HRP20220830T1 - Kompozitni materijali koji sadrže mehaničke ligande - Google Patents

Kompozitni materijali koji sadrže mehaničke ligande Download PDF

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HRP20220830T1
HRP20220830T1 HRP20220830TT HRP20220830T HRP20220830T1 HR P20220830 T1 HRP20220830 T1 HR P20220830T1 HR P20220830T T HRP20220830T T HR P20220830TT HR P20220830 T HRP20220830 T HR P20220830T HR P20220830 T1 HRP20220830 T1 HR P20220830T1
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Croatia
Prior art keywords
cmu
composite material
per cubic
ligand2
cubic millimeter
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HRP20220830TT
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English (en)
Inventor
Henrik Pedersen
Mikkel Dybro Lundorf
Tore DEHLI
Christian Benedikt Orea Nielsen
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Nanocore Aps
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Publication of HRP20220830T1 publication Critical patent/HRP20220830T1/hr

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Claims (24)

1. Jedinica kompozitnog materijala (CMU) sa strukturom (SE1-ML-LinkerL-Ligand2-SE2), naznačena time što ML je mehanički ligand, kemijski entitet koji tvori mehaničku vezu sa strukturnim entitetom SE1, gdje ML nije nanocijev, LinkerL je kemijska veza ili entitet koji kovalentno povezuje ML i Ligand2, Ligand2 je kemijski entitet kovalentno vezan na strukturni entitet SE2, ili tvori mehaničku vezu sa strukturnim entitetom SE2, i SE1 i SE2 su strukturni entiteti gdje je SE1 ugljična nanocijev, a ML je kovalentno zatvoreni prsten oko navedene ugljične nanocijevi, te gdje je strukturni entitet SE2 polimer ili je strukturni entitet SE2 ugljična nanocijev.
2. Jedinica kompozitnog materijala (CMU) u skladu s bilo kojim od patentnih zahtjeva 1, naznačena time što se strukturni entitet SE2 bira s popisa kojeg čine epoksi, polibenzimidazol, polietilen, polikarbonat, polietilen-tereftalat, polipropilen, poliester, polistiren, poliolefin, polivinil-klorid, vinilni ester, poliamid, polieterketonketon, poli(metil-metakrilat), poli(metil-metakrilat), poliamidimid, poliariletereterketon, polieterimid, poliimid, polioksimetilen, polifenilen-sulfid, politetrafluoretilen, najlon, te akrilonitril-butadien-stiren.
3. Jedinica kompozitnog materijala (CMU) u skladu s bilo kojim od patentnih zahtjeva 1-2, naznačena time što je strukturni entitet SE2 vezan s mehaničkim ligandom.
4. Jedinica kompozitnog materijala (CMU) u skladu s bilo kojim od patentnih zahtjeva 1-3, naznačena time što ML sadrži pirenski motiv, nitrobenzenski motiv, fenantrenski motiv, naftalenski motiv i/ili tetratiafulvalenski motiv.
5. Jedinica kompozitnog materijala (CMU) u skladu s bilo kojim od patentnih zahtjeva 1-4, naznačena time što ML sadrži kemijski ostatak od više od 50 Da, primjerice više od 100 Da, primjerice više od 200 Da, primjerice više od 300 Da, primjerice više od 400 Da, primjerice više od 500 Da, koji je istovjetan dijelu strukturnog entiteta SE2.
6. Jedinica kompozitnog materijala (CMU) u skladu s bilo kojim od patentnih zahtjeva 1-5, naznačena time što je strukturni entitet SE1 ugljična nanocijev s jednom stijenkom (SWNT) ili (MWNT) ugljična nanocijev s više stijenki.
