GB974073A - Bleaching of cellulosic material - Google Patents
Bleaching of cellulosic materialInfo
- Publication number
- GB974073A GB974073A GB27643/63A GB2764363A GB974073A GB 974073 A GB974073 A GB 974073A GB 27643/63 A GB27643/63 A GB 27643/63A GB 2764363 A GB2764363 A GB 2764363A GB 974073 A GB974073 A GB 974073A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrogen peroxide
- bleaching
- solution
- wood pulp
- pulp
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004061 bleaching Methods 0.000 title abstract 7
- 239000000463 material Substances 0.000 title abstract 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 14
- 229920001131 Pulp (paper) Polymers 0.000 abstract 6
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 abstract 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 2
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 abstract 2
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 abstract 1
- 239000004155 Chlorine dioxide Substances 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000008065 acid anhydrides Chemical class 0.000 abstract 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- 150000008064 anhydrides Chemical class 0.000 abstract 1
- ZJRXSAYFZMGQFP-UHFFFAOYSA-N barium peroxide Chemical compound [Ba+2].[O-][O-] ZJRXSAYFZMGQFP-UHFFFAOYSA-N 0.000 abstract 1
- 239000007844 bleaching agent Substances 0.000 abstract 1
- YHASWHZGWUONAO-UHFFFAOYSA-N butanoyl butanoate Chemical compound CCCC(=O)OC(=O)CCC YHASWHZGWUONAO-UHFFFAOYSA-N 0.000 abstract 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 abstract 1
- 239000003518 caustics Substances 0.000 abstract 1
- 238000005660 chlorination reaction Methods 0.000 abstract 1
- 235000019398 chlorine dioxide Nutrition 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- VGGRCVDNFAQIKO-UHFFFAOYSA-N formic anhydride Chemical compound O=COC=O VGGRCVDNFAQIKO-UHFFFAOYSA-N 0.000 abstract 1
- 239000011121 hardwood Substances 0.000 abstract 1
- LSACYLWPPQLVSM-UHFFFAOYSA-N isobutyric acid anhydride Chemical compound CC(C)C(=O)OC(=O)C(C)C LSACYLWPPQLVSM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 abstract 1
- 235000019341 magnesium sulphate Nutrition 0.000 abstract 1
- KKHUSADXXDNRPW-UHFFFAOYSA-N malonic anhydride Chemical compound O=C1CC(=O)O1 KKHUSADXXDNRPW-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- WYVAMUWZEOHJOQ-UHFFFAOYSA-N propionic anhydride Chemical compound CCC(=O)OC(=O)CC WYVAMUWZEOHJOQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- RINCXYDBBGOEEQ-UHFFFAOYSA-N succinic anhydride Chemical compound O=C1CCC(=O)O1 RINCXYDBBGOEEQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/1026—Other features in bleaching processes
- D21C9/1036—Use of compounds accelerating or improving the efficiency of the processes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
- D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
Abstract
Wool pulp is bleached by contacting it with an aqueous hydrogen peroxide solution to produce a partially bleached material and a partially spent aqueous hydrogen peroxide solution, adding an organic carboxylic acid anhydride, e.g. formic, acetic, propionic, n butyric, isobutyric, malonic or succinic acid anhydride, to the partially spent aqueous hydrogen peroxide solution to yield a solution having further bleaching action and further bleaching the partially bleached material with this solution the wood pulp may be contacted with the original hydrogen peroxide solution having a concentration of 1-10% by weight of the wood pulp and a pH of 6.5-9 and preferably containing sodium hydroxide in the presence of stabilizers, e.g. sodium silicate and magnesium sulphate, at a temperature of 250 DEG -100 DEG C. for 10-45 minutes. The acid anhydride is then added, preferably in an amount of 0.5-2.5 moles per mole of hydrogen peroxide in the partially spent solution, if desired together with an acid, e.g. acetic sulphuric, hydrochloric or phosphoric acid or an excess of the