GB828791A - Method of selectively polymerising alpha-olefins - Google Patents
Method of selectively polymerising alpha-olefinsInfo
- Publication number
- GB828791A GB828791A GB34154/55A GB3415455A GB828791A GB 828791 A GB828791 A GB 828791A GB 34154/55 A GB34154/55 A GB 34154/55A GB 3415455 A GB3415455 A GB 3415455A GB 828791 A GB828791 A GB 828791A
- Authority
- GB
- United Kingdom
- Prior art keywords
- solid
- catalyst
- metal
- alet3
- catalysts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004711 α-olefin Substances 0.000 title 1
- 239000007787 solid Substances 0.000 abstract 13
- 239000003054 catalyst Substances 0.000 abstract 12
- 229910052751 metal Inorganic materials 0.000 abstract 6
- 239000002184 metal Substances 0.000 abstract 6
- 125000000217 alkyl group Chemical group 0.000 abstract 5
- 239000000463 material Substances 0.000 abstract 5
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 abstract 5
- 229920000642 polymer Polymers 0.000 abstract 4
- 239000000047 product Substances 0.000 abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 229910021552 Vanadium(IV) chloride Inorganic materials 0.000 abstract 3
- 238000004519 manufacturing process Methods 0.000 abstract 3
- -1 oxyhalides Chemical class 0.000 abstract 3
- 238000006116 polymerization reaction Methods 0.000 abstract 3
- JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical compound Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 229910003074 TiCl4 Inorganic materials 0.000 abstract 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 2
- 150000004703 alkoxides Chemical class 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 229910052804 chromium Inorganic materials 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 238000010908 decantation Methods 0.000 abstract 2
- 239000006185 dispersion Substances 0.000 abstract 2
- 238000001914 filtration Methods 0.000 abstract 2
- 150000004820 halides Chemical class 0.000 abstract 2
- 150000004679 hydroxides Chemical class 0.000 abstract 2
- 150000002899 organoaluminium compounds Chemical class 0.000 abstract 2
- 238000000926 separation method Methods 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract 2
- 229910052721 tungsten Inorganic materials 0.000 abstract 2
- 229910052720 vanadium Inorganic materials 0.000 abstract 2
- 229910052726 zirconium Inorganic materials 0.000 abstract 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 1
- 229910021556 Chromium(III) chloride Inorganic materials 0.000 abstract 1
- 229910019926 CrOCl2 Inorganic materials 0.000 abstract 1
- 229910011011 Ti(OH)4 Inorganic materials 0.000 abstract 1
- 229910010068 TiCl2 Inorganic materials 0.000 abstract 1
- 229910010062 TiCl3 Inorganic materials 0.000 abstract 1
- 229910003091 WCl6 Inorganic materials 0.000 abstract 1
- 229910007932 ZrCl4 Inorganic materials 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- QSWDMMVNRMROPK-UHFFFAOYSA-K chromium(3+) trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Cr+3] QSWDMMVNRMROPK-UHFFFAOYSA-K 0.000 abstract 1
- 239000011636 chromium(III) chloride Substances 0.000 abstract 1
- 235000007831 chromium(III) chloride Nutrition 0.000 abstract 1
- 239000000706 filtrate Substances 0.000 abstract 1
- 238000005188 flotation Methods 0.000 abstract 1
- 238000005194 fractionation Methods 0.000 abstract 1
- 229910001385 heavy metal Inorganic materials 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 238000004062 sedimentation Methods 0.000 abstract 1
