GB859261A - Improvements in the control of oxidative reactions - Google Patents

Improvements in the control of oxidative reactions

Info

Publication number
GB859261A
GB859261A GB3714257A GB3714257A GB859261A GB 859261 A GB859261 A GB 859261A GB 3714257 A GB3714257 A GB 3714257A GB 3714257 A GB3714257 A GB 3714257A GB 859261 A GB859261 A GB 859261A
Authority
GB
United Kingdom
Prior art keywords
deterioration
triethylene tetramine
organic materials
aminoethyl piperazine
preserved
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3714257A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RALPH LYNDAL WORRALL
Original Assignee
RALPH LYNDAL WORRALL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by RALPH LYNDAL WORRALL filed Critical RALPH LYNDAL WORRALL
Priority to GB3714257A priority Critical patent/GB859261A/en
Publication of GB859261A publication Critical patent/GB859261A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
    • C07D487/08—Bridged systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/30—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing heterocyclic ring with at least one nitrogen atom as ring member
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B5/00—Preserving by using additives, e.g. anti-oxidants
    • C11B5/0042—Preserving by using additives, e.g. anti-oxidants containing nitrogen
    • C11B5/0064—Heterocyclic compounds containing nitrogen in the ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/221—Six-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C10M2215/226—Morpholines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/26—Amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/30—Heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/046—Polyamines, i.e. macromoleculars obtained by condensation of more than eleven amine monomers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound

Abstract

Organic materials liable to deterioration through peroxide formation are preserved by adding or applying thereto N-aminoethyl piperazine, triethylene tetramine or a metal chelate thereof. A specific chelate compound which is mentioned is ferric hydroxide triethylene tetramine. The antioxidants are effective in preventing the perishing of rubber.ALSO:Organic materials liable to deterioration through peroxide formation are preserved by adding or applying thereto N-aminoethyl piperazine, triethylene tetramine or a metal chelate thereof. A specific chelate compound which is mentioned is ferric hydroxide triethylene tetramine. The deterioration may be (1) rancidification of edible vegetable oils, (2) deterioration of volatile oils or solvents, including those used in perfumery, (3) deterioration of mineral lubricating oils, (4) excessive drying and chalking of paints, (5) perishing of rubber, (6) degradation of synthetic plastics, (7) fading of dyes, (8) rotting of textiles, (9) deteriorating of leather, (10( deterioration of paper or (11) metabolic disorder in living organisms involving abnormal peroxide formation. In the examples, (a) one drop of N-aminoethyl piperazine is added to 2 litres of diethyl ether and (b) a sheet of white typing paper is dipped into a solution (consisting of 2 drops of N-aminoethyl piperazine in 1 litre of water) and then allowed to dry. According to the Provisional Specification, the organic materials, to which the antioxidant may be added, include liquid fuels such as petrol (wherein the additive acts as an antiknock agent), and spermatazoa for use in artificial insemination.ALSO:Organic materials liable to deterioration through peroxide formation are preserved by adding or applying thereto N-aminoethyl piperazine, triethylene tetramine or a metal chelate thereof. A specific chelate compound which is mentioned is ferric hydroxide triethylene tetramine. The deterioration may be (1) rancidification of edible vegetable oils, (2) deterioration of volatile oils, including those used in perfumery, (3) deterioration of mineral lubricating oils or (4) excessive drying and chalking of paints. According to the Provisional Specification, the additive acts as an antiknock agent when added to liquid fuels, such as petrol.ALSO:Organic materials liable to deterioriation through peroxide formation are preserved by adding or applying thereto N-aminoethyl piperazine, triethylene tetramine of a metal chelate thereof. A specific chelate compound which is mentioned is ferric hydroxide triethylene tetramine. The deterioration may be (1) rancidification of edible vegetable oils, (2) rotting of textiles or (3) deterioration of leather. According to the Provisional Specification, the organic materials include spermatozoa for use in artificial insemination.
GB3714257A 1957-11-28 1957-11-28 Improvements in the control of oxidative reactions Expired GB859261A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB3714257A GB859261A (en) 1957-11-28 1957-11-28 Improvements in the control of oxidative reactions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3714257A GB859261A (en) 1957-11-28 1957-11-28 Improvements in the control of oxidative reactions

Publications (1)

Publication Number Publication Date
GB859261A true GB859261A (en) 1961-01-18

Family

ID=10394091

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3714257A Expired GB859261A (en) 1957-11-28 1957-11-28 Improvements in the control of oxidative reactions

Country Status (1)

Country Link
GB (1) GB859261A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007143309A1 (en) * 2006-05-31 2007-12-13 Dow Global Technologies Inc. Removal of trace amounts of metal contaminants from organic solvent process streams

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007143309A1 (en) * 2006-05-31 2007-12-13 Dow Global Technologies Inc. Removal of trace amounts of metal contaminants from organic solvent process streams

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