GB599778A - Improvements relating to the production of phosphate coatings on metal - Google Patents

Improvements relating to the production of phosphate coatings on metal

Info

Publication number
GB599778A
GB599778A GB2971145A GB2971145A GB599778A GB 599778 A GB599778 A GB 599778A GB 2971145 A GB2971145 A GB 2971145A GB 2971145 A GB2971145 A GB 2971145A GB 599778 A GB599778 A GB 599778A
Authority
GB
United Kingdom
Prior art keywords
metal
phosphate
nitrate
ammonium nitrate
guanidine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2971145A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SYDNEY WALGATE JOHNSON
Pyrene Co Ltd
Original Assignee
SYDNEY WALGATE JOHNSON
Pyrene Co Ltd
Filing date
Publication date
Application filed by SYDNEY WALGATE JOHNSON, Pyrene Co Ltd filed Critical SYDNEY WALGATE JOHNSON
Publication of GB599778A publication Critical patent/GB599778A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08Orthophosphates
    • C23C22/10Orthophosphates containing oxidants

Abstract

In a process for coating a metal or alloy surface with a phosphate, the surface is treated with a phosphate solution containing a heavy metal phosphate, i.e. a phosphate of a metal other than an alkaline or alkaline earth metal, with or without free phosphoric acid, in which the accelerator is ammonium nitrate which is reduced to an unstable nitrite. The ammonium nitrate may be replaced by a metal nitrate and an ammonium salt other than the nitrate or urea, hydrazine, guanidine, amino-guanidine sulphamic acid or a sulphamate or a mixture thereof. The solution may contain ferrous iron and the heavy metal may be iron, manganese, zinc or cadmium. The free acid should be maintained at a low value, e.g. by suspending scrap ferrous metal in the bath. The bath may be replenished by adding a concentrated chemical containing phosphoric acid and ammonium nitrate, or an equivalent mixture, in the required proportions. Specifications 386,739 and 514,443 are referred to.
GB2971145A 1945-11-07 Improvements relating to the production of phosphate coatings on metal Expired GB599778A (en)

Publications (1)

Publication Number Publication Date
GB599778A true GB599778A (en) 1948-03-19

Family

ID=1741727

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2971145A Expired GB599778A (en) 1945-11-07 Improvements relating to the production of phosphate coatings on metal

Country Status (1)

Country Link
GB (1) GB599778A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3178319A (en) * 1958-06-05 1965-04-13 Geraldine D Henricks Phosphate coating compositions and methods of making and using the same
EP0134895A1 (en) * 1983-07-19 1985-03-27 Gerhard Collardin GmbH Process and compounds for applying accelerated and grain-refined phosphate coatings to metallic surfaces
CN112458444A (en) * 2020-11-30 2021-03-09 李力 Iron-based composite protective film without heavy metal and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3178319A (en) * 1958-06-05 1965-04-13 Geraldine D Henricks Phosphate coating compositions and methods of making and using the same
EP0134895A1 (en) * 1983-07-19 1985-03-27 Gerhard Collardin GmbH Process and compounds for applying accelerated and grain-refined phosphate coatings to metallic surfaces
CN112458444A (en) * 2020-11-30 2021-03-09 李力 Iron-based composite protective film without heavy metal and preparation method thereof
CN112458444B (en) * 2020-11-30 2022-11-29 李力 Iron-based composite protective film without heavy metal and preparation method thereof

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