GB1591064A - Optical elements having reduced undesired reflectance - Google Patents
Optical elements having reduced undesired reflectance Download PDFInfo
- Publication number
- GB1591064A GB1591064A GB3720077A GB3720077A GB1591064A GB 1591064 A GB1591064 A GB 1591064A GB 3720077 A GB3720077 A GB 3720077A GB 3720077 A GB3720077 A GB 3720077A GB 1591064 A GB1591064 A GB 1591064A
- Authority
- GB
- United Kingdom
- Prior art keywords
- approximately
- layer
- refractive index
- silicon
- optical element
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000003287 optical effect Effects 0.000 title claims description 70
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 78
- 239000000377 silicon dioxide Substances 0.000 claims description 37
- 235000012239 silicon dioxide Nutrition 0.000 claims description 37
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 33
- 239000010703 silicon Substances 0.000 claims description 33
- 229910052710 silicon Inorganic materials 0.000 claims description 33
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 25
- 238000000576 coating method Methods 0.000 claims description 18
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 claims description 18
- 229920001059 synthetic polymer Polymers 0.000 claims description 18
- JHQVCQDWGSXTFE-UHFFFAOYSA-N 2-(2-prop-2-enoxycarbonyloxyethoxy)ethyl prop-2-enyl carbonate Chemical group C=CCOC(=O)OCCOCCOC(=O)OCC=C JHQVCQDWGSXTFE-UHFFFAOYSA-N 0.000 claims description 15
- 229920000642 polymer Polymers 0.000 claims description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000011248 coating agent Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 11
- 239000011521 glass Substances 0.000 claims description 10
- 238000005299 abrasion Methods 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- 238000000151 deposition Methods 0.000 claims description 8
- 229920000515 polycarbonate Polymers 0.000 claims description 8
- 239000004417 polycarbonate Substances 0.000 claims description 8
- 239000003513 alkali Substances 0.000 claims description 7
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 7
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 7
- 238000001704 evaporation Methods 0.000 claims description 6
- 239000004408 titanium dioxide Substances 0.000 claims description 5
- 230000003667 anti-reflective effect Effects 0.000 claims description 4
- 229910052681 coesite Inorganic materials 0.000 claims description 4
- 229910052906 cristobalite Inorganic materials 0.000 claims description 4
- 230000001419 dependent effect Effects 0.000 claims description 4
- 238000010894 electron beam technology Methods 0.000 claims description 4
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 4
- 229910052682 stishovite Inorganic materials 0.000 claims description 4
- 229910052905 tridymite Inorganic materials 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 235000013351 cheese Nutrition 0.000 claims description 2
- 238000011109 contamination Methods 0.000 claims description 2
- 239000004744 fabric Substances 0.000 claims description 2
- 239000003921 oil Substances 0.000 claims description 2
- 230000002035 prolonged effect Effects 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 66
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 8
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 230000033444 hydroxylation Effects 0.000 description 5
- 238000005805 hydroxylation reaction Methods 0.000 description 5
- 229920000307 polymer substrate Polymers 0.000 description 5
- 239000011241 protective layer Substances 0.000 description 5
- 238000001771 vacuum deposition Methods 0.000 description 5
- 230000008020 evaporation Effects 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- -1 diallyl glycol carbonates Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- 229920004142 LEXAN™ Polymers 0.000 description 2
- 239000004418 Lexan Substances 0.000 description 2
- 230000001476 alcoholic effect Effects 0.000 description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N anhydrous diethylene glycol Natural products OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 2
- 239000006117 anti-reflective coating Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 229910052810 boron oxide Inorganic materials 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000009834 vaporization Methods 0.000 description 2
- 238000001429 visible spectrum Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- QCCDYNYSHILRDG-UHFFFAOYSA-K cerium(3+);trifluoride Chemical compound [F-].[F-].[F-].[Ce+3] QCCDYNYSHILRDG-UHFFFAOYSA-K 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D11/00—Producing optical elements, e.g. lenses or prisms
