GB1589593A - Light-sensitive silver halide photographic material and method of processing thereof - Google Patents
Light-sensitive silver halide photographic material and method of processing thereof Download PDFInfo
- Publication number
- GB1589593A GB1589593A GB3145077A GB3145077A GB1589593A GB 1589593 A GB1589593 A GB 1589593A GB 3145077 A GB3145077 A GB 3145077A GB 3145077 A GB3145077 A GB 3145077A GB 1589593 A GB1589593 A GB 1589593A
- Authority
- GB
- United Kingdom
- Prior art keywords
- tetrazolium
- diphenyl
- silver halide
- light
- photographic material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 silver halide Chemical class 0.000 title claims description 150
- 229910052709 silver Inorganic materials 0.000 title claims description 90
- 239000004332 silver Substances 0.000 title claims description 90
- 239000000463 material Substances 0.000 title claims description 65
- 238000000034 method Methods 0.000 title claims description 36
- 238000012545 processing Methods 0.000 title claims description 17
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 37
- 239000000839 emulsion Substances 0.000 claims description 34
- 239000010410 layer Substances 0.000 claims description 30
- 239000008273 gelatin Substances 0.000 claims description 27
- 229920000159 gelatin Polymers 0.000 claims description 27
- 108010010803 Gelatin Proteins 0.000 claims description 26
- 235000019322 gelatine Nutrition 0.000 claims description 26
- 235000011852 gelatine desserts Nutrition 0.000 claims description 26
- 150000001875 compounds Chemical group 0.000 claims description 18
- 239000004305 biphenyl Substances 0.000 claims description 16
- 235000010290 biphenyl Nutrition 0.000 claims description 15
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 15
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 125000003118 aryl group Chemical group 0.000 claims description 9
- 239000011241 protective layer Substances 0.000 claims description 9
- ZVNPWFOVUDMGRP-UHFFFAOYSA-N 4-methylaminophenol sulfate Chemical compound OS(O)(=O)=O.CNC1=CC=C(O)C=C1.CNC1=CC=C(O)C=C1 ZVNPWFOVUDMGRP-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 150000001450 anions Chemical group 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 7
- KJUGUADJHNHALS-UHFFFAOYSA-N 1H-tetrazole Chemical compound C=1N=NNN=1 KJUGUADJHNHALS-UHFFFAOYSA-N 0.000 claims description 6
- FJMPZWOQMLJCRS-UHFFFAOYSA-N 2,3-diphenyl-1h-tetrazole-5-carbonitrile Chemical compound N1C(C#N)=NN(C=2C=CC=CC=2)N1C1=CC=CC=C1 FJMPZWOQMLJCRS-UHFFFAOYSA-N 0.000 claims description 6
- 229910021607 Silver chloride Inorganic materials 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 claims description 6
- IXNKNVCYDIVHSA-UHFFFAOYSA-N 2-(4-methylphenyl)-3,5-diphenyl-1h-tetrazole Chemical compound C1=CC(C)=CC=C1N1N(C=2C=CC=CC=2)N=C(C=2C=CC=CC=2)N1 IXNKNVCYDIVHSA-UHFFFAOYSA-N 0.000 claims description 5
