HK1006555A1 - Method of molding of silicon-containing contact lenses - Google Patents
Method of molding of silicon-containing contact lensesInfo
- Publication number
- HK1006555A1 HK1006555A1 HK98105808A HK98105808A HK1006555A1 HK 1006555 A1 HK1006555 A1 HK 1006555A1 HK 98105808 A HK98105808 A HK 98105808A HK 98105808 A HK98105808 A HK 98105808A HK 1006555 A1 HK1006555 A1 HK 1006555A1
- Authority
- HK
- Hong Kong
- Prior art keywords
- contact lenses
- molding
- silicon
- containing contact
- monomers
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D11/00—Producing optical elements, e.g. lenses or prisms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D11/00—Producing optical elements, e.g. lenses or prisms
- B29D11/00009—Production of simple or compound lenses
- B29D11/00038—Production of contact lenses
- B29D11/00125—Auxiliary operations, e.g. removing oxygen from the mould, conveying moulds from a storage to the production line in an inert atmosphere
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/38—Moulds or cores; Details thereof or accessories therefor characterised by the material or the manufacturing process
- B29C33/40—Plastics, e.g. foam or rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/61—Polysiloxanes
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
- G02B1/043—Contact lenses
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2063/00—Use of EP, i.e. epoxy resins or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2833/00—Use of polymers of unsaturated acids or derivatives thereof as mould material
- B29K2833/18—Polymers of nitriles
- B29K2833/20—PAN, i.e. polyacrylonitrile
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0037—Other properties
- B29K2995/0093—Other properties hydrophobic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S425/00—Plastic article or earthenware shaping or treating: apparatus
- Y10S425/808—Lens mold
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Ophthalmology & Optometry (AREA)
- Medicinal Chemistry (AREA)
- Optics & Photonics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Physics & Mathematics (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Eyeglasses (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Polyurethanes Or Polyureas (AREA)
- Encapsulation Of And Coatings For Semiconductor Or Solid State Devices (AREA)
- Silicon Compounds (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/618,448 US5158717A (en) | 1990-11-27 | 1990-11-27 | Method of molding shaped polymeric articles |
PCT/US1991/008735 WO1992009421A2 (en) | 1990-11-27 | 1991-11-20 | Mold materials for silicone containing lens materials |
Publications (1)
Publication Number | Publication Date |
---|---|
HK1006555A1 true HK1006555A1 (en) | 1999-03-05 |
Family
ID=24477730
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
HK98105808A HK1006555A1 (en) | 1990-11-27 | 1998-06-19 | Method of molding of silicon-containing contact lenses |
Country Status (13)
Country | Link |
---|---|
US (1) | US5158717A (xx) |
EP (1) | EP0560916B1 (xx) |
JP (1) | JP3015103B2 (xx) |
KR (1) | KR100201528B1 (xx) |
CN (1) | CN1032909C (xx) |
