GB358988A - Improvements in or relating to the treatment of coal with solvents - Google Patents
Improvements in or relating to the treatment of coal with solventsInfo
- Publication number
- GB358988A GB358988A GB11578/30A GB1157830A GB358988A GB 358988 A GB358988 A GB 358988A GB 11578/30 A GB11578/30 A GB 11578/30A GB 1157830 A GB1157830 A GB 1157830A GB 358988 A GB358988 A GB 358988A
- Authority
- GB
- United Kingdom
- Prior art keywords
- coal
- tar
- sulphur
- autoclave
- chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003245 coal Substances 0.000 title abstract 8
- 239000002904 solvent Substances 0.000 title abstract 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 5
- 239000005864 Sulphur Substances 0.000 abstract 5
- 239000011269 tar Substances 0.000 abstract 4
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 abstract 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 3
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 abstract 2
- 239000003921 oil Substances 0.000 abstract 2
- 235000005074 zinc chloride Nutrition 0.000 abstract 2
- 239000011592 zinc chloride Substances 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000011284 carbonization tar Substances 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 235000011118 potassium hydroxide Nutrition 0.000 abstract 1
- 238000010992 reflux Methods 0.000 abstract 1
- 239000011288 water-gas tar Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/04—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by extraction
Abstract
In making solutions of coal as coal to obtain coal products as described in Specification 268,372, [Class 91, Oils &c.], the solvent power of the oils and tars specified is increased by dehydrogenating them by treatment with sulphur or/and oxygen either prior to or during treatment of the coal. Condensation aids such as zinc chloride, aluminium chloride, potassium hydrate, and metal oxides, may be present. The products may be more or less freed from sulphur in any manner, e.g. by heating to higher temperatures in an autoclave and allowing the hydrogen sulphide formed to escape. For example, water-gas tar or low-temperature carbonization tar is refluxed with 10 per cent by weight of sulphur for about 6 hrs.; when evolution of sulphuretted hydrogen ceases 20 per cent of fused zinc chloride is added and refluxing continued for about 9 hrs. The tar is then separated from the chloride, and used as solvent. It is stated to be less viscous, of better colour, and lower sulphur content, and of greater solvent power for coal than the original tar. Or 80 lb. of tar, 8 lb. of sulphur, and 20 lb. of coal are heated to 320 DEG C. in a rotating autoclave until the pressure ceases to increase; the autoclave is allowed to cool to below 200 DEG C., the hydrogen sulphide allowed to escape, and the coal solution discharged.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US358988XA | 1929-04-12 | 1929-04-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB358988A true GB358988A (en) | 1931-10-12 |
Family
ID=21885441
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB11578/30A Expired GB358988A (en) | 1929-04-12 | 1930-04-11 | Improvements in or relating to the treatment of coal with solvents |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE579033C (en) |
| GB (1) | GB358988A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2156841A (en) * | 1984-04-03 | 1985-10-16 | Coal Ind | Improvements in coal liquefaction |
-
1930
- 1930-04-11 DE DE1930579033D patent/DE579033C/en not_active Expired
- 1930-04-11 GB GB11578/30A patent/GB358988A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2156841A (en) * | 1984-04-03 | 1985-10-16 | Coal Ind | Improvements in coal liquefaction |
Also Published As
| Publication number | Publication date |
|---|---|
| DE579033C (en) | 1933-06-20 |
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