KR910012441A - 발수 및 발유처리제 - Google Patents

발수 및 발유처리제 Download PDF

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KR910012441A
KR910012441A KR1019900021378A KR900021378A KR910012441A KR 910012441 A KR910012441 A KR 910012441A KR 1019900021378 A KR1019900021378 A KR 1019900021378A KR 900021378 A KR900021378 A KR 900021378A KR 910012441 A KR910012441 A KR 910012441A
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aziridinyl
weight
repellent
water
oil
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나가세 마꼬또
에밀리에 마리 루이스 어거스타 알리웨르트 캐씨
마델라인 앤 피유스 프란세스카
모리스 요한나 코펜스 디크
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도날드 밀러 쎌
미네소타 마이닝 앤드 매뉴팩츄어링 캄파니
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D06M15/576—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/48—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing the ethylene imine ring
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins
    • D06M15/437—Amino-aldehyde resins containing fluorine
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507—Polyesters
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
    • Y10T428/31544—Addition polymer is perhalogenated

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

내용 없음

Description

발수 및 발유처리제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (19)

  1. 플루오르화학계 발수 및 발유제, 아지딘 화합물 및 금속 알콜레이트 또는 에스테르를 포함하는 직물기재용 발수 및 발유처리제.
  2. 제1항에 있어서, 상기 아지리딘 화합물이 β-아지리디닐메틸 메타크릴레이트, N-시아노에틸에틸렌이민, 옥타데실 에틸렌우레아, 트리메틸올프로판트리스-[3-(1-아지리디닐)프로피오네이트], 트리메틸올프로판트리스[3-(1-아지리디닐)부티레이트], 트리메틸을 프로판[3-(1-(2-메틸)아지리디닐)프로피오네이트], 트리메틸올프로판트리스[3-(1-아지리디닐)-2-메틸프로피오네이트], 펜타에리쓰리톨트리스[3-(1-아지리디닐)프로피오네이트], 펜타에리쓰리톨트리스[3-(1-(2-메틸)아지리디닐)프로피오네이트], 디페닐메탄-4.4'-비스-N,N'-에틸렌우레아, 1-6-헥사메틸렌-비스- N,N'-에틸렌우레아, 2,4,6-(트리에틸렌이미노)-신-트리아진, 비스[1-(2-에틸)아지리디닐]벤젠-1,3-디카복실산아믿, 1,6-헥사메틸렌 디에틸렌우레아 디페닐메탄비스-4,4'-N,N'-디에틸렌우레아 및 1,1,1-트리스-(β-아지리디닐 프로피오닐옥시메틸)프로판으로 이루어진 그둡중에서 선택되는 처리제.
  3. 제1항에 있어서, 상기 금속 알콜레이트 또는 에스테르가, 상기 처리제를 섬유기재에 처리하고 90℃이하에서 건조시킬때 상기 처리제가 상기 섬유기재에 목적하는 발유성 및 발수성을 부여할수 있도록 하는 것인 처리제.
  4. 제1항에 있어서, 상기 금속 알콜레이트 또는 에르테르가 알루미늄 이소프로필레이트, 모노-2급-부록시 알루미늄 디이소프로필레이트, 알루미늄2급-부티레이트, 알루미늄 에틸레이트, 알루미늄2급-부티레이트 스테아레이트, 지르코늄 부티레이트 및 지르코늄 프로필레이트로 이루어진 그룹중에서 선택되는 처리제.
  5. 제1항에 있어서,상기 아지리딘이 상기 플루오르화학계 발수 및 발유제의 중량을 기준으로 1내지 20중량 %존재하고, 상기 금속 알콜레이트 또는 에스테르가 상기 플루오르화학계 발수 및 발유제의 중량을 기준으로 10내지 20중량 %존재하는 처리제.
  6. 제1항에 있어서, 상기 아지리딘이 상기 플루오르화하계 발수 및 발유제의 중량을 기준으로 3재지 10중량%존재 하고, 상기 금속 알콜레이트 또는 에스테르가 상기 플루오르화학계 발수 및 발유제의 중량을 기준으로 20내지 100중량 %존재하는 처리제.
