HU188660B - Process for production of cathalizator containing cooper oxid and aluminium-oxid - Google Patents
Process for production of cathalizator containing cooper oxid and aluminium-oxid Download PDFInfo
- Publication number
- HU188660B HU188660B HU81784A HU78481A HU188660B HU 188660 B HU188660 B HU 188660B HU 81784 A HU81784 A HU 81784A HU 78481 A HU78481 A HU 78481A HU 188660 B HU188660 B HU 188660B
- Authority
- HU
- Hungary
- Prior art keywords
- spinel
- catalyst
- copper
- zinc
- oxide
- Prior art date
Links
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 title claims description 22
- 238000000034 method Methods 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title abstract description 6
- 239000003054 catalyst Substances 0.000 claims abstract description 112
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 99
- 239000010949 copper Substances 0.000 claims abstract description 53
- 229910052596 spinel Inorganic materials 0.000 claims abstract description 50
- 239000011029 spinel Substances 0.000 claims abstract description 50
- 239000011787 zinc oxide Substances 0.000 claims abstract description 49
- 229910052802 copper Inorganic materials 0.000 claims abstract description 48
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 47
- 150000003751 zinc Chemical class 0.000 claims abstract description 18
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000005751 Copper oxide Substances 0.000 claims abstract description 17
- 229910000431 copper oxide Inorganic materials 0.000 claims abstract description 17
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 13
- 239000001099 ammonium carbonate Substances 0.000 claims abstract description 10
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims abstract description 9
- 235000012501 ammonium carbonate Nutrition 0.000 claims abstract description 8
- 238000000354 decomposition reaction Methods 0.000 claims abstract description 6
- 239000011248 coating agent Substances 0.000 claims abstract description 4
- 238000000576 coating method Methods 0.000 claims abstract description 4
- 239000000243 solution Substances 0.000 claims description 25
- 239000011701 zinc Substances 0.000 claims description 20
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 17
- 229910052725 zinc Inorganic materials 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 15
- 239000002244 precipitate Substances 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 9
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 6
- NKCVNYJQLIWBHK-UHFFFAOYSA-N carbonodiperoxoic acid Chemical compound OOC(=O)OO NKCVNYJQLIWBHK-UHFFFAOYSA-N 0.000 claims description 6
- 238000001354 calcination Methods 0.000 claims description 5
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims description 2
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 2
- HNFCRGNWZSPZDU-UHFFFAOYSA-N zinc lead(2+) tetranitrate Chemical compound [N+](=O)([O-])[O-].[Pb+2].[Zn+2].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-] HNFCRGNWZSPZDU-UHFFFAOYSA-N 0.000 claims 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract description 17
- 238000006243 chemical reaction Methods 0.000 abstract description 15
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract description 10
- 239000011148 porous material Substances 0.000 abstract description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 4
- 239000001257 hydrogen Substances 0.000 abstract description 4
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 4
- 238000001556 precipitation Methods 0.000 abstract description 4
- 238000001914 filtration Methods 0.000 abstract description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical group O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract description 3
- JRBRVDCKNXZZGH-UHFFFAOYSA-N alumane;copper Chemical class [AlH3].[Cu] JRBRVDCKNXZZGH-UHFFFAOYSA-N 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract description 2
