GB500475A - Improvements in the manufacture and production of watersoluble polymerisation products - Google Patents

Improvements in the manufacture and production of watersoluble polymerisation products

Info

Publication number
GB500475A
GB500475A GB21607/37A GB2160737A GB500475A GB 500475 A GB500475 A GB 500475A GB 21607/37 A GB21607/37 A GB 21607/37A GB 2160737 A GB2160737 A GB 2160737A GB 500475 A GB500475 A GB 500475A
Authority
GB
United Kingdom
Prior art keywords
acid
acrylic acid
polymerization
alpha
added
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB21607/37A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DE1937I0058703 priority Critical patent/DE695097C/en
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to GB21607/37A priority patent/GB500475A/en
Priority to FR841299D priority patent/FR841299A/en
Publication of GB500475A publication Critical patent/GB500475A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F120/00Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F120/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F120/04Acids; Metal salts or ammonium salts thereof
    • C08F120/06Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof

Abstract

500,475. Vinyl polymerization products. JOHNSON, G. W. (1. G. Farbenindustrie Akt.-Ges.) Aug. 5, 1937, No. 21607. [Class 2 (iii)] Water-soluble polymerization products are prepared by heating monomeric alkali or ammonium salts of acrylic acid or its alpha homologues, in the presence of accelerators giving off oxygen, in a slightly acid aqueous solution having a pH range of from 4À5 to 5À5 The acid employed to form the solution may be acrylic acid, a weak acid such as propionic or butyric acid, or an acid which is stronger than acrylic acid, e.g. sulphuric hydrochloric or monochloracetic acid, in which case an interaction takes place between the acid and the acrylic acid salt with the formation of free acrylic acid and the salt of the added acid. The polymerization may be carried out in a metallic vessel, e.g. a stirring vessel or kneading machine lined with sheet chromium-nickel steel. In an example, caustic soda solution is added to an aqueous solution containing an excess of monomeric acrylic acid, potassium persulphate is added, and polymerization initiated by heating. When polymerization is completed, the solution of interpolymer is neutralized. The alkali or ammonium salts of alpha-methyl or alpha-ethyl acrylic acid may be similarly treated.
GB21607/37A 1937-07-31 1937-08-05 Improvements in the manufacture and production of watersoluble polymerisation products Expired GB500475A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
DE1937I0058703 DE695097C (en) 1937-07-31 1937-07-31 Process for the preparation of alkali or ammonium salts of polyacrylic acid and their homologues
GB21607/37A GB500475A (en) 1937-07-31 1937-08-05 Improvements in the manufacture and production of watersoluble polymerisation products
FR841299D FR841299A (en) 1937-07-31 1938-07-28 Process for preparing alkali and ammonium salts of polyacrylic acid and its homologues

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE1937I0058703 DE695097C (en) 1937-07-31 1937-07-31 Process for the preparation of alkali or ammonium salts of polyacrylic acid and their homologues
GB21607/37A GB500475A (en) 1937-07-31 1937-08-05 Improvements in the manufacture and production of watersoluble polymerisation products

Publications (1)

Publication Number Publication Date
GB500475A true GB500475A (en) 1939-02-06

Family

ID=25982016

Family Applications (1)

Application Number Title Priority Date Filing Date
GB21607/37A Expired GB500475A (en) 1937-07-31 1937-08-05 Improvements in the manufacture and production of watersoluble polymerisation products

Country Status (3)

Country Link
DE (1) DE695097C (en)
FR (1) FR841299A (en)
GB (1) GB500475A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2833745A (en) * 1953-06-24 1958-05-06 Basf Ag Production of the salts of polymerized alpha.beta-unsaturated aliphatic acids

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE907827C (en) * 1941-06-20 1954-03-29 Roehm & Haas G M B H Process for the preparation of water-insoluble acrylic acid-containing polymers which can easily be converted into solutions or swellings of their salts
IT1141013B (en) * 1979-08-24 1986-10-01 Rhone Poulenc Ind PROCEDURE FOR THE PREPARATION OF AQUOUS SOLUTIONS OF POLYACRYLIC ACIDS OF LOW MOLECULAR MASSES OR THEIR SALTS

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2833745A (en) * 1953-06-24 1958-05-06 Basf Ag Production of the salts of polymerized alpha.beta-unsaturated aliphatic acids

Also Published As

Publication number Publication date
FR841299A (en) 1939-05-15
DE695097C (en) 1940-08-16

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