Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB15043/46A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Acordis UK Ltd
Original Assignee
British Celanese Ltd
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Filing date
Publication date
Application filed by British Celanese LtdfiledCriticalBritish Celanese Ltd
Publication of GB612346ApublicationCriticalpatent/GB612346A/en
C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
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Chemical & Material Sciences
(AREA)
Organic Chemistry
(AREA)
Engineering & Computer Science
(AREA)
Oil, Petroleum & Natural Gas
(AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof
(AREA)
Abstract
Crotonic acid is prepared by catalytic oxidation of crotonaldehyde with oxygen in a liquid medium at 5-10 DEG C. The solvent is preferably glacial acetic acid, and the catalyst preferably comprises a mixture of manganese acetate and potassium permanganate. The oxidation may be made continuous by alternately using dual oxidation vessels.
GB15043/46A1945-05-191946-05-17Manufacture of crotonic acid
ExpiredGB612346A
(en)
PROCEDURE FOR THE PREPARATION OF ALLYL ACETATE IN GAS PHASE BY TRANSPOSITION OF PROPENE, OXYGEN OR ACID-CONTAINING GASES AND ETHIC ACID IN THE PRESENCE OF PALLADIUM-CONTAINING ALKALY ACETATE CONTAINING CATALYSTS