GB1148060A - Vinyl ester polymer dispersions and their production - Google Patents

Vinyl ester polymer dispersions and their production

Info

Publication number
GB1148060A
GB1148060A GB3510566A GB3510566A GB1148060A GB 1148060 A GB1148060 A GB 1148060A GB 3510566 A GB3510566 A GB 3510566A GB 3510566 A GB3510566 A GB 3510566A GB 1148060 A GB1148060 A GB 1148060A
Authority
GB
United Kingdom
Prior art keywords
vinyl
vinyl ester
acrylic acid
acid
methyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3510566A
Inventor
Heinz Pohlemann
Gerhard Florus
Wolfgang Sliwka
Manfred Gellrich
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of GB1148060A publication Critical patent/GB1148060A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F18/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F18/02—Esters of monocarboxylic acids
    • C08F18/04—Vinyl esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00

Abstract

1,148,060. Aqueous dispersions of vinyl ester polymers. BADISCHE ANILIN- & SODA-FABRIK A.G. 5 Aug., 1966 [6 Aug., 1965], No. 35105/66. Heading C3P Aqueous dispersions of vinyl ester polymers are formed by polymerizing the monomer(s) in aq. phase in the presence of an emulsifier comprising (A) 15-70% of at least one copolymer of 50-90% of acrylic and/or methacrylic acid with at least one other nonionic ethylenically unsaturated monomer and which is soluble in water at a pH of at least 4, (B) 15-70% of at least one polyalkylene oxide or its derivative which is not sulphonated and (C) 15-70% of at least one sulphonated long chain alcohol having at least 8 carbon atoms. The vinyl ester polymer may be derived from vinyl propionate and acrylic acid or sodium vinyl sulphonate, tert-butyl acrylate and methyl vinyl carbinol or vinyl acetate acrylic acid or n-butyl acrylate. The emulsifier may acomprise (A) a copolymer of acrylic acid, acrylamide, methyl acrylate and/or acrylonitrile, (B) an adduct of ethylene oxide and sperm oil alcohol or iso-octylphenol and (C) a sulphonation product of (B). The polymerization may be in the presence of vinylpyrrolidone potassium persulphate, formic acid, ascorbic acid, n-dodecyl mercaptan. The aq. dispersion may be compounded with methyl cellulose, sodium metahexaphosphate, ammonium polyacrylate, aq. ammonia, chalk, rutile, kaolin, talc, dolomite, zinc white, titanium dioxide, china clay, blanc fixe, satin white and/or casein.
GB3510566A 1965-08-06 1966-08-05 Vinyl ester polymer dispersions and their production Expired GB1148060A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE1965B0083162 DE1265988B (en) 1965-08-06 1965-08-06 Process for the preparation of aqueous dispersions of vinyl ester polymers

Publications (1)

Publication Number Publication Date
GB1148060A true GB1148060A (en) 1969-04-10

Family

ID=6981832

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3510566A Expired GB1148060A (en) 1965-08-06 1966-08-05 Vinyl ester polymer dispersions and their production

Country Status (4)

Country Link
BE (1) BE685223A (en)
DE (1) DE1265988B (en)
GB (1) GB1148060A (en)
NL (1) NL6611086A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4226748A (en) * 1978-01-27 1980-10-07 Kao Soap Co., Ltd. Fabric sizing emulsion
US4228047A (en) * 1978-10-31 1980-10-14 Air Products And Chemicals, Inc. Starch compatible polyvinyl acetate latices
US5071903A (en) * 1987-10-27 1991-12-10 Unilever Patent Holdings B.V. Emulsion polymerization

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4043961A (en) * 1976-01-29 1977-08-23 E. I. Du Pont De Nemours And Company Vinyl acetate-ethylene copolymer emulsions having improved water resistance
DE2614261C3 (en) * 1976-04-02 1984-08-23 Hoechst Ag, 6230 Frankfurt Process for the production of dispersible dispersion powders

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB861986A (en) * 1956-07-04 1961-03-01 British Celanese Improvements in and relating to the production of polymers
US3080333A (en) * 1960-01-08 1963-03-05 Celanese Corp Terpolymer latex of an unsaturated ester of a fatty acid, ethyl acrylate, and another acrylic ester or a vinyl aromatic monomer

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4226748A (en) * 1978-01-27 1980-10-07 Kao Soap Co., Ltd. Fabric sizing emulsion
US4228047A (en) * 1978-10-31 1980-10-14 Air Products And Chemicals, Inc. Starch compatible polyvinyl acetate latices
US5071903A (en) * 1987-10-27 1991-12-10 Unilever Patent Holdings B.V. Emulsion polymerization

Also Published As

Publication number Publication date
DE1265988B (en) 1968-04-11
NL6611086A (en) 1967-02-07
BE685223A (en) 1967-02-08

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