IN2012DN06460A - - Google Patents
Info
- Publication number
- IN2012DN06460A IN2012DN06460A IN6460DEN2012A IN2012DN06460A IN 2012DN06460 A IN2012DN06460 A IN 2012DN06460A IN 6460DEN2012 A IN6460DEN2012 A IN 6460DEN2012A IN 2012DN06460 A IN2012DN06460 A IN 2012DN06460A
- Authority
- IN
- India
- Prior art keywords
- catalyst
- formula
- group
- activating compound
- polymer
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 abstract 4
- 230000003213 activating effect Effects 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000003446 ligand Substances 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 abstract 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002829 nitrogen Chemical class 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 1
- 239000004711 α-olefin Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/04—Cp or analog not bridged to a non-Cp X ancillary anionic donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NLPCT/NL03/00503 | 2003-07-09 | ||
| PCT/NL2004/000458 WO2005005496A2 (en) | 2003-07-09 | 2004-06-29 | Process for the production of a polymer comprising monomeric units of ethylene, an a-olefin and a vinyl norbornene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| IN2012DN06460A true IN2012DN06460A (enExample) | 2015-10-09 |
Family
ID=34056976
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IN6460DEN2012 IN2012DN06460A (enExample) | 2003-07-09 | 2004-06-29 |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US7829645B2 (enExample) |
| EP (3) | EP2261269B1 (enExample) |
| JP (2) | JP5086637B2 (enExample) |
| KR (1) | KR20060054293A (enExample) |
| CN (1) | CN100528915C (enExample) |
| IN (1) | IN2012DN06460A (enExample) |
| WO (1) | WO2005005496A2 (enExample) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005005496A2 (en) * | 2003-07-09 | 2005-01-20 | Dsm Ip Assets B.V. | Process for the production of a polymer comprising monomeric units of ethylene, an a-olefin and a vinyl norbornene |
| JP2007063409A (ja) * | 2005-08-31 | 2007-03-15 | Asahi Kasei Chemicals Corp | 環状オレフィン系共重合体の製造方法 |
| GB0610667D0 (en) * | 2006-05-30 | 2006-07-05 | Nova Chem Int Sa | Supported polymerization catalysts |
| BRPI0808187B1 (pt) * | 2007-02-08 | 2018-03-06 | Arlanxeo Netherlands B.V. | Composto elastomérico |
| WO2008148499A1 (en) * | 2007-06-06 | 2008-12-11 | Dsm Ip Assets B.V. | Imine catalyst |
| DE102007057854A1 (de) * | 2007-11-28 | 2009-06-04 | Philipps-Universität Marburg | Cyclopentadienylphosphazen-Komplexe (CpPN-Komplexe) von Metallen der 3. und 4. Gruppe und der Lanthanoide |
| EP2336205A1 (en) * | 2009-12-21 | 2011-06-22 | DSM IP Assets B.V. | TI catalyst system comprising substituted cyclopentadienyl, amidine and diene ligand |
| EP2336204A1 (en) * | 2009-12-21 | 2011-06-22 | DSM IP Assets B.V. | Borane activated ti catalyst system comprising amidine and diene ligand |
| WO2011102989A1 (en) * | 2010-02-19 | 2011-08-25 | Dow Global Technologies Llc | Metal-ligand complexes and catalysts |
