GB988473A - Polymeric compositions - Google Patents

Polymeric compositions

Info

Publication number
GB988473A
GB988473A GB15714/62A GB1571462A GB988473A GB 988473 A GB988473 A GB 988473A GB 15714/62 A GB15714/62 A GB 15714/62A GB 1571462 A GB1571462 A GB 1571462A GB 988473 A GB988473 A GB 988473A
Authority
GB
United Kingdom
Prior art keywords
ethyl
vinylidene
acrylate
poly
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB15714/62A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US107342A external-priority patent/US3256231A/en
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB988473A publication Critical patent/GB988473A/en
Priority claimed from BE672427A external-priority patent/BE672427A/fr
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10Esters
    • C08F20/22Esters containing halogen
    • C08F20/24Esters containing halogen containing perhaloalkyl radicals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F28/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/14Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
    • C08L33/16Homopolymers or copolymers of esters containing halogen atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L57/00Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • C09D133/14Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • C09D133/16Homopolymers or copolymers of esters containing halogen atoms
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C11/00Surface finishing of leather
    • C14C11/003Surface finishing of leather using macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C9/00Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10Homopolymers or copolymers of methacrylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
GB15714/62A 1961-05-03 1962-04-25 Polymeric compositions Expired GB988473A (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US10734661A 1961-05-03 1961-05-03
US10733061A 1961-05-03 1961-05-03
US107342A US3256231A (en) 1961-05-03 1961-05-03 Polymeric water and oil repellents
US288894A US3378609A (en) 1961-05-03 1963-06-19 Oil- and water-repellent compositions
BE672427A BE672427A (US07122603-20061017-C00294.png) 1963-09-26 1965-11-17

Publications (1)

Publication Number Publication Date
GB988473A true GB988473A (en) 1965-04-07

Family

ID=27507641

Family Applications (4)

Application Number Title Priority Date Filing Date
GB15714/62A Expired GB988473A (en) 1961-05-03 1962-04-25 Polymeric compositions
GB15715/62A Expired GB971732A (en) 1961-05-03 1962-04-25 New fluorinated methacrylates and polymers thereof
GB15713/62A Expired GB1010539A (en) 1961-05-03 1962-04-25 Fluorine-containing polymer compositions
GB35816/63A Expired GB1011612A (en) 1961-05-03 1963-09-11 Polymeric compositions and aqueous dispersions thereof

Family Applications After (3)

Application Number Title Priority Date Filing Date
GB15715/62A Expired GB971732A (en) 1961-05-03 1962-04-25 New fluorinated methacrylates and polymers thereof
GB15713/62A Expired GB1010539A (en) 1961-05-03 1962-04-25 Fluorine-containing polymer compositions
GB35816/63A Expired GB1011612A (en) 1961-05-03 1963-09-11 Polymeric compositions and aqueous dispersions thereof

Country Status (5)

Country Link
US (1) US3378609A (US07122603-20061017-C00294.png)
BE (3) BE645697A (US07122603-20061017-C00294.png)
CH (6) CH410403A (US07122603-20061017-C00294.png)
DE (2) DE1280208B (US07122603-20061017-C00294.png)
GB (4) GB988473A (US07122603-20061017-C00294.png)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2311784A1 (de) * 1972-03-10 1973-09-13 Ugine Kuhlmann Neue fluorverbindungen, verfahren zu ihrer herstellung und ihre verwendung als wasser- und oelabweisende mittel
EP1201815A1 (en) * 2000-10-31 2002-05-02 Asahi Glass Co., Ltd. Water repellent composition

