GB815005A - Improvements in or relating to radiation-sensitive diazotype materials - Google Patents
Improvements in or relating to radiation-sensitive diazotype materialsInfo
- Publication number
- GB815005A GB815005A GB2967356A GB2967356A GB815005A GB 815005 A GB815005 A GB 815005A GB 2967356 A GB2967356 A GB 2967356A GB 2967356 A GB2967356 A GB 2967356A GB 815005 A GB815005 A GB 815005A
- Authority
- GB
- United Kingdom
- Prior art keywords
- layer
- exposure
- diazo compound
- heat
- image
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 title abstract 5
- 230000005855 radiation Effects 0.000 title abstract 3
- 150000008049 diazo compounds Chemical class 0.000 abstract 5
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 abstract 2
- 239000011248 coating agent Substances 0.000 abstract 2
- 238000000576 coating method Methods 0.000 abstract 2
- 230000008878 coupling Effects 0.000 abstract 2
- 238000010168 coupling process Methods 0.000 abstract 2
- 238000005859 coupling reaction Methods 0.000 abstract 2
- 230000000694 effects Effects 0.000 abstract 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 abstract 1
- 239000011358 absorbing material Substances 0.000 abstract 1
- 239000000987 azo dye Substances 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 229920002301 cellulose acetate Polymers 0.000 abstract 1
- BADXJIPKFRBFOT-UHFFFAOYSA-N dimedone Chemical compound CC1(C)CC(=O)CC(=O)C1 BADXJIPKFRBFOT-UHFFFAOYSA-N 0.000 abstract 1
- 238000003618 dip coating Methods 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 230000004927 fusion Effects 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052753 mercury Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- 230000002028 premature Effects 0.000 abstract 1
- 239000011253 protective coating Substances 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/52—Compositions containing diazo compounds as photosensitive substances
- G03C1/60—Compositions containing diazo compounds as photosensitive substances with macromolecular additives
Landscapes
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Abstract
815,005. Photographic diazotype materials. ILFORD Ltd. Nov. 18, 1957 [Sept. 28, 1956; July 3, 1957], Nos. 29673/56 and 21027/57. Class 98(2) A two-component material comprises in order a layer containing a diazo compound, a fusible layer, and a layer containing a coupler, the whole carried on a sheet or film support which latter may be on either side. The material may be made by coating the layers on the support but preferably the layer applied on to the fusible layer, either that containing the diazo compound or the coupler according to the order of coating, is applied by spraying to prevent any tendency to effect fusion and hence premature coupling. In an example a methanol solution of 4-ptolythio - 2 : 5 - diethoxy benzene diazouium zincichloride is coated on to tracing paper by a roller and scraper technique and dried, the second layer is paraffin wax of melting point 60‹C. applied by dip coating from a molten bath thereof, when cold the coupler layer of dimedone and stearylamine in chloroform, is sprayed on, and finally the material is sprayed with an ethyl acetate solution of cellulose acetate to provide a protective coating. A second example specifies similarly 4 - benzoylamino - 2 : 5 - diethoxy benzene diazonium chloride as sensitizer and resorcinol as coupler. Exposure of these materiels to light through a suitable master and heating to about 80-100‹C. produces respectively orange and brown images on clear white backgrounds. Exposure by a mercury vapour lamp may provide sufficient heat in the case where the master carries an image in radiation absorbing material, such as printer's ink, carbon or silver, to ensure dye production in image areas while destroying the diazo compound in non-image areas and thus leave the product stable to subsequently applied heat or light. Exposure by heat or infra-red only may be without effect on the diazo compound of the non-image areas and these may subsequently be destroyed by daylight or ultra-violet radiation, or may be separately coupled to form a background in azo dye of different colour to that of the image areas, or may be used to apply a second image by light exposure and coupling, or a second image by a second heat or infra-red exposure. Diazotized 1 - amino - 2 : 6 - dimethoxy benzene is quoted as a diazo compound of high-heat stability for these purposes. Other substances for the fusible layer are indicated. Specification 759,045 is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2102757 | 1957-07-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB815005A true GB815005A (en) | 1959-06-17 |