AT (1) | ATE148655T1 (xx) |
BR (1) | BR9107093A (xx) |
CA (1) | CA2094920A1 (xx) |
DE (1) | DE69124625T2 (xx) |
ES (1) | ES2099819T3 (xx) |
HK (1) | HK1006555A1 (xx) |
IE (1) | IE914119A1 (xx) |
WO (1) | WO1992009421A2 (xx) |
Families Citing this family (58)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5723541A (en) * | 1993-06-16 | 1998-03-03 | Rasor Associates, Inc. | Ocular lens composition and method of formation |
US5502087A (en) * | 1993-06-23 | 1996-03-26 | Dentsply Research & Development Corp. | Dental composition, prosthesis, and method for making dental prosthesis |
AU692520B2 (en) | 1994-05-16 | 1998-06-11 | Dentsply Detrey G.M.B.H. | Method of making a dental prosthesis and curable system |
US7468398B2 (en) | 1994-09-06 | 2008-12-23 | Ciba Vision Corporation | Extended wear ophthalmic lens |
US5760100B1 (en) * | 1994-09-06 | 2000-11-14 | Ciba Vision Corp | Extended wear ophthalmic lens |
US5690865A (en) * | 1995-03-31 | 1997-11-25 | Johnson & Johnson Vision Products, Inc. | Mold material with additives |
US5849209A (en) * | 1995-03-31 | 1998-12-15 | Johnson & Johnson Vision Products, Inc. | Mold material made with additives |
TW585882B (en) * | 1995-04-04 | 2004-05-01 | Novartis Ag | A method of using a contact lens as an extended wear lens and a method of screening an ophthalmic lens for utility as an extended-wear lens |
DE69617637T2 (de) * | 1995-09-06 | 2002-07-18 | Menicon Co., Ltd. | Verfahren zur herstellung von kontaktlinsen und die so hergestellten kontaktlinsen |
CN1075439C (zh) * | 1997-03-25 | 2001-11-28 | 诺瓦提斯公司 | 模塑方法 |
US6020445A (en) * | 1997-10-09 | 2000-02-01 | Johnson & Johnson Vision Products, Inc. | Silicone hydrogel polymers |
US6822016B2 (en) | 2001-09-10 | 2004-11-23 | Johnson & Johnson Vision Care, Inc. | Biomedical devices containing internal wetting agents |
US6365082B1 (en) * | 1998-12-15 | 2002-04-02 | Ut-Battelle, Llc | Polymer gel molds |
US6638451B1 (en) * | 1999-08-31 | 2003-10-28 | Novartis Ag | Plastic casting molds |
US6488375B2 (en) | 1999-10-28 | 2002-12-03 | Ocular Sciences, Inc. | Tinted contact lens and method for making same |
US6880932B2 (en) | 1999-11-01 | 2005-04-19 | Praful Doshi | Tinted lenses and methods of manufacture |
DE60025539T2 (de) | 1999-11-01 | 2006-07-27 | Praful Poway Doshi | Getönte kontaktlinse aus kunststoff und verfahren zu deren herstellung |
US7048375B2 (en) | 1999-11-01 | 2006-05-23 | Praful Doshi | Tinted lenses and methods of manufacture |
US7267846B2 (en) | 1999-11-01 | 2007-09-11 | Praful Doshi | Tinted lenses and methods of manufacture |
DE60042841D1 (de) * | 1999-12-16 | 2009-10-08 | Asahikasei Aime Co Ltd | Zum tragen über lange zeiträume geeignete weiche kontaktlinsen |
EP1266246B1 (en) | 2000-03-24 | 2004-06-02 | Novartis AG | Crosslinkable or polymerizable prepolymers |
US6772988B2 (en) * | 2000-03-31 | 2004-08-10 | Bausch & Lomb Incorporated | Method and mold to control optical device polymerization |
JP4012680B2 (ja) * | 2000-10-26 | 2007-11-21 | 信越化学工業株式会社 | 有機ケイ素化合物 |
US6774178B2 (en) | 2001-01-05 | 2004-08-10 | Novartis Ag | Tinted, high Dk ophthalmic molding and a method for making same |