7. Jedinica kompozitnog materijala (CMU) u skladu s bilo kojim od patentnih zahtjeva 1-6, naznačena time što ML ima molekulsku težinu (MW) od 100-200 Da, ili 200-300 Da, ili 300-500 Da, ili 500-800 Da, ili 800-1200 Da, ili 1200-2000 Da, ili 2000-4000 Da, ili 4000-10000 Da, gdje je navedena molekulska težina kombinirana molekulska težina atoma koji čine najkraći niz kovalentno vezanih atoma koji tvore prsten oko strukturnog entiteta SE1,
8. Jedinica kompozitnog materijala (CMU) u skladu s bilo kojim od patentnih zahtjeva 1-7, naznačena time što je najmanje 2 SE2, primjerice najmanje 5 SE2, primjerice najmanje 10 SE2, primjerice najmanje 50 SE2 vezano na isti SE1,
9. Jedinica kompozitnog materijala (CMU) u skladu s bilo kojim od patentnih zahtjeva 1-8, naznačena time što je najmanje 2 SE1, primjerice najmanje 5 SE1, primjerice najmanje 10 SE1, primjerice najmanje 50 SE1 vezano na isti SE2.
10. Jedinica kompozitnog materijala (CMU) u skladu s bilo kojim od patentnih zahtjeva 1-9, naznačena time što je strukturni entitet SE1 vezan s više od 1 mehaničkog liganda, primjerice s više od 2 mehanička liganda, primjerice s više od 5 mehaničkih liganada, primjerice s više od 10 mehaničkih liganada, primjerice s više od 30 mehaničkih liganada, primjerice s više od 100 mehaničkih liganada, primjerice s više od 300 mehaničkih liganada, primjerice s više od 500 mehaničkih liganada, primjerice s više od 1000 mehaničkih liganada.
11. Kompozitni materijal, naznačen time što sadrži najmanje 108 jedinica kompozitnog materijala (CMU), primjerice najmanje 109 CMU, primjerice najmanje 1010 CMU, primjerice najmanje 1011 CMU, primjerice najmanje 1012 CMU, primjerice najmanje 1013 CMU, primjerice najmanje 1014 CMU, primjerice najmanje 1015 CMU, primjerice najmanje 1016 CMU, primjerice najmanje 1017 CMU, primjerice najmanje 1018 CMU, primjerice najmanje 1019 CMU, primjerice najmanje 1020 CMU, primjerice najmanje 1021 CMU, primjerice najmanje 1022 CMU, gdje su navedene jedinice kompozitnog materijala (CMU) definirane kao u bilo kojem od patentnih zahtjeva 1-10,
12. Kompozitni materijal u skladu s patentnim zahtjevom 11, naznačen time što sadrži najmanje 104 CMU po kubičnom milimetru, primjerice najmanje 105 CMU po kubičnom milimetru, primjerice najmanje 106 CMU po kubičnom milimetru, primjerice najmanje 107 CMU po kubičnom milimetru, primjerice najmanje 108 CMU po kubičnom milimetru, primjerice najmanje 109 CMU po kubičnom milimetru, primjerice najmanje 1010 CMU po kubičnom milimetru, primjerice najmanje 1011 CMU po kubičnom milimetru, primjerice najmanje 1012 CMU po kubičnom milimetru, primjerice najmanje 1013 CMU po kubičnom milimetru, primjerice najmanje 1014 CMU po kubičnom milimetru, primjerice najmanje 1015 CMU po kubičnom milimetru, primjerice najmanje 1016 CMU po kubičnom milimetru, primjerice najmanje 1017 CMU po kubičnom milimetru, primjerice najmanje 1018 CMU po kubičnom milimetru, primjerice najmanje 1019 CMU po kubičnom milimetru navedenog kompozitnog materijala.
13. Kompozitni materijal u skladu s patentnim zahtjevom 11 ili 12, naznačen time što ima električnu vodljivost od najmanje 103 S/m, primjerice najmanje 104 S/m, primjerice najmanje 105 S/m, primjerice najmanje 106 S/m, primjerice najmanje 107 S/m, primjerice najmanje 108 S/m, primjerice najmanje 109 S/m.