- B29D11/0073—Optical laminates
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/11—Anti-reflection coatings
- G02B1/113—Anti-reflection coatings using inorganic layer materials only
- G02B1/115—Multilayers
Landscapes
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Ophthalmology & Optometry (AREA)
- Mechanical Engineering (AREA)
- Surface Treatment Of Optical Elements (AREA)
- Eyeglasses (AREA)
- Physical Vapour Deposition (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US72685176A | 1976-09-27 | 1976-09-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1591064A true GB1591064A (en) | 1981-06-10 |
Family
ID=24920271
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3720077A Expired GB1591064A (en) | 1976-09-27 | 1977-09-06 | Optical elements having reduced undesired reflectance |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS5342743A (enrdf_load_stackoverflow) |
| BR (1) | BR7706393A (enrdf_load_stackoverflow) |
| CA (1) | CA1115142A (enrdf_load_stackoverflow) |
| DE (1) | DE2738044C2 (enrdf_load_stackoverflow) |
| FR (1) | FR2365813A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1591064A (enrdf_load_stackoverflow) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5424876A (en) * | 1991-10-31 | 1995-06-13 | Asahi Kogaku Kogyo Kabushiki Kaisha | Surface reflecting mirror having a silicon dioxide under layer |
| US5709930A (en) * | 1994-08-24 | 1998-01-20 | Glaverbel | Coated substrate |
| EP1058048A3 (de) * | 1999-06-01 | 2004-06-30 | Hella KG Hueck & Co. | Kunststoffscheibe von Kraftfahrzeugscheinwerfern und Kraftfahrzeugleuchten |
| WO2012013361A3 (en) * | 2010-07-30 | 2012-04-26 | Sony Corporation | A polymeric substrate having a glass-like surface and a chip made of said polymeric substrate |
| WO2012173596A1 (en) * | 2011-06-13 | 2012-12-20 | Essilor Internation (Compagnie General D'optique) | Method for obtaining optical articles having superior abrasion resistant properties, and coated articles prepared according to such method |
| EP3037851A1 (en) * | 2014-12-23 | 2016-06-29 | ESSILOR INTERNATIONAL (Compagnie Générale d'Optique) | Adaptation layer for antireflective designs on lenses of various refractive indexes |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4545646A (en) * | 1983-09-02 | 1985-10-08 | Hughes Aircraft Company | Process for forming a graded index optical material and structures formed thereby |
| DE3332872A1 (de) * | 1983-09-12 | 1985-04-04 | Optische Werke G. Rodenstock, 8000 München | Reflexionsvermindernder belag fuer ein optisches element aus organischem material |
| DE3441948A1 (de) * | 1984-11-16 | 1986-05-28 | Bayer Ag, 5090 Leverkusen | Antireflex beschichtete, transparente abdeckung von zeichen, insbesondere fuer anzeigegeraete |
| DE3818341C2 (de) * | 1987-06-04 | 1993-10-28 | Olympus Optical Co | Teildurchlässiger Spiegel aus Kunststoff |
| JPH0530807Y2 (enrdf_load_stackoverflow) * | 1987-12-10 | 1993-08-06 | ||
| JPH01273001A (ja) * | 1988-04-25 | 1989-10-31 | Olympus Optical Co Ltd | 合成樹脂製光学部品の反射防止膜 |
| DE4117256A1 (de) * | 1989-12-19 | 1992-12-03 | Leybold Ag | Belag, bestehend aus einem optisch wirkenden schichtsystem, fuer substrate, wobei das schichtsystem insbesondere eine hohe antireflexwirkung aufweist |
| US5170291A (en) * | 1989-12-19 | 1992-12-08 | Leybold Aktiengesellschaft | Coating, composed of an optically effective layer system, for substrates, whereby the layer system has a high anti-reflective effect, and method for manufacturing the coating |
| DE4128547A1 (de) * | 1991-08-28 | 1993-03-04 | Leybold Ag | Verfahren und vorrichtung fuer die herstellung einer entspiegelungsschicht auf linsen |
| DE4430363A1 (de) * | 1994-08-26 | 1996-02-29 | Leybold Ag | Optische Linse aus einem klarsichtigen Kunststoff |
| AU756842B2 (en) * | 2000-08-29 | 2003-01-23 | Hoya Corporation | Optical element having antireflection film |
| KR101586073B1 (ko) * | 2014-08-20 | 2016-01-19 | 한국과학기술연구원 | 무반사 나노코팅 구조 및 그 제조방법 |
| FR3055157B1 (fr) * | 2016-08-19 | 2018-09-07 | Essilor International | Lentille ophtalmique a revetement multicouche reflechissant et anti-abrasion, et son procede de fabrication. |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3356522A (en) * | 1964-02-10 | 1967-12-05 | Mc Donnell Douglas Corp | Polycarbonate film containing an antireflection coating |
| GB1136218A (en) * | 1965-12-14 | 1968-12-11 | Standard Telephones Cables Ltd | Improvements in or relating to the manufacture of semiconductor optical devices |
