja) | 2018-09-28 | 2024-11-20 | ダウ グローバル テクノロジーズ エルエルシー | 四官能性長鎖分岐ポリオレフィン樹脂の重合プロセス |
| JP7125569B2 (ja) * | 2020-06-29 | 2022-08-24 | ポリプラスチックス株式会社 | 環状オレフィン共重合体の製造方法、及びノルボルネン単量体とエチレンとの共重合用の触媒組成物 |
| EP4182365A1 (en) * | 2020-07-17 | 2023-05-24 | Dow Global Technologies LLC | Hydrocarbyl-modified methylaluminoxane cocatalysts for constrained geometry procatalysts |
| CN118679198B (zh) * | 2021-12-23 | 2025-12-05 | 宝理塑料株式会社 | 环烯烃共聚物的制造方法以及催化剂组合物 |
| CN115043965B (zh) * | 2022-07-27 | 2023-04-21 | 中国科学技术大学 | 含有膦亚胺配体骨架的单茂金属催化剂及其制备方法和应用 |
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| US5229478A (en) * | 1988-06-16 | 1993-07-20 | Exxon Chemical Patents Inc. | Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system |
| US4871705A (en) * | 1988-06-16 | 1989-10-03 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst |
| KR900009719A (ko) | 1988-12-16 | 1990-07-05 | 엠. 데이비드 레오나이드 | 신규 에틸렌-프로필렌 공중합체 |
| US5064802A (en) * | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| JP2673206B2 (ja) * | 1990-06-06 | 1997-11-05 | フジオーゼックス株式会社 | スクリューコンベヤに対する丸棒状素材供給装置 |
| US5491207A (en) * | 1993-12-14 | 1996-02-13 | Exxon Chemical Patents Inc. | Process of producing high molecular weight ethylene-α-olefin elastomers with an indenyl metallocene catalyst system |
| DE69511352T2 (de) | 1994-10-03 | 2000-03-30 | Sumitomo Chemical Co., Ltd. | Verfahren zur Herstellung eines Copolymerkautschuks |
| TW300246B (enExample) | 1995-04-11 | 1997-03-11 | Mitsui Petroleum Chemicals Ind | |
| US5696213A (en) * | 1995-04-21 | 1997-12-09 | Exxon Chemical Patents Inc. | Ethylene-α-olefin-diolefin elastomers solution polymerization process |
| MX9800210A (es) | 1995-06-29 | 1998-04-30 | Dsm Nv | Copolimero elastomerico. |
| JPH09241326A (ja) * | 1996-03-04 | 1997-09-16 | Sumitomo Chem Co Ltd | エチレン−α−オレフィン共重合体及びその製造方法 |
| US6225426B1 (en) * | 1996-04-10 | 2001-05-01 | Uniroyal Chemical Company, Inc. | Process for producing polyolefin elastomer employing a metallocene catalyst |
| US5965756A (en) | 1996-12-19 | 1999-10-12 | The Dow Chemical Company | Fused ring substituted indenyl metal complexes and polymerization process |
| WO1998049212A1 (en) | 1997-04-30 | 1998-11-05 | The Dow Chemical Company | Ethylene/alpha-olefin/diene interpolymers and their preparation |
| CA2206944C (en) | 1997-05-30 | 2006-08-29 | Douglas W. Stephan | High temperature solution polymerization process |
| KR100538859B1 (ko) * | 1997-06-27 | 2005-12-23 | 코닌클리즈케 디에스엠 엔.브이. | 탄성중합성 공중합체 및 그의 제조방법 |
| US6228790B1 (en) | 1998-06-29 | 2001-05-08 | Industrial Technology Research Institute | Dinuclear metallocene catalyst for preparing high molecular weight olefin polymer |
| CA2245375C (en) * | 1998-08-19 | 2006-08-15 | Nova Chemicals Ltd. | Dual reactor polyethylene process using a phosphinimine catalyst |
| GB9909724D0 (en) * | 1998-09-25 | 1999-06-23 | Macgregor Keith M | Medical cleaning compositions |
| US6225427B1 (en) | 1998-10-15 | 2001-05-01 | Uniroyal Chemical Company, Inc. | Olefin polymerization process employing metallocene catalyst provided by cocatalyst activation of a metallocene procatalyst |
| CA2254512C (en) * | 1998-11-25 | 2008-02-12 | Nova Chemicals Ltd. | Slurry polymerization process using an unsupported phosphinimine catalyst |
