GB2006225A - Method for Reducing the Monomer Content in Styrene and acrylonitrile - Google Patents
Method for Reducing the Monomer Content in Styrene and acrylonitrileInfo
- Publication number
- GB2006225A GB2006225A GB7839778A GB7839777A GB2006225A GB 2006225 A GB2006225 A GB 2006225A GB 7839778 A GB7839778 A GB 7839778A GB 7839777 A GB7839777 A GB 7839777A GB 2006225 A GB2006225 A GB 2006225A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acrylonitrile
- monomer content
- styrene
- reducing
- pellets
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 title abstract 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title abstract 3
- 239000000178 monomer Substances 0.000 title abstract 2
- 239000008188 pellet Substances 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 1
- 230000005865 ionizing radiation Effects 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/006—Removal of residual monomers by chemical reaction, e.g. scavenging
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/16—Auxiliary treatment of granules
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C71/00—After-treatment of articles without altering their shape; Apparatus therefor
- B29C71/04—After-treatment of articles without altering their shape; Apparatus therefor by wave energy or particle radiation, e.g. for curing or vulcanising preformed articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
- B29C35/0866—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using particle radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
- B29K2033/18—Polymers of nitriles
- B29K2033/20—PAN, i.e. polyacrylonitrile
Abstract
The monomer content in acrylonitrile containing polymers, as for example bottles formed from acrylonitrile/styrene copolymer, is substantially reduced by applying ionizing radiation in low dosage levels e.g. 0.05-2.0 megarad to the completely or partially formed article, the pellets from which the articles are molded or the ground resin from which the pellets are formed, or to polymer in solution or suspension.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US84041577A | 1977-10-07 | 1977-10-07 |
Publications (2)
Publication Number | Publication Date |
---|---|
GB2006225A true GB2006225A (en) | 1979-05-02 |
GB2006225B GB2006225B (en) | 1982-04-15 |
Family
ID=25282319
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB7839778A Expired GB2006225B (en) | 1977-10-07 | 1978-10-09 | Method of reducing the monomer content in styrene and acrylonitrile |
Country Status (14)
Country | Link |
---|---|
JP (1) | JPS5470391A (en) |
AT (1) | AT370745B (en) |
AU (1) | AU529029B2 (en) |
BE (1) | BE871066A (en) |
CA (1) | CA1106311A (en) |
CH (1) | CH641192A5 (en) |
DE (1) | DE2843292A1 (en) |
DK (1) | DK159927C (en) |
ES (1) | ES474011A1 (en) |
FR (1) | FR2405267B1 (en) |
GB (1) | GB2006225B (en) |
NL (1) | NL186071C (en) |
NO (1) | NO155293C (en) |
SE (1) | SE428568B (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4826889A (en) * | 1978-07-18 | 1989-05-02 | Polymer Technology, Corp. | Dimensionally stable oxygen permeable hard contact lens material and method of manufacture |
EP0333401A2 (en) * | 1988-03-15 | 1989-09-20 | Japan Atomic Energy Research Institute | Process for forming container of acrylonitrile polymers by biaxial-orientation blow-moulding preform |
GB2222603B (en) * | 1988-06-27 | 1992-09-23 | Plasmon Data Systems Inc | Improvements relating to optical disks |
GB2267907A (en) * | 1991-10-11 | 1993-12-22 | Ishida Kooki Seisakusho Kabush | Lens-forming resin and spectacle lens made thereof |
CN113789018A (en) * | 2021-01-28 | 2021-12-14 | 海信容声(广东)冰箱有限公司 | SAN material for refrigerator transparent part, preparation method of SAN material and refrigerator transparent part |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4174043A (en) * | 1977-11-10 | 1979-11-13 | Monsanto Company | Nitrile preforms and containers and process improvements for forming same |
JPS54135888A (en) * | 1978-04-03 | 1979-10-22 | Dow Chemical Co | Method of decreasing residual acrylonitrile in resin |
US4511711A (en) * | 1982-02-10 | 1985-04-16 | Sumitomo Chemical Company, Limited | Process for producing semipermeable membrane |