- ZNVBVIZZKGKHRB-UHFFFAOYSA-N 2-(5-dodecyl-3-phenyl-1H-tetrazol-2-yl)-1,3-benzothiazole Chemical compound N=1C2=CC=CC=C2SC=1N1NC(CCCCCCCCCCCC)=NN1C1=CC=CC=C1 ZNVBVIZZKGKHRB-UHFFFAOYSA-N 0.000 claims description 5
- NDQDVFVHOJQAII-UHFFFAOYSA-N 4-[5-(4-nitrophenyl)-3-phenyl-1H-tetrazol-2-yl]phenol Chemical compound C1=CC(O)=CC=C1N1N(C=2C=CC=CC=2)N=C(C=2C=CC(=CC=2)[N+]([O-])=O)N1 NDQDVFVHOJQAII-UHFFFAOYSA-N 0.000 claims description 5
- QRIJAXWENLJOBO-UHFFFAOYSA-N N1N(C=2C=CC=CC=2)N(C=2C=CC=CC=2)N=C1C(C(=C1C=2C=CC=CC=2)C=2C=CC=CC=2)=CC=C1C=1N=NNN=1 Chemical compound N1N(C=2C=CC=CC=2)N(C=2C=CC=CC=2)N=C1C(C(=C1C=2C=CC=CC=2)C=2C=CC=CC=2)=CC=C1C=1N=NNN=1 QRIJAXWENLJOBO-UHFFFAOYSA-N 0.000 claims description 5
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 claims description 5
- 125000004190 benzothiazol-2-yl group Chemical group [H]C1=C([H])C([H])=C2N=C(*)SC2=C1[H] 0.000 claims description 5
- MQRJBSHKWOFOGF-UHFFFAOYSA-L disodium;carbonate;hydrate Chemical compound O.[Na+].[Na+].[O-]C([O-])=O MQRJBSHKWOFOGF-UHFFFAOYSA-L 0.000 claims description 5
- 229940076133 sodium carbonate monohydrate Drugs 0.000 claims description 5
- XXWAHKICOZTQOW-UHFFFAOYSA-N 1-[2,3-bis(4-ethoxyphenyl)-1H-tetrazol-5-yl]ethanone Chemical compound C1=CC(OCC)=CC=C1N1N(C=2C=CC(OCC)=CC=2)N=C(C(C)=O)N1 XXWAHKICOZTQOW-UHFFFAOYSA-N 0.000 claims description 4
- QOIRFXTZHVPXLR-UHFFFAOYSA-N 2,3,5-triphenyl-1h-tetrazole Chemical compound N1N(C=2C=CC=CC=2)N(C=2C=CC=CC=2)N=C1C1=CC=CC=C1 QOIRFXTZHVPXLR-UHFFFAOYSA-N 0.000 claims description 4
- QACDNZQVHQGFAB-UHFFFAOYSA-N 2-(2,3-diphenyl-1H-tetrazol-5-yl)-1,3-benzoxazole Chemical compound N1=C(C=2OC3=CC=CC=C3N=2)NN(C=2C=CC=CC=2)N1C1=CC=CC=C1 QACDNZQVHQGFAB-UHFFFAOYSA-N 0.000 claims description 4
- ASJSXUWOFZATJM-UHFFFAOYSA-N 2-(3,5-diphenyl-1h-tetrazol-2-yl)-4,5-dimethyl-1,3-thiazole Chemical compound S1C(C)=C(C)N=C1N1N(C=2C=CC=CC=2)NC(C=2C=CC=CC=2)=N1 ASJSXUWOFZATJM-UHFFFAOYSA-N 0.000 claims description 4
- HWLXUQATWPNSAO-UHFFFAOYSA-N 2-[3-(4-methoxyphenyl)-5-phenyl-1H-tetrazol-2-yl]-1,3-benzothiazole Chemical compound C1=CC(OC)=CC=C1N1N(C=2SC3=CC=CC=C3N=2)NC(C=2C=CC=CC=2)=N1 HWLXUQATWPNSAO-UHFFFAOYSA-N 0.000 claims description 4
- XHIPMTBCWNNSFM-UHFFFAOYSA-N 5-hexyl-2,3-diphenyl-1H-tetrazole Chemical compound N1C(CCCCCC)=NN(C=2C=CC=CC=2)N1C1=CC=CC=C1 XHIPMTBCWNNSFM-UHFFFAOYSA-N 0.000 claims description 4
- HLRFVQODVVUZEA-UHFFFAOYSA-N N1N(C=2C=CC=CC=2)N(N2N=CC=CN2)N=C1C1=CC=CC=C1 Chemical compound N1N(C=2C=CC=CC=2)N(N2N=CC=CN2)N=C1C1=CC=CC=C1 HLRFVQODVVUZEA-UHFFFAOYSA-N 0.000 claims description 4
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 4
- 125000000623 heterocyclic group Chemical group 0.000 claims description 4
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 claims description 4
- 125000000636 p-nitrophenyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)[N+]([O-])=O 0.000 claims description 4
- 230000035945 sensitivity Effects 0.000 claims description 4
- 125000003107 substituted aryl group Chemical group 0.000 claims description 4
