GB670269A - Copolymerization of acrylonitrile with a vinylpyridine - Google Patents
Copolymerization of acrylonitrile with a vinylpyridineInfo
- Publication number
- GB670269A GB670269A GB3838/49A GB383849A GB670269A GB 670269 A GB670269 A GB 670269A GB 3838/49 A GB3838/49 A GB 3838/49A GB 383849 A GB383849 A GB 383849A GB 670269 A GB670269 A GB 670269A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl
- vinyl pyridine
- copolymers
- persulphate
- pyridines
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/42—Nitriles
- C08F220/44—Acrylonitrile
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Copolymers are prepared by heating acrylonitrile together with 2 to 25 per cent of a vinyl pyridine in aqueous emulsion at 30 DEG to 100 DEG C. at a pH of 7 to 10.5 in the presence of a water-soluble persulphate, such as ammonium or sodium persulphate, as the sole polymerisation catalyst. Vinyl pyridines specified are 2- and 4-vinyl pyridines, 4-ethyl-2-vinyl pyridine, and 4,6-dimethyl-2-vinyl pyridine. Suitable dispersing agents are sodium oleate, alkali metal or ammonium salts of aromatic and aliphatic sulphonates, C-cetylbetaine, and the reaction products of ethylene oxide with alcohols. The copolymers may be formed into fibres which have good dye reception, particularly for acid dyes. Specifications 586,796, 597,368 and 670,268 are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US284803XA | 1948-02-25 | 1948-02-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB670269A true GB670269A (en) | 1952-04-16 |
Family
ID=21843679
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3838/49A Expired GB670269A (en) | 1948-02-25 | 1949-02-11 | Copolymerization of acrylonitrile with a vinylpyridine |
Country Status (5)
Country | Link |
---|---|
BE (1) | BE487563A (en) |
CH (1) | CH284803A (en) |
DE (1) | DE855161C (en) |
FR (1) | FR981751A (en) |
GB (1) | GB670269A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2775567A (en) * | 1953-05-13 | 1956-12-25 | Chemstrand Corp | Method of preparing dyeable copolymers |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1078733B (en) * | 1954-09-20 | 1960-03-31 | Montedison Spa | Process for the production of threads or fibers from copolymers of acrylonitrile which can be easily dyed with Kuepen dyes |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE695098C (en) * | 1938-01-24 | 1940-08-16 | I G Farbenindustrie Akt Ges | Process for the preparation of polymerisation products of vinyl pyridine |
-
0
- BE BE487563D patent/BE487563A/xx unknown
-
1949
- 1949-01-21 DE DEP32058A patent/DE855161C/en not_active Expired
- 1949-02-11 GB GB3838/49A patent/GB670269A/en not_active Expired
- 1949-02-24 FR FR981751D patent/FR981751A/en not_active Expired
- 1949-02-25 CH CH284803D patent/CH284803A/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2775567A (en) * | 1953-05-13 | 1956-12-25 | Chemstrand Corp | Method of preparing dyeable copolymers |
Also Published As
Publication number | Publication date |
---|---|
FR981751A (en) | 1951-05-30 |
BE487563A (en) | 1949-02-26 |
CH284803A (en) | 1952-08-15 |
DE855161C (en) | 1952-11-10 |
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