anhydride, to adjust the pH value and bleaching continued at 30 DEG -70 DEG for a further 2-15 minutes. The hydrogen peroxide may be added as such or may be produced from an inorganic peroxide, e.g. sodium, potassium, lithium or barium peroxide which yields hydrogen peroxide on contact with water or from a percarbamate. The wood pulp may be ground wood pulp, chemi-ground wood pulp or semi chemical wood pulp. When bleaching hardwood pulp the process may comprise a number of steps e.g. chlorination, caustic extraction, hypochlorite bleaching, chlorine dioxide, hydrogen peroxide or additional hypochlorite bleaching followed by either a one-stage or two-stage-final hydrogen peroxide bleach.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US210193A US3193445A (en) | 1962-07-16 | 1962-07-16 | Method of bleaching cellulosic materials with hydrogen peroxide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB974073A true GB974073A (en) | 1964-11-04 |
Family
ID=22781939
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB27643/63A Expired GB974073A (en) | 1962-07-16 | 1963-07-12 | Bleaching of cellulosic material |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3193445A (en) |
| BE (1) | BE633420A (en) |
| DE (1) | DE1546276A1 (en) |
| FR (1) | FR1379645A (en) |
| GB (1) | GB974073A (en) |
| NL (1) | NL293489A (en) |
| NO (1) | NO109292C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2227759A (en) * | 1988-12-23 | 1990-08-08 | Canadian Ind | Hydrogen peroxide bleaching process |
| US5073301A (en) * | 1989-07-18 | 1991-12-17 | Degussa Aktiengesellschaft | Process for stabilization of the viscosity of wood pulps |
| GB2265392A (en) * | 1992-03-24 | 1993-09-29 | Albright & Wilson | Stabilization of peroxide bleach liquors |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1469608A1 (en) * | 1964-07-10 | 1968-12-19 | Basf Ag | Process for the simultaneous dyeing and bleaching of proteinaceous fiber material |
| US3458394A (en) * | 1965-10-08 | 1969-07-29 | Scott Paper Co | Pulping wood chips with peracetic acid and chlorine dioxide |
| US3462344A (en) * | 1966-05-31 | 1969-08-19 | Fmc Corp | Superbleaching of wood pulps |
| US3650887A (en) * | 1969-04-21 | 1972-03-21 | Kimberly Clark Co | Wood pulp bleaching process utilizing peroxide-silicate bleaching solution |
| DE2219505C3 (en) * | 1972-04-21 | 1974-10-17 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt | Chlorine-free multi-stage bleaching of cellulose |
| US4060386A (en) * | 1972-12-06 | 1977-11-29 | Jerome Katz | Alkaline hydrogen peroxide bleaching method |
| US4312634A (en) * | 1972-12-06 | 1982-01-26 | Jerome Katz | Method for treating cellulosic materials prior to bleaching |
| US4060385A (en) * | 1972-12-06 | 1977-11-29 | Jerome Katz | Method for hydrogen peroxide bleaching in acid or neutral solutions |
| US3878037A (en) * | 1973-06-29 | 1975-04-15 | Betz Laboratories | Method of enhancing the hypochlorite bleaching of pulp |
| US4022965A (en) * | 1975-01-13 | 1977-05-10 | Crown Zellerbach Corporation | Process for producing reactive, homogeneous, self-bondable lignocellulose fibers |
| US4427490A (en) | 1978-04-07 | 1984-01-24 | International Paper Company | Delignification and bleaching process for lignocellulosic pulp with peroxide in the presence of metal additives |
| US4410397A (en) * | 1978-04-07 | 1983-10-18 | International Paper Company | Delignification and bleaching process and solution for lignocellulosic pulp with peroxide in the presence of metal additives |
| DE3005947B1 (en) * | 1980-02-16 | 1981-01-29 | Degussa | Process for bleaching pulp using organic peracid |
| US4793898A (en) * | 1985-02-22 | 1988-12-27 | Oy Keskuslaboratorio - Centrallaboratorium Ab | Process for bleaching organic peroxyacid cooked material with an alkaline solution of hydrogen peroxide |
| US4731161A (en) * | 1986-07-31 | 1988-03-15 | Union Camp Corporation | Semibleaching liquor for Kraft paper products |
