GB905215A - Improvements in or relating to reproduction coatings for the preparation of images by the action of heat - Google Patents
Improvements in or relating to reproduction coatings for the preparation of images by the action of heatInfo
- Publication number
- GB905215A GB905215A GB26042/59A GB2604259A GB905215A GB 905215 A GB905215 A GB 905215A GB 26042/59 A GB26042/59 A GB 26042/59A GB 2604259 A GB2604259 A GB 2604259A GB 905215 A GB905215 A GB 905215A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- coating
- primary amine
- copying
- ketohydrindene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
- B41M5/323—Organic colour formers, e.g. leuco dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
Abstract
905,215. Thermographic copying materials. KALLE & CO. A.G. July 29, 1959 [Aug. 9, 1958], No. 26042/59. Class 98 (2). Thermographic copying materials consist of a support bearing an adherent coating containing (a) an aminocarboxylic acid, or a salt formed from a primary amine and an organic carboxylic or sulphonic acid, in combination with (b) a' ketohydrindene having 2, 3, or 4 reactive carbonyl groups, e.g. in the ratio of (a): (b) of 5 to 8: 1. The ketohydrindene may be 1: 3-diketohydrindene or its 2-(1<SP>1</SP>-ketohydrindenylidene-3<SP>1</SP>) or 2-(1<SP>1</SP>-keto-2<SP>1</SP>-bromo-hydrindenylidene-3<SP>1</SP>) derivatives, bis-diketohydrindene, or 1 : 2 : 3-triketohydrindene; the aminocarboxylic acid may be #-(3<SP>1</SP>-aminophenyl) propionic acid or 4-aminobenzoic acid; the primary amine may be aniline, benzylamine, 4 : 4<SP>1</SP>-diaminodiphenylmethane, 4-amino-diphenyl, 4-amino- 1-(m)ethoxy-benzene, n-hexylamine, n-octylamine, or 2-aminopyridine; the organic acids may be acetic acid or its chloro, bromo, cyano or phenyl derivatives, bromopropionic acid, cinnamic, malonic or benzoic acids, α-naphthalene sulphonic acid, or 4-toluene sulphonic acid. The coating is prepared by suspending the components (a) and (b) in a solution of a binder, the primary amine and organic acid being, if desired, added separately and not as a salt, applying the coating to the support and drying the coating as with a current of air at a temperature not above 40 C. Suitable binders are cyclized rubber, maleic acid-polyalcohol resins, colophony, modified colophony resins, and polymethacrylate esters and the solvents used may be aliphatic hydrocarbons, including mixtures such as petrol and ligroin, or hydrocarbon halides. The supports specified are all transparent and comprise glass, transparent paper, regenerated cellulose, cellulose acetate, and polyvinyl chloride. Copying may be effected by reflex or direct copying with radiant heat or by means of a heated stylus or stamp.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEK35503A DE1109712B (en) | 1958-08-09 | 1958-08-09 | Copy layers for producing images by heat |
Publications (1)
Publication Number | Publication Date |
---|---|
GB905215A true GB905215A (en) | 1962-09-05 |
Family
ID=7220372
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB26042/59A Expired GB905215A (en) | 1958-08-09 | 1959-07-29 | Improvements in or relating to reproduction coatings for the preparation of images by the action of heat |
Country Status (4)
Country | Link |
---|---|
US (1) | US3024362A (en) |
DE (1) | DE1109712B (en) |
FR (1) | FR1240124A (en) |
GB (1) | GB905215A (en) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3301697A (en) * | 1960-12-02 | 1967-01-31 | Robert B Russell | Thermographic transfer sheet having a support of a paper and plastic coating and the method of use |
US3129109A (en) * | 1961-09-25 | 1964-04-14 | Minnesota Mining & Mfg | Heat-sensitive copy-sheet |
NL287455A (en) * | 1962-01-05 | 1900-01-01 | ||
BE627029A (en) * | 1962-01-18 | |||
US3161770A (en) * | 1962-03-20 | 1964-12-15 | Dietzgen Co Eugene | Thermographic reproduction paper and method of using |
US3162763A (en) * | 1962-04-05 | 1964-12-22 | Dietzgen Co Eugene | Thermographic reproduction paper, method of making and method of using |
US3167651A (en) * | 1962-05-15 | 1965-01-26 | Dietzgen Co Eugene | Thermographic reproduction paper and method of making and using |
US3174038A (en) * | 1962-06-18 | 1965-03-16 | Dietzgen Co Eugene | Thermographic reproduction paper and method of using |
BE632833A (en) * | 1962-06-29 | |||
US3166433A (en) * | 1962-08-01 | 1965-01-19 | Nashua Corp | Heat sensitive copy and recording sheet |
US3185583A (en) * | 1962-11-19 | 1965-05-25 | Nashua Corp | Heat responsive marking sheets |
US3167444A (en) * | 1962-11-19 | 1965-01-26 | Nashua Corp | Heat responsive marking sheets |
US3185585A (en) * | 1962-11-19 | 1965-05-25 | Nashua Corp | Heat responsive marking sheets |
US3185584A (en) * | 1962-11-19 | 1965-05-25 | Nashua Corp | Heat responsive marking sheets |
US3293061A (en) * | 1963-11-21 | 1966-12-20 | Man Res Lab Inc | Primary amine modified secondary or tertiary amine-polyketo reaction product in a heat developable copy sheet |
US3770442A (en) * | 1971-10-15 | 1973-11-06 | Minnesota Mining & Mfg | Stabilized light-sensitive intermediate sheet |
US4061831A (en) * | 1976-04-13 | 1977-12-06 | Bard Laboratories, Inc. | Thermal recording system |
US4061836A (en) * | 1976-04-13 | 1977-12-06 | Bard Laboratories, Inc. | Thermographic recording system |
US4082555A (en) * | 1976-08-18 | 1978-04-04 | Eastman Kodak Company | Photothermographic materials and process |
US4111703A (en) * | 1977-02-25 | 1978-09-05 | Graphic Controls Corporation | Heat-sensitive coating composition with 4-aromatic and hydroxy substituted piperidine derivative and cyclic polyketo compound |
GB1565776A (en) * | 1977-03-04 | 1980-04-23 | Lawton W | Heat-sensitive recording composition |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2680062A (en) * | 1949-07-23 | 1954-06-01 | Keuffel & Esser Co | Process for the production of azo dyestuff images |
USRE24554E (en) * | 1951-02-02 | 1958-10-21 | Heat-sensitive copying-paper | |
CA535267A (en) * | 1952-05-15 | 1957-01-01 | Minnesota Mining And Manufacturing Company | Physical-mixture heat-sensitive copying-paper |
US2732286A (en) * | 1953-09-30 | 1956-01-24 | Propstl | |
NL113884C (en) * | 1956-04-02 | |||
BE558766A (en) * | 1956-06-28 | 1900-01-01 | ||
US2962382A (en) * | 1958-02-25 | 1960-11-29 | Ludlow Corp | Sheet recording material and method of making same |
US2899334A (en) * | 1958-05-19 | 1959-08-11 | Heat-sensitive layer | |
BE593980A (en) * | 1959-08-14 |
-
1958
- 1958-08-09 DE DEK35503A patent/DE1109712B/en active Pending
-
1959
- 1959-07-16 US US827426A patent/US3024362A/en not_active Expired - Lifetime
- 1959-07-29 GB GB26042/59A patent/GB905215A/en not_active Expired
- 1959-08-07 FR FR802311A patent/FR1240124A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE1109712B (en) | 1961-06-29 |
FR1240124A (en) | 1960-09-02 |
US3024362A (en) | 1962-03-06 |
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