GB965678A - A process for the production of hydrogen peroxide - Google Patents

A process for the production of hydrogen peroxide

Info

Publication number
GB965678A
GB965678A GB4607261A GB4607261A GB965678A GB 965678 A GB965678 A GB 965678A GB 4607261 A GB4607261 A GB 4607261A GB 4607261 A GB4607261 A GB 4607261A GB 965678 A GB965678 A GB 965678A
Authority
GB
United Kingdom
Prior art keywords
hydrogen peroxide
resin
polymer
aqueous
anthraquinones
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4607261A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Liquide SA, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Publication of GB965678A publication Critical patent/GB965678A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/676—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
    • C01B15/01—Hydrogen peroxide
    • C01B15/022—Preparation from organic compounds
    • C01B15/023—Preparation from organic compounds by the alkyl-anthraquinone process
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F16/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F16/36—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by a ketonic radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • C08G63/54—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation the acids or hydroxy compounds containing carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Hydrogen peroxide is produced from a reducible-oxidizable polymer having anthraquinone groups by cyclically reducing and then oxidizing the polymer by means of air or oxygen in the presence of a solvent for hydrogen peroxide. Specified polymers are polyvinyl anthraquinones, polyanthraquinonyl - methylene-malonates of linear polyalcohols having alcohol groups at each end, and acetals of formyl-2-anthraquinones and polyvinyl alcohols or acetates (see Specifications 965,676 and 965,677). They are preferably in the form of spheres, plates or strips and are reduced catalytically, e.g. palladium on alumina, or by aqueous reducing agents, e.g. titanium trichloride in hydrochloric acid, and sodium hydrosulphite. The re-oxidation may be achieved in the presence of a hydrogen peroxide stabilizer, e.g. sodium metaphosphate. An apparatus is described in which the polymer is held in a vertical tube through the top of which is introduced, in an inert atmosphere, the aqueous reducing agent. The resin is washed in an ascending current of water and air or oxygen is then blown up through the tube. The hydrogen peroxide is recovered as an aqueous solution by washing the resin. The reactions may also be effected on the polymers dissolved in a solvent, e.g. dimethyl formamide for catalytic hydrogenation, either alone or with aqueous alkali. After oxidation, the resin precipitates on dilution with water.
GB4607261A 1960-12-23 1961-12-22 A process for the production of hydrogen peroxide Expired GB965678A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR847848A FR1290837A (en) 1960-12-23 1960-12-23 New reducto-oxidizable anthraquinone polymers, their preparation processes and their application to the manufacture of hydrogen peroxide

Publications (1)

Publication Number Publication Date
GB965678A true GB965678A (en) 1964-08-06

Family

ID=8745400

Family Applications (3)

Application Number Title Priority Date Filing Date
GB4607061A Expired GB965676A (en) 1960-12-23 1961-12-22 Polyesters
GB4607161A Expired GB965677A (en) 1960-12-23 1961-12-22 New reducible oxidisable polymers
GB4607261A Expired GB965678A (en) 1960-12-23 1961-12-22 A process for the production of hydrogen peroxide

Family Applications Before (2)

Application Number Title Priority Date Filing Date
GB4607061A Expired GB965676A (en) 1960-12-23 1961-12-22 Polyesters
GB4607161A Expired GB965677A (en) 1960-12-23 1961-12-22 New reducible oxidisable polymers

Country Status (2)

Country Link
FR (1) FR1290837A (en)
GB (3) GB965676A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5624543A (en) * 1995-08-01 1997-04-29 Peroxco Incorporated Aqueous phase production of hydrogen peroxide and catalysts for use therein
CN112533864A (en) * 2018-08-02 2021-03-19 赢创有限公司 Method for producing stabilized aqueous hydrogen peroxide solution