- 239000000047 product Substances 0.000 description 63
- 235000014692 zinc oxide Nutrition 0.000 description 40
- 239000007789 gas Substances 0.000 description 22
- 230000000694 effects Effects 0.000 description 21
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 13
- 239000000460 chlorine Substances 0.000 description 13
- 229910052801 chlorine Inorganic materials 0.000 description 13
- 238000012360 testing method Methods 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical class [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 6
- 239000008188 pellet Substances 0.000 description 6
- 231100000572 poisoning Toxicity 0.000 description 6
- 230000000607 poisoning effect Effects 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 4
- 230000001376 precipitating effect Effects 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 238000000975 co-precipitation Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 230000000977 initiatory effect Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 241000907663 Siproeta stelenes Species 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 230000008092 positive effect Effects 0.000 description 2
- 239000012495 reaction gas Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 241000566137 Sagittarius Species 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- PURJYVIHCDBIRA-UHFFFAOYSA-N [Cu]=O.[O-2].[Al+3].[O-2].[O-2].[Al+3] Chemical compound [Cu]=O.[O-2].[Al+3].[O-2].[O-2].[Al+3] PURJYVIHCDBIRA-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 159000000011 group IA salts Chemical class 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910052566 spinel group Inorganic materials 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/005—Spinels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Carbon And Carbon Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NO800905A NO146046C (no) | 1980-03-28 | 1980-03-28 | Katalysator og fremgangsmaate til dens fremstilling |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| HU188660B true HU188660B (en) | 1986-05-28 |
Family
ID=19885411
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HU81784A HU188660B (en) | 1980-03-28 | 1981-03-27 | Process for production of cathalizator containing cooper oxid and aluminium-oxid |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US4308176A (en:Method) |
| EP (1) | EP0042471B1 (en:Method) |
| JP (1) | JPS56158147A (en:Method) |
| AT (1) | ATE9876T1 (en:Method) |
| AU (1) | AU541472B2 (en:Method) |
| BR (1) | BR8101848A (en:Method) |
| CA (1) | CA1144911A (en:Method) |
| DD (1) | DD157669A5 (en:Method) |
| DE (1) | DE3166670D1 (en:Method) |
| DK (1) | DK155920C (en:Method) |
| EG (1) | EG15174A (en:Method) |
| ES (1) | ES8202492A1 (en:Method) |
| HU (1) | HU188660B (en:Method) |
| IN (1) | IN155595B (en:Method) |
| NO (2) | NO146046C (en:Method) |
| ZA (1) | ZA812077B (en:Method) |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2080136B (en) * | 1980-07-16 | 1984-05-16 | Dyson Refractories | Coprecipitated modified nickel catalysts |
| DE3027890A1 (de) * | 1980-07-23 | 1982-03-04 | Basf Ag, 6700 Ludwigshafen | Hydrierkatalysatoren fuer die herstellung von propandiolen und verfahren zur herstellung von propandiolen mit solchen katalysatoren |
| DE3317725A1 (de) * | 1983-05-16 | 1984-11-22 | Süd-Chemie AG, 8000 München | Katalysator fuer die methanolsynthese |
| US4565803A (en) * | 1983-12-16 | 1986-01-21 | Shell Oil Company | Methanol synthesis catalyst |
| NO154486C (no) * | 1984-04-12 | 1986-10-01 | Norsk Hydro As | Katalysator og dens anvendelse for spalting av metanol. |
| US4772750A (en) * | 1985-06-14 | 1988-09-20 | The Dow Chemical Company | Method of producing amines |
| US4728635A (en) * | 1986-04-07 | 1988-03-01 | Katalistiks International Inc. | Alkaline earth metal spinels and processes for making |