- 239000011949 solid catalyst Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 abstract 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 abstract 1
- KPGXUAIFQMJJFB-UHFFFAOYSA-H tungsten hexachloride Chemical compound Cl[W](Cl)(Cl)(Cl)(Cl)Cl KPGXUAIFQMJJFB-UHFFFAOYSA-H 0.000 abstract 1
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT52610154 | 1954-12-03 | ||
| IT1647954 | 1954-12-16 | ||
| IT1057155 | 1955-07-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB828791A true GB828791A (en) | 1960-02-24 |
Family
ID=27272769
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB34154/55A Expired GB828791A (en) | 1954-12-03 | 1955-11-29 | Method of selectively polymerising alpha-olefins |
| GB21373/56A Expired GB836814A (en) | 1954-12-03 | 1956-07-10 | Process for the preparation of linear, high polymers of ª‡-olefins |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB21373/56A Expired GB836814A (en) | 1954-12-03 | 1956-07-10 | Process for the preparation of linear, high polymers of ª‡-olefins |
Country Status (10)
| Country | Link |
|---|---|
| BE (2) | BE543259A (enrdf_load_stackoverflow) |
| CH (2) | CH365879A (enrdf_load_stackoverflow) |
| CY (1) | CY219A (enrdf_load_stackoverflow) |
| DE (1) | DE1520237A1 (enrdf_load_stackoverflow) |
| FR (2) | FR1139806A (enrdf_load_stackoverflow) |
| GB (2) | GB828791A (enrdf_load_stackoverflow) |
| IT (1) | IT526101A (enrdf_load_stackoverflow) |
| LU (1) | LU33991A1 (enrdf_load_stackoverflow) |
| MY (1) | MY6100061A (enrdf_load_stackoverflow) |
| NL (2) | NL202552A (enrdf_load_stackoverflow) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0032734A1 (en) * | 1980-01-18 | 1981-07-29 | Montedison S.p.A. | Components of catalysts for polymerizing alpha-olefins and catalysts prepared therefrom |
| US4309522A (en) | 1979-07-25 | 1982-01-05 | Chemische Werke Huels, Aktiengesellschaft | Process for the production of extensively amorphous butene-1-propene-ethene terpolymers having a high softening point |
| US6743869B2 (en) | 1997-07-15 | 2004-06-01 | Phillips Petroleum Company | High polymer solids slurry polymerization employing 1-olefin comonomer |
| WO2008077204A3 (en) * | 2006-12-22 | 2008-10-30 | Dominique Bosteels | Catalytic combustion process with rejuvenation step |
| US7482303B2 (en) | 2001-10-10 | 2009-01-27 | Dominique Bosteels | Catalytic burning reaction |
| US7723257B2 (en) | 2001-10-10 | 2010-05-25 | Dominique Bosteels | Process for the catalytic control of radial reaction |
| US10029230B1 (en) | 2017-01-24 | 2018-07-24 | Chevron Phillips Chemical Company Lp | Flow in a slurry loop reactor |
Families Citing this family (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3141872A (en) * | 1954-12-03 | 1964-07-21 | Montedison Spa | Polymerization catalyst and stereospecific polymerization of propylene therewith |
| US4076698A (en) * | 1956-03-01 | 1978-02-28 | E. I. Du Pont De Nemours And Company | Hydrocarbon interpolymer compositions |
| US2893984A (en) * | 1956-04-02 | 1959-07-07 | Exxon Research Engineering Co | Polymerization of alpha olefins |
| US3009905A (en) * | 1956-06-11 | 1961-11-21 | Ici Ltd | Production of polymers |
| DE1209296B (de) * | 1956-10-17 | 1966-01-20 | Ethyl Corp | Verfahren zur Polymerisation oder Mischpoly-merisation von olefinisch ungesaettigten Kohlen-wasserstoffen mit mindestens drei Kohlenstoff-atomen |
| NL220937A (enrdf_load_stackoverflow) * | 1956-10-29 | |||