BE897798A (en) * | 1982-09-24 | 1984-03-21 | Cosden Technology | PROCESS AND APPARATUS FOR THE PRODUCTION OF COPOLYMERS OF STYRENIC COMPOUNDS AND ALCENYLNITRIL COMPOUNDS |
JPH05127424A (en) * | 1991-10-31 | 1993-05-25 | Tomoegawa Paper Co Ltd | Production of toner |
JPH05142860A (en) * | 1991-11-21 | 1993-06-11 | Tomoegawa Paper Co Ltd | Manufacture of toner |
JPH0714966B2 (en) * | 1992-04-20 | 1995-02-22 | 工業技術院長 | Method for reducing unreacted residual monomer in polymer |
WO2023166120A1 (en) | 2022-03-03 | 2023-09-07 | Ineos Styrolution Group Gmbh | Continuous method of manufacturing acrylonitrile-containing copolymers with reduced content of propionitrile |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB867646A (en) * | 1957-05-14 | 1961-05-10 | Ti Group Services Ltd | Improvements relating to the manufacture of plastics |
GB1279108A (en) * | 1968-12-06 | 1972-06-28 | Atlas Chem Ind | Water-soluble nitrogen-containing vinyl polymers of high molecular weight |
JPS5169587A (en) * | 1974-12-13 | 1976-06-16 | Tetsukosha Kk | Jugotaichuno zanzonenkabinirutanryotaijokyohoho |
JPS605603B2 (en) * | 1976-10-28 | 1985-02-13 | 積水化学工業株式会社 | Method for removing residual vinyl chloride monomer |
-
1978
- 1978-10-03 DK DK437678A patent/DK159927C/en not_active IP Right Cessation
- 1978-10-04 NL NLAANVRAGE7810031,A patent/NL186071C/en not_active IP Right Cessation
- 1978-10-04 SE SE7810395A patent/SE428568B/en not_active IP Right Cessation
- 1978-10-04 DE DE19782843292 patent/DE2843292A1/en active Granted
- 1978-10-04 AT AT0715678A patent/AT370745B/en not_active IP Right Cessation
- 1978-10-06 ES ES474011A patent/ES474011A1/en not_active Expired
- 1978-10-06 BE BE78190954A patent/BE871066A/en not_active IP Right Cessation
- 1978-10-06 NO NO783391A patent/NO155293C/en unknown
- 1978-10-06 FR FR787828674A patent/FR2405267B1/en not_active Expired
- 1978-10-06 CA CA312,888A patent/CA1106311A/en not_active Expired
- 1978-10-06 JP JP12275678A patent/JPS5470391A/en active Granted
- 1978-10-06 CH CH1038178A patent/CH641192A5/en not_active IP Right Cessation
- 1978-10-09 AU AU40528/78A patent/AU529029B2/en not_active Expired
- 1978-10-09 GB GB7839778A patent/GB2006225B/en not_active Expired
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4826889A (en) * | 1978-07-18 | 1989-05-02 | Polymer Technology, Corp. | Dimensionally stable oxygen permeable hard contact lens material and method of manufacture |
EP0333401A2 (en) * | 1988-03-15 | 1989-09-20 | Japan Atomic Energy Research Institute | Process for forming container of acrylonitrile polymers by biaxial-orientation blow-moulding preform |
EP0333401A3 (en) * | 1988-03-15 | 1991-08-07 | Japan Atomic Energy Research Institute | Process for forming container of acrylonitrile polymers by biaxial-orientation blow-moulding preform |
GB2222603B (en) * | 1988-06-27 | 1992-09-23 | Plasmon Data Systems Inc | Improvements relating to optical disks |
GB2267907A (en) * | 1991-10-11 | 1993-12-22 | Ishida Kooki Seisakusho Kabush | Lens-forming resin and spectacle lens made thereof |
CN113789018A (en) * | 2021-01-28 | 2021-12-14 | 海信容声(广东)冰箱有限公司 | SAN material for refrigerator transparent part, preparation method of SAN material and refrigerator transparent part |
Also Published As
Publication number | Publication date |
---|---|
DE2843292A1 (en) | 1979-04-12 |
SE428568B (en) | 1983-07-11 |
NO155293B (en) | 1986-12-01 |
ATA715678A (en) | 1982-09-15 |
FR2405267A1 (en) | 1979-05-04 |
NL186071C (en) | 1990-09-17 |
DK159927C (en) | 1991-05-21 |
AU529029B2 (en) | 1983-05-26 |
CA1106311A (en) | 1981-08-04 |
NO155293C (en) | 1987-03-11 |
NL186071B (en) | 1990-04-17 |
AT370745B (en) | 1983-04-25 |
DK437678A (en) | 1979-04-08 |
SE7810395L (en) | 1979-04-08 |
AU4052878A (en) | 1980-04-17 |
BE871066A (en) | 1979-02-01 |
JPS5470391A (en) | 1979-06-06 |
NO783391L (en) | 1979-04-10 |
GB2006225B (en) | 1982-04-15 |
NL7810031A (en) | 1979-04-10 |
FR2405267B1 (en) | 1985-07-26 |
DE2843292C2 (en) | 1988-03-31 |
ES474011A1 (en) | 1979-05-01 |
CH641192A5 (en) | 1984-02-15 |
DK159927B (en) | 1990-12-31 |
JPS5654321B2 (en) | 1981-12-24 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
732 | Registration of transactions, instruments or events in the register (sect. 32/1977) | ||
PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 19961009 |