Families Citing this family (67)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1388082A (fr) * 1963-12-27 1965-02-05 Kuhlmann Ets Procédé pour l'ignifugation et l'hydrofugation des textiles
CH1121365D (US07122603-20061017-C00294.png) * 1964-08-14
GB1123379A (en) * 1964-12-30 1968-08-14 Daikin Ind Ltd Fluorocarbon esters and polymers thereof
US3491169A (en) * 1966-07-22 1970-01-20 Du Pont Oil and water repellent
US3532659A (en) * 1967-04-26 1970-10-06 Pennsalt Chemicals Corp Fluorinated organic compounds and polymers thereof
US3546187A (en) * 1969-03-10 1970-12-08 Du Pont Oil- and water-repellent polymeric compositions
US3547856A (en) * 1969-03-11 1970-12-15 Du Pont Fluorinated oil and water repellents
US3668163A (en) * 1969-08-05 1972-06-06 Du Pont Emulsions of water in halogenated solvents which contain fluorinated oil and water repellents
US3644241A (en) * 1970-03-11 1972-02-22 Colgate Palmolive Co Antisoiling aerosol starch prepared from ethoxylated starch and a fluoroacrylate or fluoroalpha substituted acrylate polymer
DK152680C (da) * 1970-09-30 1988-08-22 Minnesota Mining & Mfg Snavsbestandigt og pletafvisende taeppemateriale samt fremgangsmaade til fremstilling af taeppematerialet
US3869465A (en) * 1971-03-29 1975-03-04 Hoechst Ag Dispersions of polymer fluorine-containing acrylic acid derivatives
US3775162A (en) * 1971-08-16 1973-11-27 Hooker Chemical Corp Leather treatment
US4032495A (en) * 1972-03-10 1977-06-28 Produits Chimiques Ugine Kuhlmann Water-repellent and oil-repellent compositions based on fluorine compound
US3997500A (en) * 1972-04-10 1976-12-14 The Dow Chemical Company Process and composition for water- and oil-proofing textiles
US3955027A (en) * 1972-04-10 1976-05-04 The Dow Chemical Company Process and composition for water- and oil-proofing textiles
US4043965A (en) * 1972-05-01 1977-08-23 Colgate-Palmolive Company Copolymer of acrylic acid and 1,1-dihydroperfluorooctyl methacrylate useful for applying non-permanent soil release finish
US4043964A (en) * 1973-11-14 1977-08-23 Minnesota Mining And Manufacturing Company Carpet treating and treated carpet
JPS50112597A (US07122603-20061017-C00294.png) * 1974-02-08 1975-09-04
DE2609462C3 (de) * 1976-03-08 1979-11-29 Hoechst Ag, 6000 Frankfurt Perfluoralkyläthylacrylat-Copolymere
US4059688A (en) * 1976-06-29 1977-11-22 Clairol Incorporated Hair fixing compositions containing fluoroterpolymers and method
US4127711A (en) * 1977-03-31 1978-11-28 E. I. Du Pont De Nemours And Company Fluorine-containing terpolymers
US4147851A (en) * 1978-06-13 1979-04-03 E. I. Du Pont De Nemours And Company Fluorine-containing oil- and water-repellant copolymers
US4256459A (en) * 1978-06-15 1981-03-17 Milliken Research Corporation Process for dyeing closely constructed non-tufted textile materials and products produced thereby
US4231744A (en) * 1978-06-15 1980-11-04 Milliken Research Corporation Process for dyeing closely constructed non-tufted textile materials and products produced thereby
JPS5845275A (ja) * 1981-09-10 1983-03-16 Daikin Ind Ltd アクリル系粘着剤
US4513059A (en) * 1982-02-02 1985-04-23 Permacel Release coating composition
US4474982A (en) * 1982-10-13 1984-10-02 Minnesota Mining And Manufacturing Company 1-Halomethyl-2-alkoxyethyl acrylates and methacrylates
US4529658A (en) * 1982-10-13 1985-07-16 Minnesota Mining And Manufacturing Company Fluorochemical copolymers and ovenable paperboard and textile fibers treated therewith
US4525423A (en) * 1982-10-13 1985-06-25 Minnesota Mining And Manufacturing Company Fluorochemical copolymers and ovenable paperboard and textile fibers treated therewith
US4564561A (en) * 1985-03-27 1986-01-14 E. I. Du Pont De Nemours And Company Fluorine-containing polymer compositions and their preparation
US4792444A (en) * 1985-06-14 1988-12-20 Kao Corporation Cosmetic comprising fluoroalkyl (meth)acrylate copolymers
FR2583414B1 (fr) * 1985-06-18 1987-07-31 Charbonnages Ste Chimique Procede de fabrication de (meth)acrylates d'alkyles fluores.
US4595518A (en) * 1985-07-10 1986-06-17 E. I. Du Pont De Nemours And Company Coating fibrous substrates with fluoropolymer amphoteric polymer and surfactants
