GB856420A - Method of making hydrogen peroxide - Google Patents
Method of making hydrogen peroxideInfo
- Publication number
- GB856420A GB856420A GB14862/57A GB1486257A GB856420A GB 856420 A GB856420 A GB 856420A GB 14862/57 A GB14862/57 A GB 14862/57A GB 1486257 A GB1486257 A GB 1486257A GB 856420 A GB856420 A GB 856420A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrogenation
- hydrogen peroxide
- quinone
- benzene
- tetrahydroanthraquinone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title abstract 6
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 abstract 6
- 238000005984 hydrogenation reaction Methods 0.000 abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- KVNYFPKFSJIPBJ-UHFFFAOYSA-N 1,2-diethylbenzene Chemical compound CCC1=CC=CC=C1CC KVNYFPKFSJIPBJ-UHFFFAOYSA-N 0.000 abstract 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- OTBHDFWQZHPNPU-UHFFFAOYSA-N 1,2,3,4-tetrahydroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1CCCC2 OTBHDFWQZHPNPU-UHFFFAOYSA-N 0.000 abstract 1
- VIDOPANCAUPXNH-UHFFFAOYSA-N 1,2,3-triethylbenzene Chemical compound CCC1=CC=CC(CC)=C1CC VIDOPANCAUPXNH-UHFFFAOYSA-N 0.000 abstract 1
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical group CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 abstract 1
- JORLUGVBYJSSAW-UHFFFAOYSA-N 2-ethyl-1,2,3,4-tetrahydroanthracene-9,10-dione Chemical group O=C1C2=CC=CC=C2C(=O)C2=C1CC(CC)CC2 JORLUGVBYJSSAW-UHFFFAOYSA-N 0.000 abstract 1
- SJEBAWHUJDUKQK-UHFFFAOYSA-N 2-ethylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC=C3C(=O)C2=C1 SJEBAWHUJDUKQK-UHFFFAOYSA-N 0.000 abstract 1
- RHLVCLIPMVJYKS-UHFFFAOYSA-N 3-octanone Chemical compound CCCCCC(=O)CC RHLVCLIPMVJYKS-UHFFFAOYSA-N 0.000 abstract 1
- HCFAJYNVAYBARA-UHFFFAOYSA-N 4-heptanone Chemical group CCCC(=O)CCC HCFAJYNVAYBARA-UHFFFAOYSA-N 0.000 abstract 1
- ZPQAKYPOZRXKFA-UHFFFAOYSA-N 6-Undecanone Chemical group CCCCCC(=O)CCCCC ZPQAKYPOZRXKFA-UHFFFAOYSA-N 0.000 abstract 1
- 238000006701 autoxidation reaction Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical group CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 abstract 1
- -1 ethylhexyl Chemical group 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- IMXBRVLCKXGWSS-UHFFFAOYSA-N methyl 2-cyclohexylacetate Chemical compound COC(=O)CC1CCCCC1 IMXBRVLCKXGWSS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/022—Preparation from organic compounds
- C01B15/023—Preparation from organic compounds by the alkyl-anthraquinone process
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
In the production of hydrogen peroxide by the successive catalytic hydrogenation and autoxidation of a quinone in a solvent medium, the quinone is 2-ethyl tetrahydroanthraquinone containing 0 to 125% by weight of 2-ethyl anthraquinone and the hydrogenation is terminated before it is more than 55% complete. The degree of hydrogenation should in general be above 20% and may be 44% (Example I) or 54.9% (Example II). Solvents specified are methyl cyclohexyl acetate alone or together with benzene, diethyl benzene or triethyl benzene, and di-isobutyl, di-n-propyl, diamyl, dihexyl, ethylhexyl, and ethylamyl ketone. The concentration of tetrahydroanthraquinone may be 40-100% of saturation. The temperature of hydrogenation may be 50-125 DEG F. The catalyst may be palladium supported on alumina. After reaction of the hydrogenated solution with air at about 120 DEG F. and extraction with water to remove hydrogen peroxide, the quinone solution may be passed through a bed of active alumina and then subjected to further hydrogenation &c. Specifications 465,070 and 671,524 are referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US856420XA | 1956-06-19 | 1956-06-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB856420A true GB856420A (en) | 1960-12-14 |
Family
ID=22192986
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB14862/57A Expired GB856420A (en) | 1956-06-19 | 1957-05-10 | Method of making hydrogen peroxide |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB856420A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5399333A (en) * | 1992-12-25 | 1995-03-21 | Mitsubishi Chemical Gas Co., Ltd. | Process for producing hydrogen peroxide |
-
1957
- 1957-05-10 GB GB14862/57A patent/GB856420A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5399333A (en) * | 1992-12-25 | 1995-03-21 | Mitsubishi Chemical Gas Co., Ltd. | Process for producing hydrogen peroxide |
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