| BR0011524A (pt) | 1999-05-14 | 2002-03-26 | Dupont Dow Elastomers Llc | Composição de interpolìmero, processo para a preparação de uma composição de interpolìmero, artigo de manufatura e artigo de múltiplas camadas |
| US6207773B1 (en) * | 1999-07-28 | 2001-03-27 | Industrial Technology Research Institute | Metallocene catalyst for preparing olefin polymer |
| US6369176B1 (en) | 1999-08-19 | 2002-04-09 | Dupont Dow Elastomers Llc | Process for preparing in a single reactor polymer blends having a broad molecular weight distribution |
| CA2311068C (en) * | 2000-06-08 | 2010-03-09 | Nova Chemicals Corporation | Process to prepare ethylene propylene elastomer |
| JP2002020414A (ja) | 2000-07-11 | 2002-01-23 | Ube Ind Ltd | 脂肪族オレフィン重合用触媒及びそれを用いた重合方法 |
| EP1195391A1 (en) | 2000-10-05 | 2002-04-10 | ATOFINA Research | Production of polypropylene |
| US6583082B2 (en) * | 2000-12-01 | 2003-06-24 | The Governors Of The University Of Alberta | Functional organic particles for catalyst supports |
| NL1016799C2 (nl) * | 2000-12-05 | 2002-06-06 | Dsm Nv | Polymeersamenstelling, werkwijze voor de bereiding van de polymeersamenstelling en vormdelen hiervan. |
| DE60201340T2 (de) | 2001-03-05 | 2005-02-17 | Stichting Dutch Polymer Institute | Katalysatorbestandteil für olefinpolymerisation und katalysatorsystem und polymerisationsverfahren unter verwendung eines solchen katalysatorsystems |
| EP1519967B2 (en) * | 2002-06-19 | 2013-08-21 | ExxonMobil Chemical Patents Inc. | Method for the polymerisation of ethylene, higher alpha-olefin comonomer and dienes, especially vinyl norbornene and polymers made using such processes |
| JP5086637B2 (ja) * | 2003-07-09 | 2012-11-28 | ランクセス エラストマーズ ビー．ブイ． | エチレン、α−オレフィン、およびビニルノルボルネンのモノマー単位を含むポリマーの製造方法 |
-
2004
- 2004-06-29 JP JP2006518558A patent/JP5086637B2/ja not_active Expired - Lifetime
- 2004-06-29 IN IN6460DEN2012 patent/IN2012DN06460A/en unknown
- 2004-06-29 EP EP16173894.3A patent/EP3112385B1/en not_active Expired - Lifetime
- 2004-06-29 CN CNB2004800238264A patent/CN100528915C/zh not_active Expired - Lifetime
- 2004-06-29 KR KR1020067000547A patent/KR20060054293A/ko not_active Ceased
- 2004-06-29 WO PCT/NL2004/000458 patent/WO2005005496A2/en not_active Ceased
- 2004-06-29 EP EP04748688A patent/EP1641847A2/en not_active Ceased
- 2004-06-29 EP EP10183547.8A patent/EP2261269B1/en not_active Expired - Lifetime
- 2004-06-29 US US10/563,377 patent/US7829645B2/en not_active Expired - Lifetime
-
2010
- 2010-09-29 US US12/923,596 patent/US8124707B2/en not_active Expired - Lifetime
-
2011
- 2011-10-21 JP JP2011231927A patent/JP5829479B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| KR20060054293A (ko) | 2006-05-22 |
| EP2261269A3 (en) | 2011-03-30 |
| JP2007521371A (ja) | 2007-08-02 |
| WO2005005496A2 (en) | 2005-01-20 |
| WO2005005496A3 (en) | 2005-12-01 |
| EP3112385B1 (en) | 2020-01-08 |
| EP3112385A1 (en) | 2017-01-04 |
| EP1641847A2 (en) | 2006-04-05 |
| EP2261269B1 (en) | 2016-11-09 |
| JP5086637B2 (ja) | 2012-11-28 |
| US20060205900A1 (en) | 2006-09-14 |
| US20110021732A1 (en) | 2011-01-27 |
| EP2261269A2 (en) | 2010-12-15 |
| JP2012046764A (ja) | 2012-03-08 |
| US7829645B2 (en) | 2010-11-09 |
| JP5829479B2 (ja) | 2015-12-09 |
| US8124707B2 (en) | 2012-02-28 |
| CN1839164A (zh) | 2006-09-27 |
| CN100528915C (zh) | 2009-08-19 |
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