US3085039A - Process for the treatment of wood - Google Patents
Process for the treatment of wood Download PDFInfo
- Publication number
- US3085039A US3085039A US51273A US5127360A US3085039A US 3085039 A US3085039 A US 3085039A US 51273 A US51273 A US 51273A US 5127360 A US5127360 A US 5127360A US 3085039 A US3085039 A US 3085039A
- Authority
- US
- United States
- Prior art keywords
- wood
- treatment
- decortication
- oxygen
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002023 wood Substances 0.000 title claims description 42
- 238000000034 method Methods 0.000 title claims description 21
- 238000011282 treatment Methods 0.000 title claims description 16
- 230000007935 neutral effect Effects 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 claims description 2
- 239000000835 fiber Substances 0.000 description 9
- 239000000126 substance Substances 0.000 description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 7
- 238000004061 bleaching Methods 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 239000002657 fibrous material Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 241000218657 Picea Species 0.000 description 1
- 241000219000 Populus Species 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000010875 treated wood Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27L—REMOVING BARK OR VESTIGES OF BRANCHES; SPLITTING WOOD; MANUFACTURE OF VENEER, WOODEN STICKS, WOOD SHAVINGS, WOOD FIBRES OR WOOD POWDER
- B27L3/00—Debarking by chemical treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27L—REMOVING BARK OR VESTIGES OF BRANCHES; SPLITTING WOOD; MANUFACTURE OF VENEER, WOODEN STICKS, WOOD SHAVINGS, WOOD FIBRES OR WOOD POWDER
- B27L1/00—Debarking or removing vestiges of branches from trees or logs; Machines therefor
- B27L1/02—Debarking or removing vestiges of branches from trees or logs; Machines therefor by rubbing the trunks against each other; Equipment for wet practice
Definitions
- Active-oxygen compounds such as H 0 peracids, or their salts, for example peracetic acid and perborates, are compounds which liberate oxygen and are useful in the process of the present invention. They are employed as aqueous solutions in an amount to provide the amount of active-oxygen present in about l-40%, and preferably about 320% of 100% hydrogen peroxide.
- the wood In the process of the present invention, it is not necessary to subject the wood to a mechanical treatment before it is contacted with the active-oxygen compound, as has hitherto been customary in the preparation of fibers.
- the process is preferably carried out on undisintegrated wood.
- the treatment can also advantageously be carried out on disintegrated wood, and results in better cleaning of the wood and removal of bark from it.
- the pressure applied in the present treatment advantageously will be about 4-15 atmospheres gauge.
- the process is carried out at or around room temperature, normally at about 20 C. to C. Under these conditions, a high concentration of chemicals can be ob tained in the wood.
- Wood treated in this way can be freed from bark and hast in decortication tunnels much more easily than wood treated with steam according to known processes. A completely clean decortication is obtained even in branch positions, where rings of bark or bast often provide difficulty. As one desirable result of the present treatment the hast, which is very strongly bound to the wood, is forced off from within and hangs very loosely from the wood, so that it is very easily removed.
- wood treated in this way is put into a decortication drum, it is possible to obtain complete decortication in a sub stantially briefer time than in the case of wood which for example has been pretreated with steam at 96 C. for four hours. The faces of the wood pieces are likewise cleaned, so that they no longer must be cut off and discarded as is customary where dirty wood is treated considerable saving in manpower and lessened wood loss.
- the wood is advantageously impregnated with the present aqueous solutions of active-oxygen compounds in a pressure tank, for example, at about 4-15 atmospheres gauge pressure for about 2-4 hours. Following this, it may be directly introduced into a decoriication drum in which it is tumbled, and loosened bark and bast are abraded from it. Surprisingly, practically no active-oxygen loss due to decomposition results from this treatment, even with the application of a very highly concentrated peroxide. When alkaline solutions were used, for example in caustic bleaching processes, substantially larger losses result. This new process accordingly differs from past processes in that the peroxidic compounds liberating oxygen are applied in about neutral or weakly acidic solutions, preferably at room temperature and at an elevated pressure.
- Woods pretreated by the present method are surprisingly clean. They are much cleaner than steam-treated wood, which is brownish and not completely free of bast, and therefore they introduce substantially no impurities into subsequent operations, such as bleaching. This means that the finished product is much cleaner and accordingly of greater quality both in appearance and physically.
