GB734204A - Improvements in or relating to the manufacture of hydrogen peroxide - Google Patents

Improvements in or relating to the manufacture of hydrogen peroxide

Info

Publication number
GB734204A
GB734204A GB2361552A GB2361552A GB734204A GB 734204 A GB734204 A GB 734204A GB 2361552 A GB2361552 A GB 2361552A GB 2361552 A GB2361552 A GB 2361552A GB 734204 A GB734204 A GB 734204A
Authority
GB
United Kingdom
Prior art keywords
hydrogen peroxide
ester
butyl
anthraquinone
relating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2361552A
Inventor
Kenneth Michael Hack
William Stanley Wood
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik LCL Ltd
Original Assignee
Laporte Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Laporte Chemicals Ltd filed Critical Laporte Chemicals Ltd
Priority to GB2361552A priority Critical patent/GB734204A/en
Publication of GB734204A publication Critical patent/GB734204A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B15/00Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
    • C01B15/01Hydrogen peroxide
    • C01B15/022Preparation from organic compounds
    • C01B15/023Preparation from organic compounds by the alkyl-anthraquinone process

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

In a cyclic process for the preparation of hydrogen peroxide by reduction of an alkyl or aryl substituted anthraquinone, e.g. 2-ethyl or butyl anthraquinones, and autoxidation of the resultant anthraquinhydrone or anthrahydroquinone with subsequent removal of the hydrogen peroxide formed, the solvent comprises an ester of phthalic acid, e.g. dibutyl-, dimethyl-, diamyl-, di-(ethylhexyl)-, di-(ethylene glycol monobutyl ether)-, dibenzyl-, or benzyl-butyl-phthalates, and should have a melting-point of not more than 50 DEG C. The reaction temperature should be sufficient for the ester to be liquid. The anthraquinone is reduced with hydrogen in the presence of a palladium catalyst say at 20 DEG or 30 DEG C. After separation of the catalyst the reduced solution is oxidized by blowing in air, and hydrogen peroxide is extracted with a countercurrent of water. Specifications 465,070, 508,881, [Group I], 669,274, and 671,524 are referred to.
GB2361552A 1952-09-19 1952-09-19 Improvements in or relating to the manufacture of hydrogen peroxide Expired GB734204A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2361552A GB734204A (en) 1952-09-19 1952-09-19 Improvements in or relating to the manufacture of hydrogen peroxide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2361552A GB734204A (en) 1952-09-19 1952-09-19 Improvements in or relating to the manufacture of hydrogen peroxide

Publications (1)

Publication Number Publication Date
GB734204A true GB734204A (en) 1955-07-27

Family

ID=10198517

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2361552A Expired GB734204A (en) 1952-09-19 1952-09-19 Improvements in or relating to the manufacture of hydrogen peroxide

Country Status (1)

Country Link
GB (1) GB734204A (en)

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