| DE102013205996A1 (de) * | 2013-04-04 | 2014-10-09 | Achim Methling Josef Ranftl GbR (vertretungsberechtigte Gesellschafter: Achim Methling, A-1110 Wien, Josef Ranftl, 82256 Fürstenfeldbruck) | Verfahren zum Abbau von synthetischen Polymeren und eine Vorrichtung zu dessen Durchführung |
| EP2818513B1 (en) * | 2013-06-25 | 2015-12-23 | Lanxess Elastomers B.V. | Oil extended ethylene-alpha-olefin-non-conjugated diene copolymer |
| CN104736579A (zh) | 2013-06-28 | 2015-06-24 | 株式会社Lg化学 | 弹性二烯三元共聚物及其制备方法 |
| WO2014209085A1 (ko) | 2013-06-28 | 2014-12-31 | 주식회사 엘지화학 | 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법 |
| EP2883889A4 (en) | 2013-06-28 | 2016-06-01 | Lg Chemical Ltd | TERNARY ELASTIC COPOLYMER WITH A DIEN AND METHOD FOR THE PRODUCTION THEREOF |
| KR101585206B1 (ko) | 2013-07-22 | 2016-01-13 | 주식회사 엘지화학 | 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법 |
| KR101585204B1 (ko) | 2013-06-28 | 2016-01-13 | 주식회사 엘지화학 | 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법 |
| EP2835381A1 (en) | 2013-08-09 | 2015-02-11 | Lanxess Elastomers B.V. | Functionalized olefinic copolymers |
| BR112016018537B1 (pt) | 2014-02-14 | 2021-09-28 | Mitsui Chemicals, Inc | Copolímero de etileno/a-olefina/polieno não conjugado e processo para produção destes, composição de resina termoplástica, composição de borracha, produto obtido por reticulação da composição de borracha, artigo reticulado modelado, processo para produção deste, produto por usar o artigo reticulado modelado, composição de resina e produto obtido por reticulação da composição de resina |
| CN108794675B (zh) * | 2014-03-21 | 2020-12-29 | 埃克森美孚化学专利公司 | 乙烯丙烯共聚物的制备方法 |
| JP6358852B2 (ja) * | 2014-05-23 | 2018-07-18 | ポリプラスチックス株式会社 | 環状オレフィン共重合体の製造方法 |
| US9441063B2 (en) * | 2014-10-09 | 2016-09-13 | Chevron Phillips Chemical Company Lp | Titanium phosphinimide and titanium iminoimidazolidide catalyst systems with activator-supports |
| US10800865B2 (en) | 2015-09-14 | 2020-10-13 | Exxonmobil Chemical Patents Inc. | Process for making branched EPDM and the EPDM therefrom |
| CN108191910B (zh) * | 2016-12-08 | 2020-11-10 | 中国石油化工股份有限公司 | 单茂金属化合物及制备方法和烯烃聚合用催化剂组合物及应用和制备丙烯均聚物的方法 |
| CN108864348B (zh) * | 2017-05-15 | 2021-02-05 | 中国石油化工股份有限公司 | 一种乙烯-α烯烃-非共轭二烯烃聚合物及其制备方法 |
| EP3409697A1 (en) | 2017-05-28 | 2018-12-05 | SABIC Global Technologies B.V. | Preparation of polymer dispersions |
| US20190248934A1 (en) | 2018-02-09 | 2019-08-15 | Exxonmobil Chemical Patents Inc. | Ethylene-a-olefin-diene Elastomers and Methods of Making Them |
| WO2019180802A1 (ja) | 2018-03-20 | 2019-09-26 | 三井化学株式会社 | エチレン・α－オレフィン・非共役ポリエン共重合体、その製造方法および用途 |
| KR102900558B1 (ko) | 2018-09-28 | 2025-12-18 | 다우 글로벌 테크놀로지스 엘엘씨 | 4작용성 장쇄 분지형 폴리올레핀 수지를 중합하는 방법 |
| KR102509512B1 (ko) * | 2020-06-29 | 2023-03-14 | 포리프라스틱 가부시키가이샤 | 환상 올레핀 공중합체의 제조방법, 및 노보넨 단량체와 에틸렌의 공중합용 촉매 조성물 |
| CN116194492A (zh) * | 2020-07-17 | 2023-05-30 | 陶氏环球技术有限责任公司 | 用于限制几何构型主催化剂的烃基改性的甲基铝氧烷助催化剂 |