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5374339A (en) * 1993-10-14 1994-12-20 Guillet; James E. Production of hydrogen peroxide
CN1273646A (en) * 1998-07-10 2000-11-15 克拉瑞特国际有限公司 Composition for bottom reflection preventive film and novel polymeric dye for use in the same
US9828324B2 (en) 2010-10-20 2017-11-28 Sirrus, Inc. Methylene beta-diketone monomers, methods for making methylene beta-diketone monomers, polymerizable compositions and products formed therefrom
US9279022B1 (en) 2014-09-08 2016-03-08 Sirrus, Inc. Solution polymers including one or more 1,1-disubstituted alkene compounds, solution polymerization methods, and polymer compositions
US10414839B2 (en) 2010-10-20 2019-09-17 Sirrus, Inc. Polymers including a methylene beta-ketoester and products formed therefrom
US9249265B1 (en) 2014-09-08 2016-02-02 Sirrus, Inc. Emulsion polymers including one or more 1,1-disubstituted alkene compounds, emulsion methods, and polymer compositions
EP2768897B1 (en) 2011-10-19 2019-01-23 Sirrus, Inc. Methods for making methylene beta-diketone monomers
CA2869112A1 (en) 2012-03-30 2013-10-03 Bioformix Inc. Composite and laminate articles and polymerizable systems for producing the same
EP2831185B1 (en) 2012-03-30 2019-09-25 Sirrus, Inc. Ink and coating formulations and polymerizable systems for producing the same
WO2013181600A2 (en) 2012-06-01 2013-12-05 Bioformix Inc. Optical material and articles formed therefrom
WO2014078689A1 (en) 2012-11-16 2014-05-22 Bioformix Inc. Plastics bonding systems and methods
EP3712928A1 (en) 2012-11-30 2020-09-23 Sirrus, Inc. Composite compositions for electronics applications
WO2014110388A1 (en) 2013-01-11 2014-07-17 Bioformix Inc. Method to obtain methylene malonate via bis(hydroxymethyl) malonate pathway
US9315597B2 (en) 2014-09-08 2016-04-19 Sirrus, Inc. Compositions containing 1,1-disubstituted alkene compounds for preparing polymers having enhanced glass transition temperatures
US9416091B1 (en) 2015-02-04 2016-08-16 Sirrus, Inc. Catalytic transesterification of ester compounds with groups reactive under transesterification conditions
US10501400B2 (en) 2015-02-04 2019-12-10 Sirrus, Inc. Heterogeneous catalytic transesterification of ester compounds with groups reactive under transesterification conditions
US9334430B1 (en) 2015-05-29 2016-05-10 Sirrus, Inc. Encapsulated polymerization initiators, polymerization systems and methods using the same
US9217098B1 (en) 2015-06-01 2015-12-22 Sirrus, Inc. Electroinitiated polymerization of compositions having a 1,1-disubstituted alkene compound
US9518001B1 (en) 2016-05-13 2016-12-13 Sirrus, Inc. High purity 1,1-dicarbonyl substituted-1-alkenes and methods for their preparation
US10196481B2 (en) 2016-06-03 2019-02-05 Sirrus, Inc. Polymer and other compounds functionalized with terminal 1,1-disubstituted alkene monomer(s) and methods thereof
US9567475B1 (en) 2016-06-03 2017-02-14 Sirrus, Inc. Coatings containing polyester macromers containing 1,1-dicarbonyl-substituted 1 alkenes
US9617377B1 (en) 2016-06-03 2017-04-11 Sirrus, Inc. Polyester macromers containing 1,1-dicarbonyl-substituted 1 alkenes
US10428177B2 (en) 2016-06-03 2019-10-01 Sirrus, Inc. Water absorbing or water soluble polymers, intermediate compounds, and methods thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5624543A (en) * 1995-08-01 1997-04-29 Peroxco Incorporated Aqueous phase production of hydrogen peroxide and catalysts for use therein
CN112533864A (en) * 2018-08-02 2021-03-19 赢创有限公司 Method for producing stabilized aqueous hydrogen peroxide solution

Also Published As

Publication number Publication date
FR1290837A (en) 1962-04-20
GB965676A (en) 1964-08-06
GB965677A (en) 1964-08-06

Similar Documents

Publication Publication Date Title
GB965678A (en) A process for the production of hydrogen peroxide
ATE24876T1 (en) CONTINUOUS PROCESS FOR THE PRODUCTION OF HYDROGEN PEROXIDE BY THE ANTHRACHINONE PROCESS.
GB965012A (en) Improvements in and relating to the production of hydrogen peroxide
US3767778A (en) Process for the production of hydrogen peroxide
ES2061104T3 (en) PROCEDURE FOR THE PREPARATION OF ALKYLTETRAHYDRO-ANTHRAHIDROQUINONE SOLUTIONS AND ITS USE AS A WORKING SOLUTION IN THE PREPARATION OF HYDROGEN PEROXIDE ACCORDING TO THE ANTRAQUINONE PROCEDURE.
GB1160712A (en) Drying Peroxidic Compounds
GB838939A (en) Regeneration of degraded alkyl anthraquinone solutions for the production of hydrogen peroxide
GB465070A (en) Improvements in the manufacture and production of hydrogen peroxide
GB787340A (en) Improvements in or relating to the regeneration of catalysts
GB967187A (en) Improvements in or relating to catalysts
GB1059317A (en) A method of purifying the recycle solution used in the production of hydrogen peroxide by the anthraquinone process
ATE234262T1 (en) PRODUCTION OF HYDROGEN PEROXIDE BY A CYCLIC ANTHRACHINONE PROCESS
GB981987A (en) A process for the production of organic acetates
ES270627A1 (en) An improved process for the production of hydrogen peroxide
GB1072399A (en) A process for the production of acetic acid
ES277120A1 (en) Procedure for regenerating the hydrogen peroxide production capacity of solutions comprising an anthrachinone (Machine-translation by Google Translate, not legally binding)
GB758235A (en) Improved solvents for the preparation of hydrogen peroxide by hydrogenation and oxidation of anthraquinones
GB856420A (en) Method of making hydrogen peroxide
GB723454A (en) Improvements in or relating to the manufacture of hydroquinone
GB996374A (en) Treatment of quinone-containing solutions
GB1298326A (en) Process for the production of 2-methylene-1,3-diacetoxypropane
GB1027323A (en) Process for the production of benzyl alcohol and benzaldehyde
DE968902C (en) Process for the preparation of alkylene chlorohydrins
GB884478A (en) Polymethacrolein derivatives and their production
GB887373A (en) Process for the manufacture of quinacridones from 6:13-dihydroquinacridones