- WFTGTFCWWWPJAF-UHFFFAOYSA-N 1-(2,3-diphenyl-1H-tetrazol-5-yl)ethanone Chemical compound N1C(C(=O)C)=NN(C=2C=CC=CC=2)N1C1=CC=CC=C1 WFTGTFCWWWPJAF-UHFFFAOYSA-N 0.000 claims description 3
- OMPBPIPZACGTHR-UHFFFAOYSA-N 2,3-diphenyl-1H-tetrazole Chemical compound N1C=NN(C=2C=CC=CC=2)N1C1=CC=CC=C1 OMPBPIPZACGTHR-UHFFFAOYSA-N 0.000 claims description 3
- 125000000175 2-thienyl group Chemical group S1C([*])=C([H])C([H])=C1[H] 0.000 claims description 3
- KPXPTOUFIZYILY-UHFFFAOYSA-N 4-(2,3-diphenyl-1H-tetrazol-5-yl)pyridine Chemical compound N1N(C=2C=CC=CC=2)N(C=2C=CC=CC=2)N=C1C1=CC=NC=C1 KPXPTOUFIZYILY-UHFFFAOYSA-N 0.000 claims description 3
- HLQLADJVXUGAKG-UHFFFAOYSA-N 5-ethyl-2,3-diphenyl-1h-tetrazole Chemical compound N1C(CC)=NN(C=2C=CC=CC=2)N1C1=CC=CC=C1 HLQLADJVXUGAKG-UHFFFAOYSA-N 0.000 claims description 3
- TXCKVRLFZFJSDF-UHFFFAOYSA-N 5-methyl-2,3-diphenyl-1h-tetrazole Chemical compound N1C(C)=NN(C=2C=CC=CC=2)N1C1=CC=CC=C1 TXCKVRLFZFJSDF-UHFFFAOYSA-N 0.000 claims description 3
- NIPMJVLJVGQZRB-UHFFFAOYSA-N Cl[IH]Br Chemical compound Cl[IH]Br NIPMJVLJVGQZRB-UHFFFAOYSA-N 0.000 claims description 3
- BNIUVQHHCJXGHT-UHFFFAOYSA-N N=1N(C=2C=CC=CC=2)N(C=2C=CC=CC=2)NC=1CC(C=1C=CC=CC=1)C(C=1C=CC=CC=1)CC=1N=NNN=1 Chemical compound N=1N(C=2C=CC=CC=2)N(C=2C=CC=CC=2)NC=1CC(C=1C=CC=CC=1)C(C=1C=CC=CC=1)CC=1N=NNN=1 BNIUVQHHCJXGHT-UHFFFAOYSA-N 0.000 claims description 3
- 125000000732 arylene group Chemical group 0.000 claims description 3
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 125000005874 benzothiadiazolyl group Chemical group 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 2
- 125000002971 oxazolyl group Chemical group 0.000 claims description 2
- 125000004076 pyridyl group Chemical group 0.000 claims description 2
- 125000000714 pyrimidinyl group Chemical group 0.000 claims description 2
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 2
- 125000001113 thiadiazolyl group Chemical group 0.000 claims description 2
- XKAKMCNHHNUUGN-UHFFFAOYSA-N 4-(5-methyl-3-phenyl-1H-tetrazol-2-yl)phenol Chemical compound N1C(C)=NN(C=2C=CC=CC=2)N1C1=CC=C(O)C=C1 XKAKMCNHHNUUGN-UHFFFAOYSA-N 0.000 claims 3
- PRRVATRGEFUPRF-UHFFFAOYSA-N 2-(2,3-diphenyl-1H-tetrazol-5-yl)quinoline Chemical compound N1=C(C=2N=C3C=CC=CC3=CC=2)NN(C=2C=CC=CC=2)N1C1=CC=CC=C1 PRRVATRGEFUPRF-UHFFFAOYSA-N 0.000 claims 2
- KNMZXRUWMYCXSG-UHFFFAOYSA-N 2-[3-(4-methylphenyl)-5-phenyl-1H-tetrazol-2-yl]-1,3-benzothiazole Chemical compound C1=CC(C)=CC=C1N1N(C=2SC3=CC=CC=C3N=2)NC(C=2C=CC=CC=2)=N1 KNMZXRUWMYCXSG-UHFFFAOYSA-N 0.000 claims 2
- RAECFAXTJBDZOD-UHFFFAOYSA-N 2-[5-(2-chlorophenyl)-3-phenyl-1H-tetrazol-2-yl]-1,3-benzothiazole Chemical compound ClC1=CC=CC=C1C1=NN(C=2C=CC=CC=2)N(C=2SC3=CC=CC=C3N=2)N1 RAECFAXTJBDZOD-UHFFFAOYSA-N 0.000 claims 2
- KWEKLFATGLFLST-UHFFFAOYSA-N 5-(furan-2-yl)-2,3-diphenyl-1H-tetrazole Chemical compound N1N(C=2C=CC=CC=2)N(C=2C=CC=CC=2)N=C1C1=CC=CO1 KWEKLFATGLFLST-UHFFFAOYSA-N 0.000 claims 2