| DE112022005556T5 (de) * | 2021-12-23 | 2024-09-19 | Daicel Corporation | Verfahren zur Herstellung eines zyklischen Olefincopolymers und Katalysatorzusammensetzung |
| CN115043965B (zh) * | 2022-07-27 | 2023-04-21 | 中国科学技术大学 | 含有膦亚胺配体骨架的单茂金属催化剂及其制备方法和应用 |
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| KR900009719A (ko) | 1988-12-16 | 1990-07-05 | 엠. 데이비드 레오나이드 | 신규 에틸렌-프로필렌 공중합체 |
| US5064802A (en) * | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| JP2673206B2 (ja) * | 1990-06-06 | 1997-11-05 | フジオーゼックス株式会社 | スクリューコンベヤに対する丸棒状素材供給装置 |
| US5491207A (en) * | 1993-12-14 | 1996-02-13 | Exxon Chemical Patents Inc. | Process of producing high molecular weight ethylene-α-olefin elastomers with an indenyl metallocene catalyst system |
| EP0708117B1 (en) | 1994-10-03 | 1999-08-11 | Sumitomo Chemical Company Limited | Process for producing copolymer rubber |
| TW300246B (enExample) | 1995-04-11 | 1997-03-11 | Mitsui Petroleum Chemicals Ind | |
| US5696213A (en) * | 1995-04-21 | 1997-12-09 | Exxon Chemical Patents Inc. | Ethylene-α-olefin-diolefin elastomers solution polymerization process |
| BR9609483A (pt) | 1995-06-29 | 1999-03-02 | Dsm Nv | Copolímero elastomérico |
| JPH09241326A (ja) * | 1996-03-04 | 1997-09-16 | Sumitomo Chem Co Ltd | エチレン−α−オレフィン共重合体及びその製造方法 |
| US6225426B1 (en) * | 1996-04-10 | 2001-05-01 | Uniroyal Chemical Company, Inc. | Process for producing polyolefin elastomer employing a metallocene catalyst |
| US5965756A (en) | 1996-12-19 | 1999-10-12 | The Dow Chemical Company | Fused ring substituted indenyl metal complexes and polymerization process |
| KR100488833B1 (ko) | 1997-04-30 | 2005-05-11 | 듀폰 다우 엘라스토마스 엘. 엘. 씨. | 에틸렌/알파-올레핀/디엔 공중합체 및 그의 제조 방법 |
| CA2206944C (en) | 1997-05-30 | 2006-08-29 | Douglas W. Stephan | High temperature solution polymerization process |
| KR100538859B1 (ko) * | 1997-06-27 | 2005-12-23 | 코닌클리즈케 디에스엠 엔.브이. | 탄성중합성 공중합체 및 그의 제조방법 |
| US6228790B1 (en) | 1998-06-29 | 2001-05-08 | Industrial Technology Research Institute | Dinuclear metallocene catalyst for preparing high molecular weight olefin polymer |
| CA2245375C (en) * | 1998-08-19 | 2006-08-15 | Nova Chemicals Ltd. | Dual reactor polyethylene process using a phosphinimine catalyst |
| GB9909724D0 (en) * | 1998-09-25 | 1999-06-23 | Macgregor Keith M | Medical cleaning compositions |
| US6225427B1 (en) | 1998-10-15 | 2001-05-01 | Uniroyal Chemical Company, Inc. | Olefin polymerization process employing metallocene catalyst provided by cocatalyst activation of a metallocene procatalyst |
| CA2254512C (en) | 1998-11-25 | 2008-02-12 | Nova Chemicals Ltd. | Slurry polymerization process using an unsupported phosphinimine catalyst |
| CN1367801A (zh) | 1999-05-14 | 2002-09-04 | 杜邦唐弹性体公司 | 高度结晶的无规乙烯/α－烯烃/多烯烃共聚体 |
| US6207773B1 (en) * | 1999-07-28 | 2001-03-27 | Industrial Technology Research Institute | Metallocene catalyst for preparing olefin polymer |