EP1245372B1 (en) * | 2001-03-26 | 2011-09-28 | Novartis AG | Mould and method for the production of ophthalmic lenses |
US6815074B2 (en) | 2001-05-30 | 2004-11-09 | Novartis Ag | Polymeric materials for making contact lenses |
JP2005504665A (ja) * | 2001-10-11 | 2005-02-17 | オキュラー サイエンシス インコーポレイテッド | 丸みのあるエッジ形態を備えたコンタクトレンズの注型方法 |
US6997693B2 (en) * | 2001-10-19 | 2006-02-14 | Novartis Ag | Casting mold half and casting mold for producing contact lenses |
US20030165015A1 (en) * | 2001-12-05 | 2003-09-04 | Ocular Sciences, Inc. | Coated contact lenses and methods for making same |
US9322958B2 (en) | 2004-08-27 | 2016-04-26 | Coopervision International Holding Company, Lp | Silicone hydrogel contact lenses |
US20060063852A1 (en) * | 2004-08-27 | 2006-03-23 | Asahikasei Aime Co. Ltd. | Silicone hydrogel contact lens |
JP2009521013A (ja) * | 2005-12-20 | 2009-05-28 | ジョンソン・アンド・ジョンソン・ビジョン・ケア・インコーポレイテッド | アルコール溶液を用いて、シリコーンヒドロゲルの眼科用レンズを浸出させ、かつ、離型させるための方法およびシステム |
US8944804B2 (en) * | 2006-01-04 | 2015-02-03 | Liquidia Technologies, Inc. | Nanostructured surfaces for biomedical/biomaterial applications and processes thereof |
KR100741611B1 (ko) | 2006-06-21 | 2007-07-23 | 성아영 | 실리콘을 포함하는 우레탄 친수성 콘택트렌즈 및 그제조방법 |
DE102006052342B4 (de) * | 2006-11-07 | 2015-08-20 | Wöhlk-Contact-Linsen GmbH | Kontaktlinsenmaterial |
JP5669396B2 (ja) | 2006-12-13 | 2015-02-12 | ノバルティス アーゲー | 化学線硬化性シリコーンヒドロゲルコポリマーおよびその使用 |
CN101641206B (zh) | 2007-03-22 | 2013-03-20 | 诺瓦提斯公司 | 具有含悬挂的聚硅氧烷的聚合物链的预聚物 |
AU2008228761B2 (en) | 2007-03-22 | 2011-11-24 | Novartis Ag | Silicone-containing prepolymers with hydrophilic polymeric chains |
JP5508261B2 (ja) * | 2007-07-10 | 2014-05-28 | ボーシュ アンド ローム インコーポレイティド | 架橋剤及び二重ラジカル硬化ポリマー |
US8044111B2 (en) | 2007-11-30 | 2011-10-25 | Novartis Ag | Actinically-crosslinkable silicone-containing block copolymers |
US20090146329A1 (en) * | 2007-12-06 | 2009-06-11 | Changhong Yin | Lens release |
US8506856B2 (en) | 2007-12-10 | 2013-08-13 | Novartis Ag | Method for making silicone hydrogel contact lenses |
US8470906B2 (en) * | 2008-09-30 | 2013-06-25 | Johnson & Johnson Vision Care, Inc. | Ionic silicone hydrogels having improved hydrolytic stability |
TWI509312B (zh) * | 2009-10-01 | 2015-11-21 | Coopervision Int Holding Co Lp | 聚矽氧水凝膠隱形眼鏡及製造聚矽氧水凝膠隱形眼鏡的方法 |
WO2012006485A2 (en) * | 2010-07-09 | 2012-01-12 | Lee Darren Norris | Polar thermoplastic opthalmic lens molds, opthalmic lenses molded therein, and related methods |
TWI573818B (zh) | 2010-07-30 | 2017-03-11 | 諾華公司 | 兩親性聚矽氧烷預聚物及其用途 |
HUE030514T2 (en) | 2010-07-30 | 2017-05-29 | Coopervision Int Holding Co Lp | Ophthalmic lens molds, molded ophthalmic lenses and associated procedures |
HUE044765T2 (hu) | 2010-10-06 | 2019-11-28 | Novartis Ag | Polimerizálható hosszabbított láncú polisziloxánok hidrofil oldalcsoportokkal |
WO2012118673A2 (en) | 2011-02-28 | 2012-09-07 | Coopervision International Holding Company, Lp | Dimensionally stable silicone hydrogel contact lenses |
CN103415789B (zh) | 2011-02-28 | 2017-07-11 | 库柏维景国际控股公司 | 含膦水凝胶隐形眼镜 |
CN103827175B (zh) | 2011-02-28 | 2016-08-10 | 库柏维景国际控股公司 | 硅酮水凝胶隐形眼镜 |