- a further advantage of the present process is that as long as the active-oxygen chemicals are present in the wood, a slow oxidation takes place even in a neutral or acid medium. It is known that the amount of oxygen liberation from these chemicals can be increased by raising the temperature, or by adding alkalies. Oxidation within the fiber structure can thus be accelerated at any desired time. Accordingly, due to the superior ability of the present neutral or acid solutions to penetrate the wood, chemical reactions can be caused to take place within timbers of substantially any thickness. These reactions have the surprising advantage that in addition to the expected bleaching which takes place, a marked disintegration of the fiber structure is provided.
- Example 1 Five cubic meters of spruce wood was impregnated in a pressure tank made of refined steel with an 8% hydrogen peroxide solution at a pressure of 7 atmospheres gauge pressure for 3 hours. After this treatment, the wood was decorticated and processed further in a decortication drum in a usual and known way. The product was clean and free of bast and bark.
- Example 2 Five cubic meters of poplar wood was treated in a pressure tank with a 6% peracetic solution at room temperature and a pressure of 8 atmospheres gauge pressure for two hours. The wood was then freed of bark and bast by means of drum decorticat ion, and was then 4 processed in a four-press grinder to form mechanical wood pulp. The pulp was of high purity and free of bast and bark particles.
- Process for the treatment of undecorticated wood comprising impregnating the Wood with a neutral to acidic aqueous solution of a peroxy-containing activeoxygen compound at a pressure of about 4 to 15 atmos pheres and at a temperature below about 60 C.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Description
United States Patent Ofifice 3,085,039 Patented Apr. 9, 1963 3,085,039 PROCESS FOR THE TREATMENT OF WOOD Wilhelm Giirtner, Neunkirchen, Germany, assignor, by mesne assignments, to FMC Corporation, New York, N.Y., a corporation of Delaware N Drawing. Filed Aug. 23, 1960, Ser. No. 51,273 4 Claims. (Cl. 162-78) This invention relates to the decortication and peeling of wood, by a process which renders the Wood particularly receptive to subsequent treatments in the production of fibrous products.
In the preparation of fibrous materials from vegetable raw materials, it is becoming increasingly important to provide a high degree of whiteness and purity in the fibers. Mechanical and chemical purification and bleaching processes for such fibrous materials have been highly developed, with processing frequently being carried out in several stages. Normally, the wood is decorticated or washed before it is subdivided mechanically or chemically into fibers, and the bleaching process is carried out as a distinct step thereafter.
Previous decortication methods have not been satisfactory, and have reduced the efficiency of subsequent treatments. Contaminants not removed in the decortication follow through to finished products, which include fine writing papers. In some cases, the contaminants make it impossible to upgrade the fibers, and at best they make necessary a greater expenditure of chemicals for bleaching and other purification treatments.
For these and other reasons, it is important to remove as many of the natural impurities as possible from the fibers before they are bleached. However, it has been found in practice that this cannot be achieved without undue losses in fiber substance, or in other reduction of quality, for example, in the decolorizing of the fibers which occurs when they are pretreated with steam. Removal of steaming-induced brown colorants, or of best and bark particles carried over from the wood, causes great difficulties in the treatment and application of the finished fibrous material. These contaminants often cannot be removed by the chemicals used for later process ing, such as the peroxide used in bleaching.
The processing involved in decortication and peeling of wood also has presented a problem. For example, it has been considered necessary to treat the wood for a long time in a decortication drum and subsequently to sort the product by hand to eliminate poor grade materials. It also has been considered necessary to cut off the dirty faces of round timbers, thus providing considerable wood losses and additional labor.
It has now been found that the above difficulties can be avoided if wood, preferably undecorticated wood, is treated with aqueous solution of active-oxygen compounds in an about neutral to acid medium, and under superatmospheric pressures at temperatures below about 60 C.
Active-oxygen compounds such as H 0 peracids, or their salts, for example peracetic acid and perborates, are compounds which liberate oxygen and are useful in the process of the present invention. They are employed as aqueous solutions in an amount to provide the amount of active-oxygen present in about l-40%, and preferably about 320% of 100% hydrogen peroxide.