| JPS5622177Y2 (enrdf_load_stackoverflow) * | 1971-09-01 | 1981-05-25 | ||
| DE2210505A1 (de) * | 1972-03-04 | 1973-09-20 | Zeiss Carl Fa | Verfahren zur herstellung einer entspiegelungsschicht auf optischen elementen aus transparentem thermisch empfindlichem material, insbesondere aus kunststoff |
| US3991234A (en) * | 1974-09-30 | 1976-11-09 | American Optical Corporation | Process for coating a lens of synthetic polymer with a durable abrasion resistant vitreous composition |
-
1977
- 1977-08-19 DE DE19772738044 patent/DE2738044C2/de not_active Expired
- 1977-08-29 FR FR7726149A patent/FR2365813A1/fr active Granted
- 1977-09-06 GB GB3720077A patent/GB1591064A/en not_active Expired
- 1977-09-09 CA CA286,388A patent/CA1115142A/en not_active Expired
- 1977-09-21 JP JP11275077A patent/JPS5342743A/ja active Granted
- 1977-09-26 BR BR7706393A patent/BR7706393A/pt unknown
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2261079B (en) * | 1991-10-31 | 1995-06-14 | Asahi Optical Co Ltd | Surface reflecting mirror |
| US5583704A (en) * | 1991-10-31 | 1996-12-10 | Asahi Kogaku Kogyo Kabushiki Kaisha | Surface reflecting mirror having a surface reflecting multilayer film |
| US5424876A (en) * | 1991-10-31 | 1995-06-13 | Asahi Kogaku Kogyo Kabushiki Kaisha | Surface reflecting mirror having a silicon dioxide under layer |
| US5709930A (en) * | 1994-08-24 | 1998-01-20 | Glaverbel | Coated substrate |
| EP1058048A3 (de) * | 1999-06-01 | 2004-06-30 | Hella KG Hueck & Co. | Kunststoffscheibe von Kraftfahrzeugscheinwerfern und Kraftfahrzeugleuchten |
| CN103080197B (zh) * | 2010-07-30 | 2015-10-07 | 索尼公司 | 具有玻璃样表面的聚合物衬底和由所述聚合物衬底制成的芯片 |
| WO2012013361A3 (en) * | 2010-07-30 | 2012-04-26 | Sony Corporation | A polymeric substrate having a glass-like surface and a chip made of said polymeric substrate |
| US9586810B2 (en) | 2010-07-30 | 2017-03-07 | Sony Corporation | Polymeric substrate having an etched-glass-like surface and a microfluidic chip made of said polymeric substrate |
| CN103080197A (zh) * | 2010-07-30 | 2013-05-01 | 索尼公司 | 具有玻璃样表面的聚合物衬底和由所述聚合物衬底制成的芯片 |
| CN103597377A (zh) * | 2011-06-13 | 2014-02-19 | 埃西勒国际通用光学公司 | 用于获得具有超级耐磨损特性的光学物品的方法，以及根据这样的方法制备的涂覆物品 |
| US9075189B2 (en) | 2011-06-13 | 2015-07-07 | Essilor International (Compagnie Generale D'optique) | Method for obtaining optical articles having superior abrasion resistant properties, and coated articles prepared according to such method |
| US20140125945A1 (en) * | 2011-06-13 | 2014-05-08 | Essilor International (Compagnie Generale D'optique | Method for Obtaining Optical Articles Having Superior Abrasion Resistant Properties, and Coated Articles Prepared According to Such Method |
| AU2011370999B2 (en) * | 2011-06-13 | 2016-01-14 | Essilor International | Method for obtaining optical articles having superior abrasion resistant properties, and coated articles prepared according to such method |
| CN103597377B (zh) * | 2011-06-13 | 2016-08-17 | 埃西勒国际通用光学公司 | 用于获得具有超级耐磨损特性的光学物品的方法，以及根据这样的方法制备的涂覆物品 |
| EA024640B1 (ru) * | 2011-06-13 | 2016-10-31 | Эссилор Энтернасьональ (Компани Женераль Д'Оптик) | Способ изготовления стойкого к истиранию оптического изделия |
| WO2012173596A1 (en) * | 2011-06-13 | 2012-12-20 | Essilor Internation (Compagnie General D'optique) | Method for obtaining optical articles having superior abrasion resistant properties, and coated articles prepared according to such method |
| EP3037851A1 (en) * | 2014-12-23 | 2016-06-29 | ESSILOR INTERNATIONAL (Compagnie Générale d'Optique) | Adaptation layer for antireflective designs on lenses of various refractive indexes |
| US9835767B2 (en) | 2014-12-23 | 2017-12-05 | Essilor International (Compagnie Generale D'optique) | Adaptation layer for antireflective designs on lenses of various refractive indexes |
Also Published As
| Publication number | Publication date |
|---|---|
| BR7706393A (pt) | 1978-06-06 |
| JPS6232441B2 (enrdf_load_stackoverflow) | 1987-07-15 |
| CA1115142A (en) | 1981-12-29 |
| JPS5342743A (en) | 1978-04-18 |
| DE2738044C2 (de) | 1984-11-29 |
| FR2365813A1 (fr) | 1978-04-21 |
| FR2365813B1 (enrdf_load_stackoverflow) | 1981-12-18 |
| DE2738044A1 (de) | 1978-03-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| 732 | Registration of transactions, instruments or events in the register (sect. 32/1977) | ||
| 732 | Registration of transactions, instruments or events in the register (sect. 32/1977) | ||
| PE20 | Patent expired after termination of 20 years |
Effective date: 19970905 |