| US6369176B1 (en) | 1999-08-19 | 2002-04-09 | Dupont Dow Elastomers Llc | Process for preparing in a single reactor polymer blends having a broad molecular weight distribution |
| CA2311068C (en) | 2000-06-08 | 2010-03-09 | Nova Chemicals Corporation | Process to prepare ethylene propylene elastomer |
| JP2002020414A (ja) | 2000-07-11 | 2002-01-23 | Ube Ind Ltd | 脂肪族オレフィン重合用触媒及びそれを用いた重合方法 |
| EP1195391A1 (en) | 2000-10-05 | 2002-04-10 | ATOFINA Research | Production of polypropylene |
| US6583082B2 (en) * | 2000-12-01 | 2003-06-24 | The Governors Of The University Of Alberta | Functional organic particles for catalyst supports |
| NL1016799C2 (nl) * | 2000-12-05 | 2002-06-06 | Dsm Nv | Polymeersamenstelling, werkwijze voor de bereiding van de polymeersamenstelling en vormdelen hiervan. |
| US6858558B2 (en) | 2001-03-05 | 2005-02-22 | Stichting Dutch Polymer Institute | Olefin polymerization catalyst component and catalyst system and polymerization process using such a catalyst system |
| DE60327855D1 (de) * | 2002-06-19 | 2009-07-16 | Exxonmobil Chem Patents Inc | Verfahren zur polymerisation von ethylen, höheren alpha-olefin-comonomeren und dienen, insbesondere vinyl norbornen und nach diesem verfahren hergestellte polymere |
| WO2005005496A2 (en) | 2003-07-09 | 2005-01-20 | Dsm Ip Assets B.V. | Process for the production of a polymer comprising monomeric units of ethylene, an a-olefin and a vinyl norbornene |
-
2004
- 2004-06-29 WO PCT/NL2004/000458 patent/WO2005005496A2/en not_active Ceased
- 2004-06-29 EP EP10183547.8A patent/EP2261269B1/en not_active Expired - Lifetime
- 2004-06-29 US US10/563,377 patent/US7829645B2/en not_active Expired - Lifetime
- 2004-06-29 CN CNB2004800238264A patent/CN100528915C/zh not_active Expired - Lifetime
- 2004-06-29 KR KR1020067000547A patent/KR20060054293A/ko not_active Ceased
- 2004-06-29 IN IN6460DEN2012 patent/IN2012DN06460A/en unknown
- 2004-06-29 EP EP16173894.3A patent/EP3112385B1/en not_active Expired - Lifetime
- 2004-06-29 JP JP2006518558A patent/JP5086637B2/ja not_active Expired - Lifetime
- 2004-06-29 EP EP04748688A patent/EP1641847A2/en not_active Ceased
-
2010
- 2010-09-29 US US12/923,596 patent/US8124707B2/en not_active Expired - Lifetime
-
2011
- 2011-10-21 JP JP2011231927A patent/JP5829479B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| WO2005005496A3 (en) | 2005-12-01 |
| EP1641847A2 (en) | 2006-04-05 |
| JP5829479B2 (ja) | 2015-12-09 |
| EP3112385B1 (en) | 2020-01-08 |
| JP2007521371A (ja) | 2007-08-02 |
| EP3112385A1 (en) | 2017-01-04 |
| JP2012046764A (ja) | 2012-03-08 |
| EP2261269B1 (en) | 2016-11-09 |
| KR20060054293A (ko) | 2006-05-22 |
| WO2005005496A2 (en) | 2005-01-20 |
| US20110021732A1 (en) | 2011-01-27 |
| US7829645B2 (en) | 2010-11-09 |
| CN1839164A (zh) | 2006-09-27 |
| EP2261269A3 (en) | 2011-03-30 |
| EP2261269A2 (en) | 2010-12-15 |
| CN100528915C (zh) | 2009-08-19 |
| JP5086637B2 (ja) | 2012-11-28 |
| US8124707B2 (en) | 2012-02-28 |
| US20060205900A1 (en) | 2006-09-14 |
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