In the process of the present invention, it is not necessary to subject the wood to a mechanical treatment before it is contacted with the active-oxygen compound, as has hitherto been customary in the preparation of fibers. The process is preferably carried out on undisintegrated wood. However, the treatment can also advantageously be carried out on disintegrated wood, and results in better cleaning of the wood and removal of bark from it.
The pressure applied in the present treatment advantageously will be about 4-15 atmospheres gauge. The process is carried out at or around room temperature, normally at about 20 C. to C. Under these conditions, a high concentration of chemicals can be ob tained in the wood.
Operation at an acid or neutral pH makes it possible to compress large amounts of the present chemicals into the wood. When alkaline solutions are used, this is not possible because of the alkali-induced swelling of the wood. When the present acid or neutral solutions are compressed into the wood, a reaction begins within the wood whereby bark and bast, as well as other impurities still adhering to the wood, are forced from the surface of the wood.
Wood treated in this way can be freed from bark and hast in decortication tunnels much more easily than wood treated with steam according to known processes. A completely clean decortication is obtained even in branch positions, where rings of bark or bast often provide difficulty. As one desirable result of the present treatment the hast, which is very strongly bound to the wood, is forced off from within and hangs very loosely from the wood, so that it is very easily removed. When wood treated in this way is put into a decortication drum, it is possible to obtain complete decortication in a sub stantially briefer time than in the case of wood which for example has been pretreated with steam at 96 C. for four hours. The faces of the wood pieces are likewise cleaned, so that they no longer must be cut off and discarded as is customary where dirty wood is treated considerable saving in manpower and lessened wood loss.
The wood is advantageously impregnated with the present aqueous solutions of active-oxygen compounds in a pressure tank, for example, at about 4-15 atmospheres gauge pressure for about 2-4 hours. Following this, it may be directly introduced into a decoriication drum in which it is tumbled, and loosened bark and bast are abraded from it. Surprisingly, practically no active-oxygen loss due to decomposition results from this treatment, even with the application of a very highly concentrated peroxide. When alkaline solutions were used, for example in caustic bleaching processes, substantially larger losses result. This new process accordingly differs from past processes in that the peroxidic compounds liberating oxygen are applied in about neutral or weakly acidic solutions, preferably at room temperature and at an elevated pressure.
Woods pretreated by the present method are surprisingly clean. They are much cleaner than steam-treated wood, which is brownish and not completely free of bast, and therefore they introduce substantially no impurities into subsequent operations, such as bleaching. This means that the finished product is much cleaner and accordingly of greater quality both in appearance and physically.
A further advantage of the present process is that as long as the active-oxygen chemicals are present in the wood, a slow oxidation takes place even in a neutral or acid medium. It is known that the amount of oxygen liberation from these chemicals can be increased by raising the temperature, or by adding alkalies. Oxidation within the fiber structure can thus be accelerated at any desired time. Accordingly, due to the superior ability of the present neutral or acid solutions to penetrate the wood, chemical reactions can be caused to take place within timbers of substantially any thickness. These reactions have the surprising advantage that in addition to the expected bleaching which takes place, a marked disintegration of the fiber structure is provided. Accordingly, later disintegration is facilitated by the present treatment of the raw material, and at the same time a Example 1 Five cubic meters of spruce wood was impregnated in a pressure tank made of refined steel with an 8% hydrogen peroxide solution at a pressure of 7 atmospheres gauge pressure for 3 hours. After this treatment, the wood was decorticated and processed further in a decortication drum in a usual and known way. The product was clean and free of bast and bark.
Example 2 Five cubic meters of poplar wood was treated in a pressure tank with a 6% peracetic solution at room temperature and a pressure of 8 atmospheres gauge pressure for two hours. The wood was then freed of bark and bast by means of drum decorticat ion, and was then 4 processed in a four-press grinder to form mechanical wood pulp. The pulp was of high purity and free of bast and bark particles.
What is claimed is:
1. Process for the treatment of undecorticated wood, comprising impregnating the Wood with a neutral to acidic aqueous solution of a peroxy-containing activeoxygen compound at a pressure of about 4 to 15 atmos pheres and at a temperature below about 60 C.
2. Process in accordance with claim 1, wherein the treatment takes place at about room temperature.
3. Processes in accordance with claim 1, wherein an aqueous solution is employed which contains the peroxy-eontaining active-oxygen compound in an amount of about 1 to 40%, calculated as hydrogen peroxide.