- SCRSUBWYUBGSPK-UHFFFAOYSA-N 5-nitro-2,3-diphenyl-1H-tetrazole Chemical compound N1C([N+](=O)[O-])=NN(C=2C=CC=CC=2)N1C1=CC=CC=C1 SCRSUBWYUBGSPK-UHFFFAOYSA-N 0.000 claims 2
- 125000003762 3,4-dimethoxyphenyl group Chemical group [H]C1=C([H])C(OC([H])([H])[H])=C(OC([H])([H])[H])C([H])=C1* 0.000 claims 1
- 150000001768 cations Chemical group 0.000 claims 1
- 230000001681 protective effect Effects 0.000 claims 1
- 101150061972 zur gene Proteins 0.000 claims 1
- 239000000243 solution Substances 0.000 description 63
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 32
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 24
- 125000003831 tetrazolyl group Chemical group 0.000 description 15
- 238000011161 development Methods 0.000 description 14
- 239000011248 coating agent Substances 0.000 description 12
- 238000000576 coating method Methods 0.000 description 12
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 9
- 208000015181 infectious disease Diseases 0.000 description 8
- 230000002458 infectious effect Effects 0.000 description 8
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 8
- 229940101006 anhydrous sodium sulfite Drugs 0.000 description 6
- JXCNUCFTHLGXDQ-UHFFFAOYSA-N 2h-tetrazol-2-ium;chloride Chemical compound Cl.C1=NN=NN1 JXCNUCFTHLGXDQ-UHFFFAOYSA-N 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
- 229920000058 polyacrylate Polymers 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 4
- FEGBZZCTJZRSJQ-UHFFFAOYSA-N 2-[2-(4-methoxyphenyl)-5-phenyl-1,3-dihydrotetrazol-3-ium-3-yl]-1,3-benzothiazole;chloride Chemical compound [Cl-].C1=CC(OC)=CC=C1N1[NH+](C=2SC3=CC=CC=C3N=2)N=C(C=2C=CC=CC=2)N1 FEGBZZCTJZRSJQ-UHFFFAOYSA-N 0.000 description 4
- BKFGFBHIORTGEL-UHFFFAOYSA-N 3-[4-[2,3-bis[4-(2-carboxyethyl)phenyl]-1H-tetrazol-5-yl]phenyl]propanoic acid Chemical compound C1=CC(CCC(=O)O)=CC=C1N1N(C=2C=CC(CCC(O)=O)=CC=2)N=C(C=2C=CC(CCC(O)=O)=CC=2)N1 BKFGFBHIORTGEL-UHFFFAOYSA-N 0.000 description 4
- YUUSISNBOVSHOI-UHFFFAOYSA-N 5-(4-bromophenyl)-3-phenyl-2-(2,4,6-trichlorophenyl)-1,3-dihydrotetrazol-3-ium;chloride Chemical compound [Cl-].ClC1=CC(Cl)=CC(Cl)=C1N1[NH+](C=2C=CC=CC=2)N=C(C=2C=CC(Br)=CC=2)N1 YUUSISNBOVSHOI-UHFFFAOYSA-N 0.000 description 4
- QSRWBKPZDIVSSZ-UHFFFAOYSA-N 5-ethyl-2,3-diphenyl-1,3-dihydrotetrazol-3-ium;chloride Chemical compound [Cl-].[NH2+]1C(CC)=NN(C=2C=CC=CC=2)N1C1=CC=CC=C1 QSRWBKPZDIVSSZ-UHFFFAOYSA-N 0.000 description 4
- XMFHLCILBOUUDK-UHFFFAOYSA-N C1=CC(OC(C)(C)CC(C)(C)C)=CC=C1C1=NN(C=2C=CC=CC=2)N(C=2C=CC=CC=2)N1 Chemical compound C1=CC(OC(C)(C)CC(C)(C)C)=CC=C1C1=NN(C=2C=CC=CC=2)N(C=2C=CC=CC=2)N1 XMFHLCILBOUUDK-UHFFFAOYSA-N 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 238000003672 processing method Methods 0.000 description 4
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 4
- 229910052721 tungsten Inorganic materials 0.000 description 4
- 239000010937 tungsten Substances 0.000 description 4
- KVVCFVUUHKDIST-UHFFFAOYSA-N 1-[2,3-bis(4-ethoxyphenyl)-1,3-dihydrotetrazol-3-ium-5-yl]ethanone;chloride Chemical compound [Cl-].C1=CC(OCC)=CC=C1N1[NH+](C=2C=CC(OCC)=CC=2)N=C(C(C)=O)N1 KVVCFVUUHKDIST-UHFFFAOYSA-N 0.000 description 3
