GB464667A - Method of producing hydrogen by converting carbon monoxide with steam - Google Patents

Method of producing hydrogen by converting carbon monoxide with steam

Info

Publication number
GB464667A
GB464667A GB26169/36A GB2616936A GB464667A GB 464667 A GB464667 A GB 464667A GB 26169/36 A GB26169/36 A GB 26169/36A GB 2616936 A GB2616936 A GB 2616936A GB 464667 A GB464667 A GB 464667A
Authority
GB
United Kingdom
Prior art keywords
iron ore
steam
carbon monoxide
oxide
iron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB26169/36A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Osterreichisch Amerikanische Magnesit AG
Original Assignee
Osterreichisch Amerikanische Magnesit AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Osterreichisch Amerikanische Magnesit AG filed Critical Osterreichisch Amerikanische Magnesit AG
Publication of GB464667A publication Critical patent/GB464667A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

The production of hydrogen from carbon monoxide and steam at temperatures below 500 DEG C. is carried out with the aid of a catalyst consisting of magnesium oxide, alkali carbonate (preferably potassium carbonate), carbonaceous substances, e.g. wood charcoal, and iron oxide in the form of natural iron ore. Suitable ores include haematite, micaceous iron ore, blood stone, limonite, bog iron ore, gothite and ores which yield ferric oxide or hydroxide at the working temperature, e.g. siderite, magnetite or breunerite. The proportion of iron oxide to the total quantity of magnesium oxide and alkali carbonate may vary from 1 : 30 to 1 : 2, but preferably the iron oxide should not exceed 10 per cent of the catalyst mass. According to an example, caustic magnesia and dried bog iron ore are mixed together. Wood charcoal is added and the mixing repeated. A concentrated solution of potassium carbonate and a binding agent, e.g. wet asphalt are then added and the mixture passed through a pug mill. The mixture is then compressed at and heated at 800 DEG C., with exclusion of air. The reaction between carbon monoxide and steam is preferably carried out at temperatures up to 500 DEG C. in the initial zone, and the temperature is allowed to decrease gradually in the succeeding zones, being between 350 and 370 DEG C. at the discharge end of the furnace.
GB26169/36A 1935-10-23 1936-09-26 Method of producing hydrogen by converting carbon monoxide with steam Expired GB464667A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
AT464667X 1935-10-23

Publications (1)

Publication Number Publication Date
GB464667A true GB464667A (en) 1937-04-22

Family

ID=3674638

Family Applications (1)

Application Number Title Priority Date Filing Date
GB26169/36A Expired GB464667A (en) 1935-10-23 1936-09-26 Method of producing hydrogen by converting carbon monoxide with steam

Country Status (6)

Country Link
US (1) US2147780A (en)
BE (1) BE417743A (en)
DE (1) DE706868C (en)
FR (1) FR811736A (en)
GB (1) GB464667A (en)
NL (1) NL44648C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3512831A (en) * 1964-08-24 1970-05-19 Hyland C Flint Spring seat
US4054644A (en) * 1972-03-16 1977-10-18 Exxon Research & Engineering Co. Water gas shift process

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE467131A (en) * 1945-08-28
US2950258A (en) * 1956-08-29 1960-08-23 Phillips Petroleum Co Dehydrogenation catalyst
US3539297A (en) * 1968-04-08 1970-11-10 Exxon Research Engineering Co Preventing catalyst poisoning by sulfur
BE758677A (en) * 1969-11-10 1971-05-10 Exxon Research Engineering Co NEW CATALYST FOR THE PRODUCTION OF HYDROGEN BY DISPLACING GAS TO WATER
DE2409762A1 (en) * 1974-03-01 1975-10-09 Rheinische Braunkohlenw Ag PROCESS FOR THE PRODUCTION OF HYDROGEN
US4595787A (en) * 1985-06-24 1986-06-17 Phillips Petroleum Company Potassium carbonate supports, catalysts and olefin dimerization processes therewith
US5171914A (en) * 1991-08-30 1992-12-15 Shell Oil Company Dehydrogenation catalyst and process
US20060177639A1 (en) * 2005-02-04 2006-08-10 Elzen Kerstin T Process for the production of primer surfacer-free multi-layer coatings

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3512831A (en) * 1964-08-24 1970-05-19 Hyland C Flint Spring seat
US4054644A (en) * 1972-03-16 1977-10-18 Exxon Research & Engineering Co. Water gas shift process

Also Published As

Publication number Publication date
US2147780A (en) 1939-02-21
NL44648C (en)
FR811736A (en) 1937-04-21
DE706868C (en) 1941-06-07
BE417743A (en)

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