| DE3837308A1 (de) * | 1988-11-03 | 1990-05-10 | Basf Ag | Kupferhaltiger katalysator zur tieftemperaturkonvertierung |
| DE4419486C2 (de) * | 1994-06-03 | 1996-09-05 | Daimler Benz Ag | Katalysator, Verfahren zu dessen Herstellung sowie Verwendung des Katalysators |
| DE4420932A1 (de) * | 1994-06-16 | 1996-01-11 | Basf Ag | Material zur katalytischen Reduktion von Stickoxiden |
| DE69513792T2 (de) | 1995-01-11 | 2000-04-27 | United Catalysts Inc., Louisville | Aktivierter und stabilisierter Kupferoxid- und Zinkoxidkatalysator und Verfahren zu seiner Herstellung |
| DE19546481C2 (de) * | 1995-12-13 | 1998-08-13 | Daimler Benz Ag | Katalysator und Verfahren zu dessen Herstellung und Verwendung desselben |
| DE19546612A1 (de) * | 1995-12-13 | 1997-06-19 | Basf Ag | Verfahren zur Reduktion von NOx aus Abgasen |
| DE19546476A1 (de) * | 1995-12-13 | 1997-06-19 | Daimler Benz Ag | Katalysator, Verfahren zu dessen Herstellung und Verwendung desselben |
| JP4183752B2 (ja) * | 1996-03-21 | 2008-11-19 | エンゲルハルト コーポレイション | Ｃｕ／Ｃｒ触媒の用途に用いられるクロム不含触媒の調製と使用 |
| DE19848595A1 (de) * | 1998-10-21 | 2000-04-27 | Basf Ag | Hochtemperaturstabile Katalysatoren zur Zersetzung von N¶2¶0 |
| US6306795B1 (en) | 1999-09-07 | 2001-10-23 | Cytec Technology Corp. | Stable highly active supported copper based catalysts |
| DE19950325A1 (de) * | 1999-10-19 | 2001-04-26 | Basf Ag | Spinellmonolith-Katalysator und Verfahren zu seiner Herstellung |
| DK1298089T3 (da) * | 2000-06-22 | 2005-03-21 | Consejo Superior Investigacion | Fremgangsmåde til fremstilling af hydrogen ved delvis methanoloxidering |
| US6455182B1 (en) * | 2001-05-09 | 2002-09-24 | Utc Fuel Cells, Llc | Shift converter having an improved catalyst composition, and method for its use |
| US6821494B2 (en) * | 2001-07-31 | 2004-11-23 | Utc Fuel Cells, Llc | Oxygen-assisted water gas shift reactor having a supported catalyst, and method for its use |
| US6693057B1 (en) | 2002-03-22 | 2004-02-17 | Sud-Chemie Inc. | Water gas shift catalyst |
| US20030186805A1 (en) * | 2002-03-28 | 2003-10-02 | Vanderspurt Thomas Henry | Ceria-based mixed-metal oxide structure, including method of making and use |
| US20040082669A1 (en) * | 2002-10-28 | 2004-04-29 | Ruettinger Wolfgang Friedrich | Operating conditions for copper-based water-gas shift catalysts |
| US6903050B2 (en) * | 2002-10-28 | 2005-06-07 | Engelhard Corporation | Method of preparation of non-pyrophoric copper-alumina catalysts |
| US6932848B2 (en) * | 2003-03-28 | 2005-08-23 | Utc Fuel Cells, Llc | High performance fuel processing system for fuel cell power plant |
| JP4774197B2 (ja) * | 2003-05-20 | 2011-09-14 | 出光興産株式会社 | 酸素含有炭化水素の改質触媒、それを用いた水素又は合成ガスの製造方法及び燃料電池システム |
| DE10357716A1 (de) * | 2003-12-09 | 2005-07-14 | Basf Ag | Verbesserter Katalysator für die Hydrierung von Maleinsäureanhydrid zu γ-Butyrolacton und Tetrahydrofuran |
| GB2410449B (en) * | 2004-01-28 | 2008-05-21 | Statoil Asa | Fischer-Tropsch catalysts |
| CN1311904C (zh) * | 2004-12-21 | 2007-04-25 | 中国科学院广州能源研究所 | 合成甲醇催化剂的制备方法 |
| US8507404B2 (en) | 2005-07-12 | 2013-08-13 | Exxonmobil Research And Engineering Company | Regenerable sulfur traps for on-board vehicle applications |
| KR20070019428A (ko) * | 2005-08-12 | 2007-02-15 | 에스케이 주식회사 | 유기황화합물 제거용 탈황제, 이의 제조방법 및 이를이용한 유기황화합물의 제거방법 |
| DE102005049135A1 (de) * | 2005-10-14 | 2007-04-19 | Basf Ag | Verfahren zur Hydrierung von Carbonylverbindungen |
| JP2010005498A (ja) * | 2008-06-24 | 2010-01-14 | Mitsubishi Heavy Ind Ltd | 燃料電池のｄｓｓ運転用のｃｏ変成触媒、その製造方法及び燃料電池システム |
| EP2272587A1 (en) * | 2009-06-26 | 2011-01-12 | Bayer MaterialScience AG | Catalyst for chlorine production comprising a copper aluminate of the spinel type |
| GB2473071B (en) | 2009-09-01 | 2013-09-11 | Gtl F1 Ag | Fischer-tropsch catalysts |
| GB2475492B (en) | 2009-11-18 | 2014-12-31 | Gtl F1 Ag | Fischer-Tropsch synthesis |
| US9242229B2 (en) | 2010-08-09 | 2016-01-26 | Gtl.F1 Ag | Fischer-tropsch catalysts |