- PKDBCJSWQUOKDO-UHFFFAOYSA-M 2,3,5-triphenyltetrazolium chloride Chemical compound [Cl-].C1=CC=CC=C1C(N=[N+]1C=2C=CC=CC=2)=NN1C1=CC=CC=C1 PKDBCJSWQUOKDO-UHFFFAOYSA-M 0.000 description 3
- NIKHKQWWXBDHGC-UHFFFAOYSA-N 2,3-diphenyl-1,3-dihydrotetrazol-3-ium-5-carbonitrile;thiocyanate Chemical compound [S-]C#N.N1C(C#N)=N[NH+](C=2C=CC=CC=2)N1C1=CC=CC=C1 NIKHKQWWXBDHGC-UHFFFAOYSA-N 0.000 description 3
- CDNHHFDCGUXITF-UHFFFAOYSA-N 2,3-diphenyl-5-[4-(2,4,4-trimethylpentan-2-yloxy)phenyl]-1h-tetrazol-1-ium;chloride Chemical compound [Cl-].C1=CC(OC(C)(C)CC(C)(C)C)=CC=C1C1=NN(C=2C=CC=CC=2)N(C=2C=CC=CC=2)[NH2+]1 CDNHHFDCGUXITF-UHFFFAOYSA-N 0.000 description 3
- AQPVLFWWOYVUOV-UHFFFAOYSA-N 2,3-diphenyl-5-thiophen-2-yl-1,3-dihydrotetrazol-3-ium;chloride Chemical compound [Cl-].[NH2+]1N(C=2C=CC=CC=2)N(C=2C=CC=CC=2)N=C1C1=CC=CS1 AQPVLFWWOYVUOV-UHFFFAOYSA-N 0.000 description 3
- IPZIKIFFPGSDIV-UHFFFAOYSA-N 2-(2,3-diphenyl-1,3-dihydrotetrazol-3-ium-5-yl)-1,3-benzoxazole;chloride Chemical compound [Cl-].N1=C(C=2OC3=CC=CC=C3N=2)NN(C=2C=CC=CC=2)[NH+]1C1=CC=CC=C1 IPZIKIFFPGSDIV-UHFFFAOYSA-N 0.000 description 3
- OPRFPVHIAQGVQF-UHFFFAOYSA-N 2-(2,3-diphenyl-1,3-dihydrotetrazol-3-ium-5-yl)quinoline;chloride Chemical compound [Cl-].N1=C(C=2N=C3C=CC=CC3=CC=2)NN(C=2C=CC=CC=2)[NH+]1C1=CC=CC=C1 OPRFPVHIAQGVQF-UHFFFAOYSA-N 0.000 description 3
- KYENMFWIKMBWJG-UHFFFAOYSA-N 2-(2,5-diphenyl-1h-tetrazol-1-ium-3-yl)-4,5-dimethyl-1,3-thiazole;chloride Chemical compound [Cl-].S1C(C)=C(C)N=C1N1N(C=2C=CC=CC=2)[NH2+]C(C=2C=CC=CC=2)=N1 KYENMFWIKMBWJG-UHFFFAOYSA-N 0.000 description 3
- FBCHOEIZLLKXOF-UHFFFAOYSA-N 2-(4-methylphenyl)-3,5-diphenyl-1,3-dihydrotetrazol-3-ium;methyl sulfate Chemical compound COS([O-])(=O)=O.C1=CC(C)=CC=C1N1[NH+](C=2C=CC=CC=2)N=C(C=2C=CC=CC=2)N1 FBCHOEIZLLKXOF-UHFFFAOYSA-N 0.000 description 3
- GMRATZJUJPHZKS-UHFFFAOYSA-N 2-[2-(4-methylphenyl)-5-phenyl-1,3-dihydrotetrazol-3-ium-3-yl]-1,3-benzothiazole;chloride Chemical compound [Cl-].C1=CC(C)=CC=C1N1[NH+](C=2SC3=CC=CC=C3N=2)N=C(C=2C=CC=CC=2)N1 GMRATZJUJPHZKS-UHFFFAOYSA-N 0.000 description 3
- KAOXCMHGMWDTBV-UHFFFAOYSA-N 2-[5-(2-chlorophenyl)-2-phenyl-1,3-dihydrotetrazol-3-ium-3-yl]-1,3-benzothiazole;bromide Chemical compound [Br-].ClC1=CC=CC=C1C1=N[NH+](C=2SC3=CC=CC=C3N=2)N(C=2C=CC=CC=2)N1 KAOXCMHGMWDTBV-UHFFFAOYSA-N 0.000 description 3
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- 239000006224 matting agent Substances 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- ZAKLKBFCSHJIRI-UHFFFAOYSA-N mucochloric acid Natural products OC1OC(=O)C(Cl)=C1Cl ZAKLKBFCSHJIRI-UHFFFAOYSA-N 0.000 description 1
- QQPSGKLPTFKHCN-UHFFFAOYSA-N n-(4-benzamido-2,5-dihydroxyphenyl)benzamide Chemical compound OC=1C=C(NC(=O)C=2C=CC=CC=2)C(O)=CC=1NC(=O)C1=CC=CC=C1 QQPSGKLPTFKHCN-UHFFFAOYSA-N 0.000 description 1