EP0294648B1 (en) * 1987-05-25 1993-01-07 Daikin Industries, Limited Novel copolymer and water- and oil-repellent comprising the same
AU8327891A (en) * 1990-07-11 1992-02-04 E.I. Du Pont De Nemours And Company A method for improving the hydrolytic resistance of aramid fiber
AU649318B2 (en) * 1991-03-06 1994-05-19 Minnesota Mining And Manufacturing Company Polyfluoropolyether graft copolymers
US5314959A (en) * 1991-03-06 1994-05-24 Minnesota Mining And Manufacturing Company Graft copolymers containing fluoroaliphatic groups
US5162469A (en) * 1991-08-05 1992-11-10 Optical Research Inc. Composition for rigid gas permeable contact lenses
US5387640A (en) * 1992-01-22 1995-02-07 Bayer Aktiengesellschaft Fluorine-containing copolymers and aqueous dispersions prepared therefrom
FR2689134B1 (fr) * 1992-03-27 1997-08-14 Atochem Elf Sa Copolymeres d'ethylene ou de derives de l'ethylene et de (methiacrylates fluores leur procede de fabrication et leur application aux semelles de ski.
US5380455A (en) * 1992-06-01 1995-01-10 Kao Corporation Detergent composition
US5451440A (en) * 1993-07-30 1995-09-19 American Tape Co. Release coating for silicone pressure sensitive adhesives
US5623036A (en) * 1994-09-12 1997-04-22 Elf Atochem S. A. Method for making a surface hydrophobic
US5859126A (en) * 1995-09-18 1999-01-12 E. I. Du Pont De Nemours And Company Coatings containing fluorinated esters
US5637657A (en) * 1995-09-18 1997-06-10 E. I. Du Pont De Nemours And Company Surface coating compositions containing fluoroalkyl esters of unsaturated fatty acids
US5681902A (en) * 1996-01-11 1997-10-28 E. I. Du Pont De Nemours And Company Process for the perfluoroalkylation of substances having terminal unsaturation
US5847134A (en) * 1996-01-11 1998-12-08 E. I. Du Pont De Nemours And Company Fluorocarbon-containing isocyanate derivatives and soil-resist agents
TW377370B (en) * 1996-04-12 1999-12-21 Du Pont Waterborne fluoropolymer solutions for treating hard surfaces
US5670573A (en) * 1996-08-07 1997-09-23 E. I. Du Pont De Nemours And Company Coatings containing fluorinated esters
FR2758570A1 (fr) * 1997-01-23 1998-07-24 Atochem Elf Sa Procede pour le traitement hydrophobe et oleophobe des cuirs
US5789513A (en) * 1997-02-26 1998-08-04 E. I. Du Pont De Nemours And Company Polyfluorourethane additives for curable coating compositions
US6120892A (en) * 1997-11-20 2000-09-19 E. I. Du Pont De Nemours And Company Waterborne fluoropolymer solutions for treating hard surfaces
US6326447B1 (en) 1998-06-19 2001-12-04 E. I. Du Pont De Nemours And Company Polymeric compositions for soil release on fabrics
US6271289B1 (en) 1999-11-16 2001-08-07 E. I. Du Pont De Nemours And Company Stain resistant compositions
TW200416277A (en) 2002-10-15 2004-09-01 Asahi Glass Co Ltd Water-and-oil repellant composition
EP1709089B1 (en) * 2003-12-31 2008-03-05 3M Innovative Properties Company Water-and oil-repellent fluoroacrylates
US7411020B2 (en) * 2004-12-28 2008-08-12 3M Innovative Properties Company Water-based release coating containing fluorochemical
US20060142530A1 (en) * 2004-12-28 2006-06-29 Moore George G Water- and oil-repellent fluorourethanes and fluoroureas
US7291688B2 (en) * 2004-12-28 2007-11-06 3M Innovative Properties Company Fluoroacrylate-mercaptofunctional copolymers
US7345123B2 (en) * 2004-12-28 2008-03-18 3M Innovative Properties Company Fluoroacrylate-multifunctional acrylate copolymer compositions
US7253241B2 (en) * 2004-12-28 2007-08-07 3M Innovative Properties Company Fluorochemical containing low adhesion backsize
CN101142165B (zh) 2005-03-15 2010-05-19 株式会社德山 (甲基)丙烯酸含氟烷基酯的制造方法
US7652112B2 (en) * 2005-07-06 2010-01-26 E.I. Du Pont De Nemours And Company Polymeric extenders for surface effects
US20070275174A1 (en) * 2006-05-24 2007-11-29 Hanson Eric L Fishing fly and fly fishing line with fluorocarbon coating
EP2660372A1 (de) 2012-05-04 2013-11-06 LANXESS Deutschland GmbH Thermoplastfasern mit reduzierter Oberflächenspannung
US20140165263A1 (en) 2012-12-18 2014-06-19 Ansell Limited Fluid repellent elastomeric barrier
AU2016345053A1 (en) 2015-10-30 2018-04-26 Ansell Limited Leak resistant article

