GB769252A - Improvements in or relating to textile coloring compositions - Google Patents
Improvements in or relating to textile coloring compositionsInfo
- Publication number
- GB769252A GB769252A GB9743/55A GB974355A GB769252A GB 769252 A GB769252 A GB 769252A GB 9743/55 A GB9743/55 A GB 9743/55A GB 974355 A GB974355 A GB 974355A GB 769252 A GB769252 A GB 769252A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl
- methyl
- pigments
- acrylonitrile
- dimethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/16—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by esterified hydroxyl radicals
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/273—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of unsaturated carboxylic esters having epoxy groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coloring (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
An aqueous composition for colouring textiles comprises a pigment mixed with a waterinsoluble linear copolymer containing 1 to 25 per cent of glycidyl acrylate or methacrylate and at least one other monoethylenically unsaturated copolymerizable monomer such as methyl, ethyl, propyl, isopropyl, butyl, isobutyl, amyl, phenyl, benzyl and phenylethyl esters of acrylic, methacrylic, propacrylic, chloroacrylic and bromoacrylic acids, hexyl, heptyl, n-octyl and 2-ethylhexyl esters of acrylic and methacrylic acids, N-dimethyl, -diethyl, -dipropyl, -dibutyl, -diamyl, -dihexyl and -dioctyl acrylamides, styrene, alpha-methyl styrene, dimethylstyrenes, dichlorostyrenes, cyanostyrenes, methoxystyrenes, 4-chloro-1-vinyl naphthalene, vinyl and vinylidene chlorides and bromides, methyl and ethyl vinyl ketones, methyl isopropenyl ketone, dimethyl, diethyl, dipropyl, dibutyl, diphenyl, dibenzyl and di-(phenylethyl) itaconates, vinyl, allyl and methallyl acetates, propionates and valerates, acrylonitrile, methacrylonitrile, vinyl thiophene and 4-vinyl pyridine. The copolymer dispersions are suitably prepared by the copolymerization of the monomers in an aqueous medium in the presence of a non-ionic emulsifying agent, e.g. an ethylene oxide condensation product with tert.-octyl phenol, and a catalyst which preferably consists of a mixture of an oxidizing agent, such as alkali metal and ammonium persulphates and perborates, hydrogen peroxide, tert.-butyl and cumene hydroperoxides and tert.-butyl perbenzoate, and a reducing agent such as sodium hydrosulphite and metabisulphite, water-soluble thiosulphates and salts of metals capable of existing in more than one valence state, e.g. cobalt, nickel, iron and copper. The pigment may be added to the aqueous dispersion either before or after polymerization, suitable pigments being azo-pigments and lakes, phthalocyanine pigments, vatdyestuffs in their water-insoluble form, carbon black, iron oxides, chrome yellows, titanium dioxide, lithopone and metals in powder or flake form, e.g. aluminium, bronze, brass, chromium and gold. The dispersions may also include thickeners such as tragacanth, polyvinyl alcohol, partially saponified polyvinyl acetate, methyl cellulose and hydroxyethyl cellulose. The aqueous compositions are applied to textiles and dried by heating, which results in cross-linking of the copolymer through its epoxy groups, this reaction being accelerated by the addition of catalysts such as ammonium chloride or p-toluene sulphonic acid. Alternatively cross-linking agents may be included in the compositions, for example polyamines, dialdehydes and monomeric or low molecular weight reaction products of an aldehyde with urea, thiourea and biuret and derivatives thereof, triazines and substitution products of biguanide.ALSO:Textile materials are coloured either locally or overall with an aqueous composition comprising a pigment mixed with a water-insoluble copolymer containing 1 to 25 per cent of glycidyl acrylate or methacrylate and at least one other monoethylenically unsaturated copolymerizable monomer such as methyl, ethyl, phepyl, isopropyl, butyl, isobutyl, amyl, pronyl, benzyl, and phenylethyl esters of acrylic, methacrylic, propacrylic, chloroacrylic and bromoacrylic acids, hexyl, heptyl, n-octyl and 2 - ethylhexyl esters of acrylic and methacrylic acids, N - dimethyl, -diethyl, -dipropyl, -dibutyl, -diamyl, -dihexyl and -dioctyl acrylamides, styrene, alphamethyl stryrene, dimethyl-styrenes, dichlorostyrenes, cyanostyrenes, methoxystyrenes, 4 - chloro - 1 - vinyl naphthalene, vinyl and vinylidene chlorides and bromides, methyl and ethyl vinyl ketones, methyl isopropenyl ketone, dimethyl, diethyl, dipropyl, dibutyl, diphenyl, dibenzyl and di -(phenylethyl) itaconates, vinyl, allyl and methallyl acetates, propionates and valerates, acrylonitrile, methacrylonitrile, vinyl thiophene and 4 - vinyl pyridine. Pigments specified are azo-pigments and lakes, phthalocyanine pigments, vat dyestuffs in their water-insoluble form, carbon black, iron oxides, chrome yellows, titanium oxides, lithopone and metals in powder or flake form, e.g. aluminium, bronze, brass, chromium and gold. The dispersions may also include thickeners such as tragacanth, polyvinyl alcohol, partially saponified polyvinyl acetate, methyl cellulose and hydroxyethyl cellulose. The fabrics to which the compositions are applied may be made from fibres of cotton, rayon, wool, silk, linen, cellulose acetate, casein, soya bean protein, polyamides, polyglycol terephthalate, polyethylene, polyvinyl and polyvinylidene chlorides, polyacrylonitrile, copolmers of vinyl chloride with vinyl acetate, acrylonitrile or vinylidene chloride, copolymers of vinylidene chloride with vinyl acetate, ethylene or acrylonitrile and copolymers of acrylonitrile with vinyl acetate, methacrylonitrile or vinyl pyridines. The dispersions are applied to the textiles and dried by heating which results in cross-linking through the epoxy groups of the copolymer. Alternatively cross-linking agents may be included in the compositions, for example dialdehydes, polyamines and monomeric or low molecular weight reaction products of an aldehyde with urea, thiourea and biuret and derivatives thereof, triazines and substitution products of biguanide.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US769252XA | 1954-04-14 | 1954-04-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB769252A true GB769252A (en) | 1957-03-06 |
Family
ID=22135018
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB9743/55A Expired GB769252A (en) | 1954-04-14 | 1955-04-04 | Improvements in or relating to textile coloring compositions |
Country Status (2)
Country | Link |
---|---|
FR (3) | FR1128526A (en) |
GB (1) | GB769252A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10597817B2 (en) | 2017-09-12 | 2020-03-24 | Cotton, Inc. | Balance of durable press properties of cotton fabrics using non-formaldehyde technology |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU530553B2 (en) * | 1978-05-09 | 1983-07-21 | Commonwealth Scientific And Industrial Research Organisation | Treatment of textile materials |
-
1955
- 1955-04-04 GB GB9743/55A patent/GB769252A/en not_active Expired
- 1955-04-07 FR FR1128526D patent/FR1128526A/en not_active Expired
- 1955-04-13 FR FR1122577D patent/FR1122577A/en not_active Expired
- 1955-04-13 FR FR1122576D patent/FR1122576A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10597817B2 (en) | 2017-09-12 | 2020-03-24 | Cotton, Inc. | Balance of durable press properties of cotton fabrics using non-formaldehyde technology |
Also Published As
Publication number | Publication date |
---|---|
FR1128526A (en) | 1957-01-07 |
FR1122576A (en) | 1956-09-10 |
FR1122577A (en) | 1956-09-10 |
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