KR101742352B1 (ko) | 2011-02-28 | 2017-05-31 | 쿠퍼비젼 인터내셔날 홀딩 캄파니, 엘피 | 실리콘 히드로겔 콘택트 렌즈 |
SG192236A1 (en) | 2011-02-28 | 2013-09-30 | Coopervision Int Holding Co Lp | Wettable silicone hydrogel contact lenses |
EP2681120B1 (en) | 2011-02-28 | 2018-10-31 | CooperVision International Holding Company, LP | Silicone hydrogel contact lenses and related compositions and methods |
TWI506334B (zh) | 2011-02-28 | 2015-11-01 | Coopervision Int Holding Co Lp | 具有可接受程度之能量損失的聚矽氧水凝膠隱形眼鏡 |
KR101369381B1 (ko) * | 2011-11-04 | 2014-03-06 | 에스케이이노베이션 주식회사 | 함불소 화합물을 포함하는 저굴절 코팅 조성물, 이를 이용한 반사방지 필름, 이를 포함하는 편광판 및 표시장치 |
US10422927B2 (en) * | 2016-07-14 | 2019-09-24 | Coopervision International Holding Company, Lp | Method of manufacturing silicone hydrogel contact lenses having reduced rates of evaporation |
CN114853955A (zh) * | 2022-05-31 | 2022-08-05 | 爱生华(苏州)光学有限公司 | 一种高透氧超柔软的硅水凝胶日抛透片的制备方法 |
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US2976576A (en) * | 1956-04-24 | 1961-03-28 | Wichterle Otto | Process for producing shaped articles from three-dimensional hydrophilic high polymers |
US3220960A (en) * | 1960-12-21 | 1965-11-30 | Wichterle Otto | Cross-linked hydrophilic polymers and articles made therefrom |
NL128305C (xx) * | 1963-09-11 | |||
AT251910B (de) * | 1964-07-02 | 1967-01-25 | Ceskoslovenska Akademie Ved | Verfahren zur Herstellung von weichen, biegsamen Kontaktlinsen |
US3426102A (en) * | 1965-08-18 | 1969-02-04 | Standard Oil Co | Polymerizates of olefinic nitriles and diene-nitrile rubbers |
US3428043A (en) * | 1966-06-09 | 1969-02-18 | Nat Patent Dev Corp | Bandage containing absorbed therapeutic materials |
US3520949A (en) * | 1966-07-26 | 1970-07-21 | Nat Patent Dev Corp | Hydrophilic polymers,articles and methods of making same |
US3679504A (en) * | 1968-04-05 | 1972-07-25 | Ceskoslovenska Akademie Ved | Method of forming color effects in hydrogel contact lenses and ophthalmic prostheses |
US3830460A (en) * | 1969-07-15 | 1974-08-20 | Beattie Dev Co | Polymeric replica molds and replication processes for producing plastic optical components |
US3618231A (en) * | 1970-06-03 | 1971-11-09 | Helen G Nason | Educational game |
US3931373A (en) * | 1971-12-21 | 1976-01-06 | J. O. Beattie Research Company | Replication processes for producing plastic optical components |
US3871803A (en) * | 1971-12-21 | 1975-03-18 | Beattie Dev Company | Apparatus for producing an optical molding plaque |
US4197266A (en) * | 1974-05-06 | 1980-04-08 | Bausch & Lomb Incorporated | Method for forming optical lenses |
US4113224A (en) * | 1975-04-08 | 1978-09-12 | Bausch & Lomb Incorporated | Apparatus for forming optical lenses |
US4245069A (en) * | 1978-12-28 | 1981-01-13 | Permavision | Polysiloxane composition |
US4136250A (en) * | 1977-07-20 | 1979-01-23 | Ciba-Geigy Corporation | Polysiloxane hydrogels |
US4153641A (en) * | 1977-07-25 | 1979-05-08 | Bausch & Lomb Incorporated | Polysiloxane composition and contact lens |
US4189546A (en) * | 1977-07-25 | 1980-02-19 | Bausch & Lomb Incorporated | Polysiloxane shaped article for use in biomedical applications |
US4555372A (en) * | 1981-03-23 | 1985-11-26 | Bausch & Lomb Incorporated | Rotational molding of contact lenses |