14. Kompozitni materijal u skladu s bilo kojim od patentnih zahtjeva 11-13, naznačen time što ima torzijsku čvrstoću od najmanje 1 MPa, primjerice najmanje 10 MPa, primjerice najmanje 100 MPa, primjerice najmanje 100 MPa, primjerice najmanje 100 MPa, primjerice najmanje 300 MPa, primjerice najmanje 600 MPa, primjerice najmanje 900 MPa, primjerice najmanje 1200 MPa, primjerice najmanje 1500 MPa, primjerice najmanje 2000 MPa.
15. Kompozitni materijal u skladu s bilo kojim od patentnih zahtjeva 11-14, naznačen time što ima Youngov modul elastičnosti od najmanje 0,01 GPa, primjerice najmanje 0,1 GPa, primjerice najmanje 0,5 GPa, primjerice najmanje 1 GPa, primjerice najmanje 1,5 GPa, primjerice najmanje 2 GPa, primjerice najmanje 3 GPa.
16. Kompozitni materijal u skladu s bilo kojim od patentnih zahtjeva 11-15, naznačen time što sadrži silicijev dioksid, silikat, pijesak, aluminosilikate, kvarc ili kremen u koncentraciji od najmanje 0,01%, težinski, u kompozitnom materijalu.
17. Kompozitni materijal u skladu s bilo kojim od patentnih zahtjeva 11-16, naznačen time što je kompozitni materijal s keramičkom matricom ili kompozitni materijal s metalnom matricom.
18. Postupak dobivanja jedinice kompozitnog materijala (CMU) u skladu s bilo kojim od patentnih zahtjeva 1-9, naznačen time što se navedeni postupak sastoji u sljedećim koracima: a. osiguravanja prvog strukturnog entiteta (SE1) b. osiguravanja drugog strukturnog entiteta (SE2) c. osiguravanja spojnice, LinkerL d. osiguravanja preteče ML ili ML e. osiguravanja Liganda2 f. reakcija, bilo kojim redoslijedom, osiguranih strukturnih entiteta, spojnica i liganada, kako bi se dobilo jedinicu kompozitnog materijala (CMU) sa strukturom (SE1-ML-LinkerL-Ligand2-SE2), gdje su prvi strukturni entitet (SE1), drugi strukturni entitet (SE2), LinkerL, ML i Ligand2 definirani u patentnim zahtjevima 1-9.
19. Polimer ojačan ugljičnim nanocijevima (CNT), naznačen time što sadrži jednu ili više jedinica kompozitnog materijala u skladu s bilo kojim od patentnih zahtjeva 1-9.
20. CMU u skladu s bilo kojim od patentnih zahtjeva 1-9, naznačen time što je SE1 nanocijev s omjerom dimenzija od najmanje 100,
21. Polimerna struktura CMU, u strukturi (SE1-ML-Linker-Ligand2-SE2-Ligand2-Linker-ML-)n-SE1, naznačena time što su SE1, ML, Linker, Ligand2, SE2, Ligand2, Linker, ML i SE1 definirani u skladu s bilo kojim od patentnih zahtjeva 1-9, gdje je n bilo koji cijeli broj veći od jedan.
22. Polimerna struktura CMU u skladu s patentnim zahtjevom 21, naznačena time što je SE1 ugljična nanocijev, SE2 nije ugljična nanocijev, a n = 2, 3, 4 ili viši.
23. Polimerna struktura CMU u skladu s patentnim zahtjevom 21, naznačena time što je SE1 ugljična nanocijev, SE2 je druga ugljična nanocijev, a n = 2, 3, 4 ili viši.
24. Polimerna struktura CMU u skladu s patentnih zahtjeva 21-23, naznačena time što su svi SE1 u strukturi (SE1-ML-Linker-Ligand2-SE2-Ligand2-Linker-ML-)nSE1 odvojene i različite molekule i svi SE2 u strukturi (SE1-ML-Linker-Ligand2-SE2-Ligand2-Linker-ML-)nSE1 su odvojene i različite molekule.
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