- QHEPZDDANRVQLQ-UHFFFAOYSA-N n-[4-(3,5-diphenyl-1,3-dihydrotetrazol-3-ium-2-yl)phenyl]acetamide;chloride Chemical compound [Cl-].C1=CC(NC(=O)C)=CC=C1N1[NH+](C=2C=CC=CC=2)N=C(C=2C=CC=CC=2)N1 QHEPZDDANRVQLQ-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000004957 naphthylene group Chemical group 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 125000006501 nitrophenyl group Chemical group 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- COWNFYYYZFRNOY-UHFFFAOYSA-N oxazolidinedione Chemical compound O=C1COC(=O)N1 COWNFYYYZFRNOY-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
- CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical compound N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
- 235000019252 potassium sulphite Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 239000000473 propyl gallate Substances 0.000 description 1
- 235000010388 propyl gallate Nutrition 0.000 description 1
- 229940075579 propyl gallate Drugs 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000005180 public health Effects 0.000 description 1
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical compound O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- KIWUVOGUEXMXSV-UHFFFAOYSA-N rhodanine Chemical compound O=C1CSC(=S)N1 KIWUVOGUEXMXSV-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- IYKVLICPFCEZOF-UHFFFAOYSA-N selenourea Chemical compound NC(N)=[Se] IYKVLICPFCEZOF-UHFFFAOYSA-N 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229940083542 sodium Drugs 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229940087562 sodium acetate trihydrate Drugs 0.000 description 1
- 229940001593 sodium carbonate Drugs 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- FZHLWVUAICIIPW-UHFFFAOYSA-M sodium gallate Chemical compound [Na+].OC1=CC(C([O-])=O)=CC(O)=C1O FZHLWVUAICIIPW-UHFFFAOYSA-M 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 229940001482 sodium sulfite Drugs 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000003003 spiro group Chemical group 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- CBDKQYKMCICBOF-UHFFFAOYSA-N thiazoline Chemical compound C1CN=CS1 CBDKQYKMCICBOF-UHFFFAOYSA-N 0.000 description 1
- 150000003568 thioethers Chemical group 0.000 description 1
- 125000005323 thioketone group Chemical group 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 229960001479 tosylchloramide sodium Drugs 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 230000004304 visual acuity Effects 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/067—Additives for high contrast images, other than hydrazine compounds
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP51091918A JPS6015936B2 (ja) | 1976-07-31 | 1976-07-31 | ハロゲン化銀写真感光材料 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1589593A true GB1589593A (en) | 1981-05-13 |
Family
ID=14039951
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3145077A Expired GB1589593A (en) | 1976-07-31 | 1977-07-27 | Light-sensitive silver halide photographic material and method of processing thereof |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS6015936B2 (enExample) |