US4424328A (en) * | 1981-12-04 | 1984-01-03 | Polymer Technology Corporation | Silicone-containing contact lens material and contact lenses made thereof |
US4463149A (en) * | 1982-03-29 | 1984-07-31 | Polymer Technology Corporation | Silicone-containing contact lens material and contact lenses made thereof |
JPS59111102A (ja) * | 1982-12-16 | 1984-06-27 | Nippon Denso Co Ltd | 防眩型反射鏡 |
US4652622A (en) * | 1983-04-29 | 1987-03-24 | Bausch & Lomb Incorporated | Polysiloxane composition with improved surface wetting characteristics and biomedical devices made thereof |
US4711943A (en) * | 1985-04-26 | 1987-12-08 | Sola U.S.A. Inc. | Hydrophilic siloxane monomers and dimers for contact lens materials, and contact lenses fabricated therefrom |
US4686267A (en) * | 1985-10-11 | 1987-08-11 | Polymer Technology Corporation | Fluorine containing polymeric compositions useful in contact lenses |
US4740533A (en) * | 1987-07-28 | 1988-04-26 | Ciba-Geigy Corporation | Wettable, flexible, oxygen permeable, substantially non-swellable contact lens containing block copolymer polysiloxane-polyoxyalkylene backbone units, and use thereof |
US4810764A (en) * | 1988-02-09 | 1989-03-07 | Bausch & Lomb Incorporated | Polymeric materials with high oxygen permeability and low protein substantivity |
US4921205A (en) * | 1988-05-17 | 1990-05-01 | Sola Usa, Inc. | Lens mold assembly |
-
1990
- 1990-11-27 US US07/618,448 patent/US5158717A/en not_active Expired - Lifetime
-
1991
- 1991-11-20 KR KR1019930701541A patent/KR100201528B1/ko not_active IP Right Cessation
- 1991-11-20 DE DE69124625T patent/DE69124625T2/de not_active Expired - Fee Related
- 1991-11-20 BR BR9107093A patent/BR9107093A/pt not_active IP Right Cessation
- 1991-11-20 CA CA002094920A patent/CA2094920A1/en not_active Abandoned
- 1991-11-20 JP JP4502643A patent/JP3015103B2/ja not_active Expired - Lifetime
- 1991-11-20 EP EP92902321A patent/EP0560916B1/en not_active Expired - Lifetime
- 1991-11-20 ES ES92902321T patent/ES2099819T3/es not_active Expired - Lifetime
- 1991-11-20 WO PCT/US1991/008735 patent/WO1992009421A2/en active IP Right Grant
- 1991-11-20 AT AT92902321T patent/ATE148655T1/de not_active IP Right Cessation
- 1991-11-26 IE IE411991A patent/IE914119A1/en not_active IP Right Cessation
- 1991-11-27 CN CN91111174A patent/CN1032909C/zh not_active Expired - Fee Related
-
1998
- 1998-06-19 HK HK98105808A patent/HK1006555A1/xx not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
ATE148655T1 (de) | 1997-02-15 |
WO1992009421A3 (en) | 1992-07-09 |
EP0560916A1 (en) | 1993-09-22 |
ES2099819T3 (es) | 1997-06-01 |
WO1992009421A2 (en) | 1992-06-11 |
EP0560916B1 (en) | 1997-02-05 |
IE914119A1 (en) | 1992-06-03 |
JPH06503276A (ja) | 1994-04-14 |
JP3015103B2 (ja) | 2000-03-06 |
BR9107093A (pt) | 1994-04-19 |
DE69124625T2 (de) | 1997-09-25 |
CN1061931A (zh) | 1992-06-17 |
US5158717A (en) | 1992-10-27 |
CN1032909C (zh) | 1996-10-02 |
KR100201528B1 (ko) | 1999-06-15 |
KR930703141A (ko) | 1993-11-29 |
CA2094920A1 (en) | 1992-05-28 |
DE69124625D1 (de) | 1997-03-20 |
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