GB500475A - Improvements in the manufacture and production of watersoluble polymerisation products - Google Patents
Improvements in the manufacture and production of watersoluble polymerisation productsInfo
- Publication number
- GB500475A GB500475A GB21607/37A GB2160737A GB500475A GB 500475 A GB500475 A GB 500475A GB 21607/37 A GB21607/37 A GB 21607/37A GB 2160737 A GB2160737 A GB 2160737A GB 500475 A GB500475 A GB 500475A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- acrylic acid
- polymerization
- alpha
- added
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/04—Acids; Metal salts or ammonium salts thereof
- C08F120/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
Abstract
500,475. Vinyl polymerization products. JOHNSON, G. W. (1. G. Farbenindustrie Akt.-Ges.) Aug. 5, 1937, No. 21607. [Class 2 (iii)] Water-soluble polymerization products are prepared by heating monomeric alkali or ammonium salts of acrylic acid or its alpha homologues, in the presence of accelerators giving off oxygen, in a slightly acid aqueous solution having a pH range of from 4À5 to 5À5 The acid employed to form the solution may be acrylic acid, a weak acid such as propionic or butyric acid, or an acid which is stronger than acrylic acid, e.g. sulphuric hydrochloric or monochloracetic acid, in which case an interaction takes place between the acid and the acrylic acid salt with the formation of free acrylic acid and the salt of the added acid. The polymerization may be carried out in a metallic vessel, e.g. a stirring vessel or kneading machine lined with sheet chromium-nickel steel. In an example, caustic soda solution is added to an aqueous solution containing an excess of monomeric acrylic acid, potassium persulphate is added, and polymerization initiated by heating. When polymerization is completed, the solution of interpolymer is neutralized. The alkali or ammonium salts of alpha-methyl or alpha-ethyl acrylic acid may be similarly treated.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE1937I0058703 DE695097C (en) | 1937-07-31 | 1937-07-31 | Process for the preparation of alkali or ammonium salts of polyacrylic acid and their homologues |
GB21607/37A GB500475A (en) | 1937-07-31 | 1937-08-05 | Improvements in the manufacture and production of watersoluble polymerisation products |
FR841299D FR841299A (en) | 1937-07-31 | 1938-07-28 | Process for preparing alkali and ammonium salts of polyacrylic acid and its homologues |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE1937I0058703 DE695097C (en) | 1937-07-31 | 1937-07-31 | Process for the preparation of alkali or ammonium salts of polyacrylic acid and their homologues |
GB21607/37A GB500475A (en) | 1937-07-31 | 1937-08-05 | Improvements in the manufacture and production of watersoluble polymerisation products |
Publications (1)
Publication Number | Publication Date |
---|---|
GB500475A true GB500475A (en) | 1939-02-06 |
Family
ID=25982016
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB21607/37A Expired GB500475A (en) | 1937-07-31 | 1937-08-05 | Improvements in the manufacture and production of watersoluble polymerisation products |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE695097C (en) |
FR (1) | FR841299A (en) |
GB (1) | GB500475A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2833745A (en) * | 1953-06-24 | 1958-05-06 | Basf Ag | Production of the salts of polymerized alpha.beta-unsaturated aliphatic acids |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE907827C (en) * | 1941-06-20 | 1954-03-29 | Roehm & Haas G M B H | Process for the preparation of water-insoluble acrylic acid-containing polymers which can easily be converted into solutions or swellings of their salts |
IT1141013B (en) * | 1979-08-24 | 1986-10-01 | Rhone Poulenc Ind | PROCEDURE FOR THE PREPARATION OF AQUOUS SOLUTIONS OF POLYACRYLIC ACIDS OF LOW MOLECULAR MASSES OR THEIR SALTS |
-
1937
- 1937-07-31 DE DE1937I0058703 patent/DE695097C/en not_active Expired
- 1937-08-05 GB GB21607/37A patent/GB500475A/en not_active Expired
-
1938
- 1938-07-28 FR FR841299D patent/FR841299A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2833745A (en) * | 1953-06-24 | 1958-05-06 | Basf Ag | Production of the salts of polymerized alpha.beta-unsaturated aliphatic acids |
Also Published As
Publication number | Publication date |
---|---|
FR841299A (en) | 1939-05-15 |
DE695097C (en) | 1940-08-16 |
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