4. Process in accordance with claim 3, wherein the peroxy-containing active-oxygen compound is present in an amount of about 3 to 20%, calculated as hydrogen peroxide.
MacMahon Sept. 26, 1944 Dreyfus Feb. 19, 1946
Claims (1)
1. PROCESS FOR THE TREATMENT OF UNDECORTICATED WOOD, COMPRISING IMPREGNATING THE WOOD WITH A NEUTRAL TO ACIDIC AQUEOUS SOLUTION OF A PEROXY-CONTAINING ACTIVEOXYGEN COMPOUND AT A PRESSURE OF ABOUT 4 TO 15 ATMOSPHERES AND AT A TEMPERATURE BELOW ABOUT 60*C.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US51273A US3085039A (en) | 1960-08-23 | 1960-08-23 | Process for the treatment of wood |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US51273A US3085039A (en) | 1960-08-23 | 1960-08-23 | Process for the treatment of wood |
Publications (1)
Publication Number | Publication Date |
---|---|
US3085039A true US3085039A (en) | 1963-04-09 |
Family
ID=21970292
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US51273A Expired - Lifetime US3085039A (en) | 1960-08-23 | 1960-08-23 | Process for the treatment of wood |
Country Status (1)
Country | Link |
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US (1) | US3085039A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3193445A (en) * | 1962-07-16 | 1965-07-06 | Pittsburgh Plate Glass Co | Method of bleaching cellulosic materials with hydrogen peroxide |
US3458394A (en) * | 1965-10-08 | 1969-07-29 | Scott Paper Co | Pulping wood chips with peracetic acid and chlorine dioxide |
US3467575A (en) * | 1964-08-13 | 1969-09-16 | Hooker Chemical Corp | Process of bleaching paper with peracetic acid |
US3867246A (en) * | 1972-04-21 | 1975-02-18 | Degussa | Chlorine-free multiple step bleaching of cellulose |
US4966601A (en) * | 1986-03-21 | 1990-10-30 | Klaus Draenert | Evacuatable bone cement syringe |
EP0435061A2 (en) * | 1989-12-27 | 1991-07-03 | Kone Oy | Procedure for the debarking of logs |
US20070125507A1 (en) * | 2005-12-02 | 2007-06-07 | Akzo Nobel N.V. | Process of producing high-yield pulp |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2358866A (en) * | 1943-08-13 | 1944-09-26 | Mathieson Alkali Works Inc | Acid aqueous solutions of chlorites |
US2394989A (en) * | 1942-03-11 | 1946-02-19 | Bonard Claude | Manufacture of cellulose |
-
1960
- 1960-08-23 US US51273A patent/US3085039A/en not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2394989A (en) * | 1942-03-11 | 1946-02-19 | Bonard Claude | Manufacture of cellulose |
US2358866A (en) * | 1943-08-13 | 1944-09-26 | Mathieson Alkali Works Inc | Acid aqueous solutions of chlorites |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3193445A (en) * | 1962-07-16 | 1965-07-06 | Pittsburgh Plate Glass Co | Method of bleaching cellulosic materials with hydrogen peroxide |
US3467575A (en) * | 1964-08-13 | 1969-09-16 | Hooker Chemical Corp | Process of bleaching paper with peracetic acid |
US3458394A (en) * | 1965-10-08 | 1969-07-29 | Scott Paper Co | Pulping wood chips with peracetic acid and chlorine dioxide |
US3867246A (en) * | 1972-04-21 | 1975-02-18 | Degussa | Chlorine-free multiple step bleaching of cellulose |
US4966601A (en) * | 1986-03-21 | 1990-10-30 | Klaus Draenert | Evacuatable bone cement syringe |
EP0435061A2 (en) * | 1989-12-27 | 1991-07-03 | Kone Oy | Procedure for the debarking of logs |
EP0435061A3 (en) * | 1989-12-27 | 1991-10-16 | Kone Oy | Procedure for the debarking of logs |
US20070125507A1 (en) * | 2005-12-02 | 2007-06-07 | Akzo Nobel N.V. | Process of producing high-yield pulp |
US8268122B2 (en) * | 2005-12-02 | 2012-09-18 | Akzo Nobel N.V. | Process of producing high-yield pulp |
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