| US2935495A (en) * | 1956-11-27 | 1960-05-03 | Sun Oil Co | Manufacture of polyolefins |
| US2948711A (en) * | 1956-11-27 | 1960-08-09 | Sun Oil Co | Preparation of polyolefins |
| US3107236A (en) * | 1956-12-17 | 1963-10-15 | Sun Oil Co | Preparation of polypropylene |
| GB877050A (en) * | 1958-06-16 | 1961-09-13 | Ici Ltd | Improvements in and relating to the polymerisation of olefines, catalysts for such polymerisation, crystalline materials suitable as components of the catalysts and processes for their preparation |
| BE554685A (enrdf_load_stackoverflow) * | 1957-02-02 | |||
| GB860647A (en) * | 1957-03-04 | 1961-02-08 | Exxon Research Engineering Co | Method for preparing titanium trichloride containing polymerization catalyst and polymerization process |
| NL120959C (enrdf_load_stackoverflow) * | 1957-04-27 | |||
| US2976252A (en) * | 1957-05-10 | 1961-03-21 | Exxon Research Engineering Co | Temperature-staged catalyst pretreatment |
| BE568002A (enrdf_load_stackoverflow) * | 1957-05-28 | |||
| NL108999C (enrdf_load_stackoverflow) * | 1957-07-16 | |||
| US2918457A (en) * | 1957-09-26 | 1959-12-22 | Sun Oil Co | Copolymer of propylene and butene-1 |
| BE572163A (enrdf_load_stackoverflow) * | 1957-10-19 | |||
| BE571954A (enrdf_load_stackoverflow) * | 1957-10-21 | |||
| BE572307A (enrdf_load_stackoverflow) * | 1957-10-23 | |||
| NL104123B (enrdf_load_stackoverflow) * | 1957-10-25 | |||
| DE1128662B (de) * | 1957-11-09 | 1962-04-26 | Ruhrchemie Ag | Verfahren zur Herstellung von Polyolefinen |
| BE587870A (enrdf_load_stackoverflow) * | 1957-12-11 | |||
| NL113090C (enrdf_load_stackoverflow) * | 1958-02-03 | |||
| DE1240285B (de) * | 1958-02-06 | 1967-05-11 | Hibernia Ag | Verfahren zur Herstellung von hochmolekularen und hochkristallinen Polymerisaten ausOlefinen mit 3 und mehr Kohlenstoffatomen |
| NL102197C (enrdf_load_stackoverflow) * | 1958-03-21 | |||
| DE1117308B (de) * | 1958-03-31 | 1961-11-16 | Eastman Kodak Co | Verfahren zur Herstellung Aryl- oder alicyclische Reste enthaltender Polyolefine |
| BE578139A (enrdf_load_stackoverflow) * | 1958-05-05 | |||
| NL240240A (enrdf_load_stackoverflow) * | 1958-06-27 | |||
| DE1135661B (de) * | 1958-08-02 | 1962-08-30 | Huels Chemische Werke Ag | Verfahren zur Aufarbeitung von Niederdruck-Polypropylen |
| US3082197A (en) * | 1958-12-01 | 1963-03-19 | Phillips Petroleum Co | Polymerization of conjugated diolefins in the presence of transition metal borohydrides |
| BE585154A (enrdf_load_stackoverflow) * | 1958-12-06 | |||
| BE585563A (enrdf_load_stackoverflow) * | 1958-12-12 | |||
| DE1105618B (de) * | 1959-01-26 | 1961-04-27 | Huels Chemische Werke Ag | Verfahren zur Herstellung von isotaktischen Polystyrolen |
| US3244678A (en) * | 1959-01-27 | 1966-04-05 | Du Pont | Process for copolymerizing a straight chain alpha olefin with a conjugated diene |
| US2965692A (en) * | 1959-04-06 | 1960-12-20 | Sun Oil Co | Preparation of viscous polymers |
| IT609922A (enrdf_load_stackoverflow) * | 1959-06-06 | |||
| BE591405A (enrdf_load_stackoverflow) * | 1959-06-12 | |||
| DE1183245B (de) * | 1959-06-24 | 1964-12-10 | Huels Chemische Werke Ag | Verfahren zur Herstellung von Polyolefinen einheitlichen Polymerisationsgrades |
| DE1164666B (de) * | 1959-06-29 | 1964-03-05 | Grace W R & Co | Verfahren zur Herstellung von hochmolekularem Polypropylen |
| US3129255A (en) * | 1959-12-01 | 1964-04-14 | Gulf Research Development Co | Alkylation of benzene with propylene in the presence of ticl4 and alkyl aluminum sesquichloride |