| AU (1) | AU500387B2 (enExample) |
| CA (1) | CA1110484A (enExample) |
| DE (1) | DE2734336C2 (enExample) |
| FR (1) | FR2360910A1 (enExample) |
| GB (1) | GB1589593A (enExample) |
| SE (1) | SE7708669L (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5917819B2 (ja) * | 1977-01-27 | 1984-04-24 | コニカ株式会社 | ハロゲン化銀写真感光材料 |
| JPS5950975B2 (ja) * | 1977-02-01 | 1984-12-11 | コニカ株式会社 | 高コントラスト銀画像の形成方法 |
| JPS5919886B2 (ja) * | 1978-02-02 | 1984-05-09 | セントラル硝子株式会社 | フロ−ト法における板ガラス製造方法 |
| JPS58189629A (ja) * | 1982-04-07 | 1983-11-05 | Konishiroku Photo Ind Co Ltd | 銀画像形成方法 |
| JPS5979244A (ja) * | 1982-10-29 | 1984-05-08 | Konishiroku Photo Ind Co Ltd | 銀画像形成方法 |
| JPS60126645A (ja) * | 1983-12-13 | 1985-07-06 | Konishiroku Photo Ind Co Ltd | 明室用直接ポジハロゲン化銀写真感光材料による画像形成方法 |
| EP0181728A3 (en) * | 1984-11-13 | 1988-08-24 | Konishiroku Photo Industry Co. Ltd. | Light-sensitive silver halide photographic material |
| DE3684430D1 (de) | 1985-12-25 | 1992-04-23 | Fuji Photo Film Co Ltd | Verfahren zur herstellung eines bildes. |
| DE3709724C2 (de) * | 1986-03-25 | 1994-12-01 | Fuji Photo Film Co Ltd | Verfahren und Vorrichtung zum Reproduzieren einer Bild- und Schrifteile umfassende Darstellung |
| JPH051571A (ja) * | 1991-06-21 | 1993-01-08 | Kubota Corp | デイーゼルエンジンのガバナ装置 |
| EP4006330A4 (en) | 2019-07-30 | 2022-11-23 | Mitsubishi Jidosha Kogyo Kabushiki Kaisha | Fuel tank system |
| US11698044B2 (en) | 2019-07-30 | 2023-07-11 | Mitsubishi Jidosha Kogyo Kabushtkt Kaisha | Fuel tank system |
| WO2021020488A1 (ja) | 2019-07-30 | 2021-02-04 | 三菱自動車工業株式会社 | 燃料タンクシステム |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE615097A (enExample) * | 1961-03-14 | |||
| IT984942B (it) * | 1973-05-07 | 1974-11-20 | Minnesota Mining & Mfg | C ossi betaine di tetrazolio come agenti antivelo per emulsioni foto grafiche agli alogenuri d argento |
| JPS5917825B2 (ja) * | 1975-08-02 | 1984-04-24 | コニカ株式会社 | 高コントラスト銀画像の形成方法 |
-
1976
- 1976-07-31 JP JP51091918A patent/JPS6015936B2/ja not_active Expired
-
1977
- 1977-07-26 AU AU27318/77A patent/AU500387B2/en not_active Expired
- 1977-07-27 GB GB3145077A patent/GB1589593A/en not_active Expired
- 1977-07-28 SE SE7708669A patent/SE7708669L/ not_active Application Discontinuation
- 1977-07-29 DE DE19772734336 patent/DE2734336C2/de not_active Expired
- 1977-07-29 CA CA283,721A patent/CA1110484A/en not_active Expired
- 1977-08-01 FR FR7723667A patent/FR2360910A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| AU500387B2 (en) | 1979-05-17 |
| DE2734336C2 (de) | 1985-12-05 |
| JPS5317719A (en) | 1978-02-18 |
| DE2734336A1 (de) | 1978-02-02 |
| SE7708669L (sv) | 1978-02-01 |
| AU2731877A (en) | 1979-02-01 |
| JPS6015936B2 (ja) | 1985-04-23 |
| FR2360910B1 (enExample) | 1980-04-18 |
| FR2360910A1 (fr) | 1978-03-03 |
| CA1110484A (en) | 1981-10-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |