GB975331A - Lubricating compositions - Google Patents

Lubricating compositions

Info

Publication number
GB975331A
GB975331A GB17113/61A GB1711361A GB975331A GB 975331 A GB975331 A GB 975331A GB 17113/61 A GB17113/61 A GB 17113/61A GB 1711361 A GB1711361 A GB 1711361A GB 975331 A GB975331 A GB 975331A
Authority
GB
United Kingdom
Prior art keywords
cellulose
resin
particles
total solids
per cent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB17113/61A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Acheson Industries Inc
Original Assignee
Acheson Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Acheson Industries Inc filed Critical Acheson Industries Inc
Publication of GB975331A publication Critical patent/GB975331A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M7/00—Solid or semi-solid compositions essentially based on lubricating components other than mineral lubricating oils or fatty oils and their use as lubricants; Use as lubricants of single solid or semi-solid substances
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D101/00—Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
    • C09D101/08—Cellulose derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
    • C10M2201/042—Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/061—Carbides; Hydrides; Nitrides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/065—Sulfides; Selenides; Tellurides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/065—Sulfides; Selenides; Tellurides
    • C10M2201/066—Molybdenum sulfide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/16—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/18—Ammonia
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/12—Polysaccharides, e.g. cellulose, biopolymers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/041—Triaryl phosphates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/015—Dispersions of solid lubricants
    • C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/04—Aerosols
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/08—Solids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10—Semi-solids; greasy

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Lubricants (AREA)
  • Paints Or Removers (AREA)

Abstract

A lubricating composition comprises finely-divided lubricating particles, at least one cellulosic resin, and a solvent for said resin, the composition having 0.5-40 wt. per cent total solids, made up of 84-62% (by vol. of total solids) of the lubricating particles and 66.38% (by vol. of total solids) of the resin, the said particles containing at least 10 wt. per cent of molybdenum disulphide. The lubricating particles may be entirely of MoS2 or may contain up to 15 wt. per cent. of graphite and/or up to 90 wt. per cent. of WS2, TiS2, BN, lead oxide, or mixtures thereof, and the particle size is 0.2-20 microns in largest dimension, at least 40% of the particles being less than 0.7 micron. The cellulosic resin is an ester or ether, those specified being cellulose acetate, cellulose acetate butyrate, cellulose acetate propionate, cellulose triacetate, cellulose propionate, nitrocellulose, ethyl cellulose, ethyl hydroxyethyl cellulose, carboxyethyl cellulose, hydroxypropyl methyl cellulose, and carboxymethyl hydroxy cellulose, or mixtures thereof. Solvents for the resins include ethanol, ethyl acetate, toluene, acetone, hexylene glycol, diethylene glycol ether, methylene chloride, CCl4, dioxane, nitropropane and tetrahydrofuran, others of similar nature also being specified. A common diluent may also be used, e.g. heptane or mineral spirits, others also being mentioned. A plasticizer for the resin may also be present, e.g. tricresyl phosphate, dibutylphthalate, castor oil or mineral oil.ALSO:A lubricating composition comprises finely-divided lubricating particles, at least one cellulosic resin, and a solvent for said resin, the composition having from 0.5 to 40% by weight total solids, made up of 34 to 62% (by volume of the total solids) of the lubricating particles, and 66 to 38% (by volume of the total solids) of the resin, the said particles containing at least 10% by weight of molybdenum disulphide. The lubricating particles may be entirely of MoS2 or may contain up to 15% by weight of graphite and/or up to 90% by weight of WS2, TiS2, BN, lead oxide, or mixtures thereof, and the particle size is 0.2 to 20 microns in largest dimension, at least 40% of the particles being less than 0.7 micron. The cellulosic resin is a cellulose ester or ether, those specified being cellulose acetate, cellulose acetate butyrate, cellulose acetate propionate, cellulose triacetate, cellulose propionate, nitrocellulose, ethyl cellulose, ethyl hydroxyethyl cellulose, carboxyethyl cellulose, hydroxypropyl methyl cellulose, and carboxymethyl hydroxy cellulose, or mixtures thereof. Specified solvents for the cellulose resins include ethanol, ethyl acetate, toluene, acetone, hexylene glycol, diethylene glycol ether, methylene chloride, carbon tetrachloride, dioxan, nitropropane, and tetrahydrofuran, many others of similar nature also being specifically mentioned. A common diluent may also be used, e.g. heptane or mineral spirits, others also being mentioned. A plasticizer for the cellulosic resin may also be present, e.g. tricresyl phosphate, dibutylphthalate, castor oil or mineral oil.ALSO:The surfaces of metal, rubber, glass, wood, paper, cloth, leather, cork, polystyrene and nylon are coated with a composition comprising finely divided lubricating particles, at least one cellulosic resin, and a solvent for said resin, the composition having from 0,5-40 weight per cent total solids, made up of 34-62% (by volume of the total solids) of the lubricating particles, and 66-38% (by volume of the total solids) of the resin, the said particles containing at least 10 weight per cent of molybdenum disulphide. The lubricating particles may be entirely of MoS2 or may contain up to 15 weight per cent of graphite and/or up to 90 weight per cent of WS2, TiS2, BN, lead oxide, or mixtures thereof, and the particle size is 0,2-20 microns in largest dimension, at least 40% of the particles being less than 0,7 micron. The cellulosic resin is an ester or ether, those specified being cellulose acetate, cellulose acetate butyrate, cellulose acetate propionate, cellulose triacetate, cellulose propionate, nitrocellulose, ethyl cellulose, ethyl hydroxyethyl cellulose, carboxyethyl cellulose, hydroxypropyl methyl cellulose, and carboxymethyl hydroxy cellulose, or mixtures thereof. Specified solvents for the resin include ethanol, ethyl acetate, toluene, acetone, hexylene glycol, diethylene glycol ether, methylene chloride, CCl4, dioxan, nitropropane, and tetrahydrofuran, many others of similar nature also being specified. A common diluent may also be used, e.g. heptane or mineral spirits, others also being mentioned. A plasticizer for the cellulosic resin may also be present, e.g. tricresyl phosphate, dibutylphthalate, castor oil or mineral oil. The compositions may be applied to the substrate by spraying, brushing or dipping, and allowed to air-dry, thus forming an adherent lubricating film on the surface. Several thin layers may be applied in this way to the same surface. The surface is preferably roughened prior to coating, e.g. by grit blasting, and where the surface is metallic a chemical conversion coating may be applied, e.g. a metallic phosphate, oxalate, sulphide, oxide or chromate.
GB17113/61A 1960-05-10 1961-05-10 Lubricating compositions Expired GB975331A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US2800460A 1960-05-10 1960-05-10