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB636535A (en) * 1942-12-24 1950-05-03 Goodrich Co B F Improvements in or relating to synthetic resin latices and method of making same
FR1000895A (fr) * 1949-11-29 1952-02-18 Perfectionnements aux procédés de traitement des tissus
US2642416A (en) * 1950-05-26 1953-06-16 Minnesota Mining & Mfg Fluorinated acrylates and polymers
US2803615A (en) * 1956-01-23 1957-08-20 Minnesota Mining & Mfg Fluorocarbon acrylate and methacrylate esters and polymers
US3102103A (en) * 1957-08-09 1963-08-27 Minnesota Mining & Mfg Perfluoroalkyl acrylate polymers and process of producing a latex thereof
US3282905A (en) * 1961-05-03 1966-11-01 Du Pont Fluorine containing esters and polymers thereof
DE1444114C3 (de) * 1963-09-26 1975-09-18 E.I. Du Pont De Nemours And Co., Wilmington, Del. (V.St.A.) Latex zum Wasser- und ÖlabstoBendmachen von Fasermaterial

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2311784A1 (de) * 1972-03-10 1973-09-13 Ugine Kuhlmann Neue fluorverbindungen, verfahren zu ihrer herstellung und ihre verwendung als wasser- und oelabweisende mittel
EP1201815A1 (en) * 2000-10-31 2002-05-02 Asahi Glass Co., Ltd. Water repellent composition
US6590035B2 (en) 2000-10-31 2003-07-08 Asahi Glass Company, Limited Water repellent composition

Also Published As

Publication number Publication date
CH504578A (de) 1969-09-30
CH413580A (de) 1966-05-15
BE645697A (US07122603-20061017-C00294.png) 1964-07-16
GB971732A (en) 1964-10-07
CH527662A4 (US07122603-20061017-C00294.png) 1966-07-15
DE1280208B (de) 1968-10-17
BE634770A (US07122603-20061017-C00294.png)
CH410403A (de) 1966-03-31
CH527462A4 (US07122603-20061017-C00294.png) 1969-09-30
DE1444117A1 (de) 1969-03-06
CH527562A4 (US07122603-20061017-C00294.png) 1969-09-30
CH439747A (de) 1967-07-15
CH504577A (de) 1969-09-30
CH404638A (de) 1966-07-15
GB1011612A (en) 1965-12-01
BE635437A (US07122603-20061017-C00294.png)
GB1010539A (en) 1965-11-17
US3378609A (en) 1968-04-16

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