GB946318A - Method of producing an anhydrous crystalline zirconium tetraacetate - Google Patents
Method of producing an anhydrous crystalline zirconium tetraacetateInfo
- Publication number
- GB946318A GB946318A GB43084/60A GB4308460A GB946318A GB 946318 A GB946318 A GB 946318A GB 43084/60 A GB43084/60 A GB 43084/60A GB 4308460 A GB4308460 A GB 4308460A GB 946318 A GB946318 A GB 946318A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acetic acid
- acetic anhydride
- zirconium
- tetraacetate
- acetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- MFFVROSEPLMJAP-UHFFFAOYSA-J zirconium(4+);tetraacetate Chemical compound [Zr+4].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O MFFVROSEPLMJAP-UHFFFAOYSA-J 0.000 title abstract 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 23
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 abstract 15
- 229960000583 acetic acid Drugs 0.000 abstract 8
- 239000000203 mixture Substances 0.000 abstract 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- MJOQJPYNENPSSS-XQHKEYJVSA-N [(3r,4s,5r,6s)-4,5,6-triacetyloxyoxan-3-yl] acetate Chemical compound CC(=O)O[C@@H]1CO[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O MJOQJPYNENPSSS-XQHKEYJVSA-N 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 150000003842 bromide salts Chemical class 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 150000001805 chlorine compounds Chemical class 0.000 abstract 1
- ZICYSHJXIHXTOG-UHFFFAOYSA-N chloro hypochlorite zirconium hydrate Chemical compound O.[Zr].ClOCl ZICYSHJXIHXTOG-UHFFFAOYSA-N 0.000 abstract 1
- 239000012362 glacial acetic acid Substances 0.000 abstract 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract 1
- 150000004694 iodide salts Chemical class 0.000 abstract 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- CMOAHYOGLLEOGO-UHFFFAOYSA-N oxozirconium;dihydrochloride Chemical compound Cl.Cl.[Zr]=O CMOAHYOGLLEOGO-UHFFFAOYSA-N 0.000 abstract 1
- 239000002244 precipitate Substances 0.000 abstract 1
- 239000000344 soap Substances 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
- C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Anhydrous crystalline zirconium tetraacetate is prepared by heating a solution of a monochlorozirconyltriacetate acetic acid complex in a mixture of acetic anhydride and acetic acid so as to drive off acetic acid and hydrogen chloride, the resulting zirconium tetraacetate which precipitates in the remaining acetic anhydride being recovered and dried. The heating is preferably carried out at a reduced pressure of about 40-50 m.m. Hg. and a temperature of about 60 DEG C. and may be terminated when about two-thirds of the volume corresponding with that of the acetic acid originally introduced has distilled over, the remaining mixture being treated with an oxidising agent, preferably hydrogen peroxide, at about 110-120 DEG C. and atmospheric pressure to remove the residual chlorine content. The solution of the monochlorozirconyltriacetate acetic acid complex may be obtained by (1) dissolving zirconinm tetrachloride in glacial acetic acid at 50-60 DEG C. to give a solution of a dichlorozirconyldiacetate acetic acid complex which is then treated with acetic anhydride; (2) dissolving zirconium oxychloride hydrate in acetic anhydride; and (3) dissolving polymeric zirconium oxychloride in a mixture of acetic anhydride and acetic acid. The corresponding bromides or iodides may be used in place of the chlorides. The tetraacetate may be readily converted to soap of higher aliphatic acids such as zirconium octoate or stearate.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEG28916A DE1148992B (en) | 1960-01-29 | 1960-01-29 | Process for the production of crystallized, storable zirconium tetraacetate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB946318A true GB946318A (en) | 1964-01-08 |
Family
ID=7123604
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB43084/60A Expired GB946318A (en) | 1960-01-29 | 1960-12-14 | Method of producing an anhydrous crystalline zirconium tetraacetate |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE599270A (en) |
| CH (1) | CH420085A (en) |
| DE (1) | DE1148992B (en) |
| GB (1) | GB946318A (en) |
-
1960
- 1960-01-29 DE DEG28916A patent/DE1148992B/en active Pending
- 1960-11-26 CH CH1332860A patent/CH420085A/en unknown
- 1960-12-14 GB GB43084/60A patent/GB946318A/en not_active Expired
-
1961
- 1961-01-19 BE BE599270A patent/BE599270A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE1148992B (en) | 1963-05-22 |
| BE599270A (en) | 1961-05-16 |
| CH420085A (en) | 1966-09-15 |
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