Publications (1)

Publication Number Publication Date
GB975331A true GB975331A (en) 1964-11-18

Family

ID=21841020

Family Applications (1)

Application Number Title Priority Date Filing Date
GB17113/61A Expired GB975331A (en) 1960-05-10 1961-05-10 Lubricating compositions

Country Status (1)

Country Link
GB (1) GB975331A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0214434A2 (en) * 1985-09-09 1987-03-18 Lonza Ag Lubricating active agent in a powdery to pasty form
WO1999000468A1 (en) * 1997-06-26 1999-01-07 David Thomas Brown Ballistics conditioning with molybdenum disulfide
WO2001016381A1 (en) * 1999-09-02 2001-03-08 Pittards Plc Treated leather
WO2001083651A3 (en) * 2000-05-04 2002-04-04 Honeywell Int Inc Continuously coated multi-composition, multi-layered solid lubricant coatings based on polyimide polymer compositions
US6576598B2 (en) 2001-08-22 2003-06-10 David Thomas Brown Ballistics conditioning
US6685746B1 (en) 1999-04-27 2004-02-03 Pittards Public Limited Company Impregnation of leather with micro-encapsulated material
WO2014004507A1 (en) * 2012-06-27 2014-01-03 Shell Oil Company Fuel and engine oil composition and its use
CN113801522A (en) * 2021-09-17 2021-12-17 深圳深沪标准件实业有限公司 Anti-seizing liquid medicine for bolt and preparation method thereof
CN115418147A (en) * 2022-09-29 2022-12-02 中国科学院兰州化学物理研究所 Room temperature curing lubricating aerosol and preparation method thereof

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0214434A2 (en) * 1985-09-09 1987-03-18 Lonza Ag Lubricating active agent in a powdery to pasty form
EP0214434A3 (en) * 1985-09-09 1988-06-08 Lonza Ag Lubricating active agent in a powdery to pasty form
WO1999000468A1 (en) * 1997-06-26 1999-01-07 David Thomas Brown Ballistics conditioning with molybdenum disulfide
US6685746B1 (en) 1999-04-27 2004-02-03 Pittards Public Limited Company Impregnation of leather with micro-encapsulated material
WO2001016381A1 (en) * 1999-09-02 2001-03-08 Pittards Plc Treated leather
WO2001083651A3 (en) * 2000-05-04 2002-04-04 Honeywell Int Inc Continuously coated multi-composition, multi-layered solid lubricant coatings based on polyimide polymer compositions
US6548453B1 (en) 2000-05-04 2003-04-15 Honeywell International Inc. Continuously coated multi-composition, multi-layered solid lubricant coatings based on polyimide polymer compositions
US6576598B2 (en) 2001-08-22 2003-06-10 David Thomas Brown Ballistics conditioning
WO2014004507A1 (en) * 2012-06-27 2014-01-03 Shell Oil Company Fuel and engine oil composition and its use
CN113801522A (en) * 2021-09-17 2021-12-17 深圳深沪标准件实业有限公司 Anti-seizing liquid medicine for bolt and preparation method thereof
CN115418147A (en) * 2022-09-29 2022-12-02 中国科学院兰州化学物理研究所 Room temperature curing lubricating aerosol and preparation method thereof

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