| BR112019018144A2 (pt) * | 2017-03-06 | 2020-04-07 | Basf Corp | composições de catalisação, artigo, método de tratamento de uma corrente de escape, sistema de tratamento de emissões e método para preparar uma composição |
| US10998553B1 (en) | 2019-10-31 | 2021-05-04 | EnPower, Inc. | Electrochemical cell with integrated ceramic separator |
| DE102020106964A1 (de) * | 2020-03-13 | 2021-09-16 | Clariant International Ltd | Chromfreier hydrierkatalysator mit erhoehter wasser- und saeurestabilitaet |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3303001A (en) * | 1963-12-16 | 1967-02-07 | Catalysts & Chem Inc | Low temperature shift reaction involving a zinc oxide-copper catalyst |
| GB1131631A (en) * | 1965-01-05 | 1968-10-23 | Ici Ltd | Catalysts of high activity at low temperature |
| DE1542044C3 (de) * | 1965-10-19 | 1980-03-27 | Catalysts And Chemicals Inc., Louisville, Ky. (V.St.A.) | Katalysator, der nach Reduktion als aktive Bestandteile Zinkoxid und Kupfer enthält |
| US3388972A (en) * | 1966-12-14 | 1968-06-18 | Catalysts & Chemicals Inc | Low temperature shift reaction catalysts and methods for their preparation |
| GB1262299A (en) * | 1968-02-08 | 1972-02-02 | Chemetron Corp | Production of low-temperature water-gas shift catalyst |
| GB1296212A (en:Method) * | 1969-03-04 | 1972-11-15 | ||
| FR2054524A1 (en:Method) * | 1969-07-25 | 1971-04-23 | Inst Francais Du Petrole | |
| GB1405012A (en) * | 1972-01-21 | 1975-09-03 | Ici Ltd | Method of making composition convertible to a catalyst precursor and catalyst and methanol synthesis using the catalyst |
| JPS5263192A (en) * | 1975-11-20 | 1977-05-25 | Toyota Motor Corp | Method of producing catalyst carrier |
| US4199479A (en) * | 1978-02-24 | 1980-04-22 | Chevron Research Company | Hydrogenation catalyst |
-
0
- NO NO146046D patent/NO146046L/no unknown
-
1980
- 1980-03-28 NO NO800905A patent/NO146046C/no unknown
- 1980-08-29 US US06/182,615 patent/US4308176A/en not_active Expired - Lifetime
-
1981
- 1981-03-18 IN IN150/DEL/81A patent/IN155595B/en unknown
- 1981-03-19 EP EP81102072A patent/EP0042471B1/en not_active Expired
- 1981-03-19 AT AT81102072T patent/ATE9876T1/de active
- 1981-03-19 DE DE8181102072T patent/DE3166670D1/de not_active Expired
- 1981-03-20 AU AU68603/81A patent/AU541472B2/en not_active Ceased
- 1981-03-27 HU HU81784A patent/HU188660B/hu not_active IP Right Cessation
- 1981-03-27 ZA ZA00812077A patent/ZA812077B/xx unknown
- 1981-03-27 DK DK139481A patent/DK155920C/da not_active IP Right Cessation
- 1981-03-27 ES ES500771A patent/ES8202492A1/es not_active Expired
- 1981-03-27 JP JP4425581A patent/JPS56158147A/ja active Granted
- 1981-03-27 BR BR8101848A patent/BR8101848A/pt unknown
- 1981-03-27 DD DD81228662A patent/DD157669A5/de not_active IP Right Cessation
- 1981-03-27 CA CA000373996A patent/CA1144911A/en not_active Expired
- 1981-03-28 EG EG169/81A patent/EG15174A/xx active
Also Published As
| Publication number | Publication date |
|---|---|
| DE3166670D1 (en) | 1984-11-22 |
| ES500771A0 (es) | 1982-02-01 |
| DD157669A5 (de) | 1982-12-01 |
| ATE9876T1 (de) | 1984-11-15 |
| NO146046L (en:Method) | |
| DK139481A (da) | 1981-09-29 |
| NO800905L (no) | 1981-09-29 |
| DK155920B (da) | 1989-06-05 |
| DK155920C (da) | 1989-10-30 |
| BR8101848A (pt) | 1981-09-29 |
| AU541472B2 (en) | 1985-01-10 |
| JPS6354420B2 (en:Method) | 1988-10-27 |
| NO146046B (no) | 1982-04-13 |
| US4308176A (en) | 1981-12-29 |
| NO146046C (no) | 1982-07-21 |
| IN155595B (en:Method) | 1985-02-16 |
| EP0042471A1 (en) | 1981-12-30 |
| JPS56158147A (en) | 1981-12-05 |
| ZA812077B (en) | 1982-04-28 |
| EG15174A (en) | 1985-12-31 |
| EP0042471B1 (en) | 1984-10-17 |
| ES8202492A1 (es) | 1982-02-01 |
| AU6860381A (en) | 1981-10-01 |
| CA1144911A (en) | 1983-04-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| HU90 | Patent valid on 900628 | ||
| HMM4 | Cancellation of final prot. due to non-payment of fee |