Family
ID=10155955
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2967356A Expired GB815005A (en) | 1957-07-03 | 1956-09-28 | Improvements in or relating to radiation-sensitive diazotype materials |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB815005A (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3194660A (en) * | 1961-06-26 | 1965-07-13 | Ibm | Reflex copying method |
| US3194659A (en) * | 1961-03-06 | 1965-07-13 | Kalvar Corp | Reflex copying method using heat developable light scattering materials |
| US3281244A (en) * | 1962-01-27 | 1966-10-25 | Keuffel & Esser Co | Heat-developable two-component diazotype reproduction material |
| US3284201A (en) * | 1961-12-21 | 1966-11-08 | Grinten Chem L V D | Three layered light-sensitive diazotype material |
| US3294534A (en) * | 1963-05-31 | 1966-12-27 | Gen Aniline & Film Corp | Diazotype photoprinting material susceptible to thermal development |
| US3380830A (en) * | 1963-09-24 | 1968-04-30 | Bauchet & Cie | Heat developable diazo photocopying sheet |
| US3418120A (en) * | 1965-12-28 | 1968-12-24 | Ibm | Method for developing one-component diazotype materials |
| US3620740A (en) * | 1968-01-09 | 1971-11-16 | Agfa Gevaert Nv | Thermodiazo-type copying |
| US3976488A (en) * | 1969-02-19 | 1976-08-24 | Mita Industrial Company, Ltd. | Treating agent for diazo-type multicolor reproduction |
| US3981730A (en) * | 1973-04-18 | 1976-09-21 | Mita Industrial Company, Ltd. | Diazo-type multicolor reproduction process |
| FR2470984A1 (en) * | 1979-11-28 | 1981-06-12 | Schaeffer Andre | DIAZOTYPE MATERIAL DEVELOPABLE BY VAPOR, WATER OR HEAT |
| EP0065053A1 (en) * | 1981-05-20 | 1982-11-24 | INTERNATIONAL DIAZO CHAPEL et Cie Société dite | Diazotype material to be developed by heat, water or vapour |
| GB2526531A (en) * | 2014-04-30 | 2015-12-02 | Rue De Int Ltd | Security device components and methods of manufacture thereof |
-
1956
- 1956-09-28 GB GB2967356A patent/GB815005A/en not_active Expired
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3194659A (en) * | 1961-03-06 | 1965-07-13 | Kalvar Corp | Reflex copying method using heat developable light scattering materials |
| US3194660A (en) * | 1961-06-26 | 1965-07-13 | Ibm | Reflex copying method |
| US3284201A (en) * | 1961-12-21 | 1966-11-08 | Grinten Chem L V D | Three layered light-sensitive diazotype material |
| US3281244A (en) * | 1962-01-27 | 1966-10-25 | Keuffel & Esser Co | Heat-developable two-component diazotype reproduction material |
| US3294534A (en) * | 1963-05-31 | 1966-12-27 | Gen Aniline & Film Corp | Diazotype photoprinting material susceptible to thermal development |
| US3380830A (en) * | 1963-09-24 | 1968-04-30 | Bauchet & Cie | Heat developable diazo photocopying sheet |
| US3418120A (en) * | 1965-12-28 | 1968-12-24 | Ibm | Method for developing one-component diazotype materials |
| US3620740A (en) * | 1968-01-09 | 1971-11-16 | Agfa Gevaert Nv | Thermodiazo-type copying |
| US3976488A (en) * | 1969-02-19 | 1976-08-24 | Mita Industrial Company, Ltd. | Treating agent for diazo-type multicolor reproduction |
| US3981730A (en) * | 1973-04-18 | 1976-09-21 | Mita Industrial Company, Ltd. | Diazo-type multicolor reproduction process |
| FR2470984A1 (en) * | 1979-11-28 | 1981-06-12 | Schaeffer Andre | DIAZOTYPE MATERIAL DEVELOPABLE BY VAPOR, WATER OR HEAT |
| EP0065053A1 (en) * | 1981-05-20 | 1982-11-24 | INTERNATIONAL DIAZO CHAPEL et Cie Société dite | Diazotype material to be developed by heat, water or vapour |
| GB2526531A (en) * | 2014-04-30 | 2015-12-02 | Rue De Int Ltd | Security device components and methods of manufacture thereof |
| GB2526531B (en) * | 2014-04-30 | 2017-08-30 | De La Rue Int Ltd | Security device components and methods of manufacture thereof |
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