| US3067189A (en) * | 1959-12-24 | 1962-12-04 | Shell Oil Co | Diene polymerization catalyst |
| DE1201996B (de) * | 1960-05-18 | 1965-09-30 | Grace W R & Co | Verfahren zur Polymerisation oder Mischpolymerisation von Monoolefinen, Diolefinen oder Styrol |
| US3100218A (en) * | 1961-07-20 | 1963-08-06 | Monsanto Chemicals | Purification of diethylaluminum chloride with crystalline titanium trichloride |
| DE1520348B2 (de) * | 1962-11-08 | 1971-07-22 | Mitsubishi Petrochemical Co , Ltd , Tokio | Verfahren zur herstellung von festen homo oder mischpolymeri saten des isobutylens |
| US3226336A (en) * | 1963-05-08 | 1965-12-28 | Rexall Drug Chemical | Composition and process for preparing a three-component polymerization system |
-
0
- NL NL111136D patent/NL111136C/xx active
- BE BE549638D patent/BE549638A/xx unknown
- IT IT526101D patent/IT526101A/it unknown
- NL NL202552D patent/NL202552A/xx unknown
- BE BE543259D patent/BE543259A/xx unknown
- LU LU33991D patent/LU33991A1/xx unknown
-
1955
- 1955-11-19 CH CH536961A patent/CH365879A/de unknown
- 1955-11-19 CH CH2680655A patent/CH365222A/de unknown
- 1955-11-29 GB GB34154/55A patent/GB828791A/en not_active Expired
- 1955-11-30 FR FR1139806D patent/FR1139806A/fr not_active Expired
-
1956
- 1956-07-10 GB GB21373/56A patent/GB836814A/en not_active Expired
- 1956-07-13 FR FR70731D patent/FR70731E/fr not_active Expired
-
1960
- 1960-09-21 DE DE19601520237 patent/DE1520237A1/de active Pending
-
1961
- 1961-04-13 CY CY21961A patent/CY219A/xx unknown
- 1961-12-31 MY MY196161A patent/MY6100061A/xx unknown
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4309522A (en) | 1979-07-25 | 1982-01-05 | Chemische Werke Huels, Aktiengesellschaft | Process for the production of extensively amorphous butene-1-propene-ethene terpolymers having a high softening point |
| EP0032734A1 (en) * | 1980-01-18 | 1981-07-29 | Montedison S.p.A. | Components of catalysts for polymerizing alpha-olefins and catalysts prepared therefrom |
| US6743869B2 (en) | 1997-07-15 | 2004-06-01 | Phillips Petroleum Company | High polymer solids slurry polymerization employing 1-olefin comonomer |
| US6806324B2 (en) | 1997-07-15 | 2004-10-19 | Phillips Petroleum Company | High solids slurry polymerization using heat exchange to condense the flashed diluent |
| US7482303B2 (en) | 2001-10-10 | 2009-01-27 | Dominique Bosteels | Catalytic burning reaction |
| US7723257B2 (en) | 2001-10-10 | 2010-05-25 | Dominique Bosteels | Process for the catalytic control of radial reaction |
| WO2008077204A3 (en) * | 2006-12-22 | 2008-10-30 | Dominique Bosteels | Catalytic combustion process with rejuvenation step |
| US10029230B1 (en) | 2017-01-24 | 2018-07-24 | Chevron Phillips Chemical Company Lp | Flow in a slurry loop reactor |
Also Published As
| Publication number | Publication date |
|---|---|
| NL111136C (enrdf_load_stackoverflow) | |
| CY219A (en) | 1961-04-13 |
| BE543259A (enrdf_load_stackoverflow) | |
| LU33991A1 (enrdf_load_stackoverflow) | |
| CH365879A (de) | 1962-11-30 |
| FR1139806A (fr) | 1957-07-05 |
| GB836814A (en) | 1960-06-09 |
| IT526101A (enrdf_load_stackoverflow) | |
| CH365222A (de) | 1962-10-31 |
| FR70731E (fr) | 1959-07-10 |
| DE1520237A1 (de) | 1969-03-27 |
| BE549638A (enrdf_load_stackoverflow) | |
| NL202552A (enrdf_load_stackoverflow) | |
| MY6100061A (en) | 1961-12-31 |
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