  7. 제1항에 있어서, 상기 프루오로화학계 발수 및 발유제가 플루오로 지방족 라디칼 함유 아크릴레이트 또는 메나크릴 레이트 단량체와 알킬아크릴레이트 또는 메타크릴 레이트 단량체의 공중합체를 포함하는 처리제.
  8. 제1항에 있어서, 실리콘계 화합물을 또한 포함하는 처리제.
  9. A)섬유지재를 플루오로화학계 발수 및 발유제, 아지디딘 화합물 및 금속 알콜레이트 또는 에스테르를 포함하는 용애과 접촉시키고; B) 단계A로부터 생성된 기재를 건조시킴을 포함하는 섬유 기재의 처리방법.
  10. 제9항에 있어서, 상기 건조를 90℃미만에서 수행하는 방법.
  11. 제9항에 있어서, 상기 건조를 30℃미만에서 수행하는 방법.
  12. 제9항에 있어서, 상기 아지리딘 화합물이 β-아지리디닐메틸 메타크릴레이트, N-시아노에틸에틸렌이민, 옥타데실 에틸렌우레아, 트리메틸올프로판트리스-[3-(1-아지리디닐)프로피오네이트], 트리메틸올프로판트리스[3-(1-아지리디닐)부티레이트], 트리메틸을 프로판[3-(1-(2-메틸)아지리디닐)프로피오네이트], 트리메틸올프로판트리스[3-(1-아지리디닐)-2-메틸프로피오네이트], 펜타에리쓰리톨트리스[3-(1-아지리디닐)프로피오네이트], 펜타에리쓰리톨트리스[3-(1-(2-메틸)아지리디닐)프로피오네이트], 디페닐메탄-4.4'-비스-N,N'-에틸렌우레아, 1-6-헥사메틸렌-비스- N,N'-에틸렌우레아, 2,4,6-(트리에틸렌이미노)-신-트리아진, 비스[1-(2-에틸)아지리디닐]벤젠-1,3-디카복실산아믿, 1,6-헥사메틸렌 디에틸렌우레아 디페닐메탄비스-4,4'-N,N'-디에틸렌우레아 및 1,1,1-트리스-(β-아지리디닐 프로피오닐옥시메틸)프로판으로 이루어진 그둡중에서 선택되는 방법.
  13. 제9항에 있어서, 상기 금속 알콜레이트 또는 에르테르가 알루미늄 이소프로필레이트, 모노-2급-부록시 알루미늄 디이소프로필레이트, 알루미늄2급-부티레이트, 알루미늄 에틸레이트, 알루미늄2급-부티레이트 스테아레이트, 지르코늄 부티레이트 및 지르코늄 프로필레이트로 이루어진 그룹중에서 선택되는 방법.
  14. 제9항에 있어서, 상기 아지리딘이 상기 플루오르화학계 발수 및 발유제의 중량을 기준으로 1내지 20중량 %존재하고, 상기 금속 알콜레이트 또는 에스테르가 상기 플루오르화학계 발수 및 발유제의 중량을 기준으로 10내지 200중량 %존재하는 방법.
  15. 제9항에 있어서, 상기 아지리딘이 상기 플루오르화학계 발수 및 발유제의 중량을 기준으로 3내지 10중량 %존재하고, 상기 금속 알콜레이트 또는 에스테르가 상기 플루오르화학계 발수 및 발유제의 중량을 기준으로 20내지 100중량 %존재하는 방법.
  16. 제9항에 있어서, 상기 플루오로화학계 발수 및 발유제가 플루오로 지방족 라디칼 함유 아크릴레이트 또는 메타크릴레이트 단량체와 알킬아크릴레이트 또는 메타크릴 레이트 단량체의 공중합체를 포함하는 방법.
  17. 제9항에 있어서, 상기 혼합물이 실리콘계 화합물을 또한 포함하는 방법.
  18. 제1항의 처리제로 처리한 섬유기재.
  19. 제18항에 있어서, 상기 섬유기재가 실크, 모, 면, 가죽, 마 레이욘 및 혼방섬유로 이루어진 그룹중에서 선택되는 섬유기재.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900021378A 1989-12-22 1990-12-21 발수 및 발유처리제, 처리방법 및 처리된 섬유기재 KR0147824B1 (ko)

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JP1334621A JPH03193975A (ja) 1989-12-22 1989-12-22 撥水撥油処理剤
JP334621/89 1989-12-22

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KR910012441A true KR910012441A (ko) 1991-08-07
KR0147824B1 KR0147824B1 (ko) 1998-08-01

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US (1) US5084191A (ko)
EP (1) EP0438886B1 (ko)
JP (1) JPH03193975A (ko)
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DE (1) DE69006477T2 (ko)

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US5084191A (en) 1992-01-28
KR0147824B1 (ko) 1998-08-01
DE69006477T2 (de) 1994-08-25
DE69006477D1 (de) 1994-03-17
EP0438886B1 (en) 1994-02-02
EP0438886A1 (en) 1991-07-31

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