| SE8700569D0 (en) * | 1987-02-12 | 1987-02-12 | Josef Kubat | AN IMPROVED PEROXIDE BLEACHING METHOD |
| SE505980C2 (en) * | 1993-12-23 | 1997-10-27 | Bim Kemi Ab | Ways to prevent peroxide-degrading enzymes by bleaching with hydrogen peroxide |
| US7052578B2 (en) * | 2000-01-28 | 2006-05-30 | Martin Marietta Magnesia Specialties, Inc. | Process employing magnesium hydroxide in peroxide bleaching of mechanical pulp |
| US7297225B2 (en) * | 2004-06-22 | 2007-11-20 | Georgia-Pacific Consumer Products Lp | Process for high temperature peroxide bleaching of pulp with cool discharge |
| US7967948B2 (en) * | 2006-06-02 | 2011-06-28 | International Paper Company | Process for non-chlorine oxidative bleaching of mechanical pulp in the presence of optical brightening agents |
| US8845860B2 (en) | 2010-09-16 | 2014-09-30 | Georgia-Pacific Consumer Products Lp | High brightness pulps from lignin rich waste papers |
| ITLO20130003A1 (en) * | 2013-08-08 | 2015-02-09 | Milano Politecnico | PRODUCTION OF TEXTILE MATERIAL FROM CITRUS FRUIT |
| TW201544652A (en) | 2014-05-20 | 2015-12-01 | Georgia Pacific Consumer Prod | Bleaching and shive reduction process for non-wood fibers |
| TW201610265A (en) | 2014-05-20 | 2016-03-16 | 喬治亞太平洋消費者產品公司 | Bleaching and shive reduction process for non-wood fibers |
| TW201610261A (en) * | 2014-05-20 | 2016-03-16 | 喬治亞太平洋消費者產品公司 | Bleaching and shive reduction process for non-wood fibers |
| BR102014016692A2 (en) * | 2014-07-04 | 2016-03-29 | Univ Estadual Paulista Julio D | pulp bleaching process and pulp production |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2104120A (en) * | 1938-01-04 | Bleaching composition | ||
| US2112116A (en) * | 1936-05-02 | 1938-03-22 | Brown Co | Production of cellulose fiber of low solution viscosity for conversion into cellulose derivatives |
| US2173474A (en) * | 1939-04-14 | 1939-09-19 | Evoy Martin | Bleaching |
| US2287064A (en) * | 1940-05-01 | 1942-06-23 | Du Pont | Stable dry compositions useful as bleaching and oxidizing agents |
| US2426142A (en) * | 1943-09-01 | 1947-08-19 | Du Pont | Bleaching cotton textile goods |
| US2822236A (en) * | 1954-11-19 | 1958-02-04 | Fmc Corp | Process of maintaining brightness in high density wood pulp having a ph6-10 by adding hydrogen peroxide and composition produced thereby |
| US2939813A (en) * | 1956-04-25 | 1960-06-07 | Columbia Cellulose Company Ltd | Pulping of lignocellulosic material |
| US3085039A (en) * | 1960-08-23 | 1963-04-09 | Fmc Corp | Process for the treatment of wood |
-
0
- BE BE633420D patent/BE633420A/xx unknown
- NO NO109292D patent/NO109292C/no unknown
- NL NL293489D patent/NL293489A/xx unknown
-
1962
- 1962-07-16 US US210193A patent/US3193445A/en not_active Expired - Lifetime
-
1963
- 1963-06-07 FR FR937347A patent/FR1379645A/en not_active Expired
- 1963-07-04 DE DE19631546276 patent/DE1546276A1/en active Pending
- 1963-07-12 GB GB27643/63A patent/GB974073A/en not_active Expired
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2227759A (en) * | 1988-12-23 | 1990-08-08 | Canadian Ind | Hydrogen peroxide bleaching process |
| GB2227759B (en) * | 1988-12-23 | 1992-05-20 | Canadian Ind | Hydrogen peroxide bleaching process |
| US5073301A (en) * | 1989-07-18 | 1991-12-17 | Degussa Aktiengesellschaft | Process for stabilization of the viscosity of wood pulps |
| GB2265392A (en) * | 1992-03-24 | 1993-09-29 | Albright & Wilson | Stabilization of peroxide bleach liquors |
| GB2265392B (en) * | 1992-03-24 | 1995-08-30 | Albright & Wilson | Stabilization of peroxide bleach liquors by chlorine dioxide |
| US5618385A (en) * | 1992-03-24 | 1997-04-08 | Albright & Wilson Limited | Method of peroxide bleaching of pulp using a peroxide decomposing inactivator |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1379645A (en) | 1964-11-27 |
| US3193445A (en) | 1965-07-06 |
| BE633420A (en) | |
| DE1546276A1 (en) | 1970-04-30 |
| NO109292C (en) | |
| NL293489A (en) |
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