CA1110484A - Light-sensitive silver halide photographic material containing a tetrazolium compound - Google Patents
Light-sensitive silver halide photographic material containing a tetrazolium compoundInfo
- Publication number
- CA1110484A CA1110484A CA283,721A CA283721A CA1110484A CA 1110484 A CA1110484 A CA 1110484A CA 283721 A CA283721 A CA 283721A CA 1110484 A CA1110484 A CA 1110484A
- Authority
- CA
- Canada
- Prior art keywords
- group
- tetrazolium
- diphenyl
- silver halide
- light
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 silver halide Chemical class 0.000 title claims abstract description 134
- 229910052709 silver Inorganic materials 0.000 title claims abstract description 118
- 239000004332 silver Substances 0.000 title claims abstract description 118
- 239000000463 material Substances 0.000 title claims abstract description 63
- 238000000034 method Methods 0.000 claims abstract description 34
- 238000012545 processing Methods 0.000 claims abstract description 16
- 239000010410 layer Substances 0.000 claims description 33
- 239000008273 gelatin Substances 0.000 claims description 32
- 108010010803 Gelatin Proteins 0.000 claims description 31
- 150000001875 compounds Chemical class 0.000 claims description 31
- 229920000159 gelatin Polymers 0.000 claims description 31
- 235000019322 gelatine Nutrition 0.000 claims description 31
- 235000011852 gelatine desserts Nutrition 0.000 claims description 31
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 26
- 125000003118 aryl group Chemical group 0.000 claims description 15
- 150000003839 salts Chemical class 0.000 claims description 14
- 125000000623 heterocyclic group Chemical group 0.000 claims description 13
- 239000011241 protective layer Substances 0.000 claims description 13
- 150000001450 anions Chemical group 0.000 claims description 11
- ZVNPWFOVUDMGRP-UHFFFAOYSA-N 4-methylaminophenol sulfate Chemical compound OS(O)(=O)=O.CNC1=CC=C(O)C=C1.CNC1=CC=C(O)C=C1 ZVNPWFOVUDMGRP-UHFFFAOYSA-N 0.000 claims description 7
- 125000000732 arylene group Chemical group 0.000 claims description 6
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 125000005874 benzothiadiazolyl group Chemical group 0.000 claims description 5
- 239000004305 biphenyl Substances 0.000 claims description 5
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 5
- CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical compound N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 claims description 5
- 125000001113 thiadiazolyl group Chemical group 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 229910021607 Silver chloride Inorganic materials 0.000 claims description 4
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 125000003277 amino group Chemical group 0.000 claims description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 125000002971 oxazolyl group Chemical group 0.000 claims description 4
- 125000004076 pyridyl group Chemical group 0.000 claims description 4
- 125000000714 pyrimidinyl group Chemical group 0.000 claims description 4
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 claims description 4
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 claims description 4
- WFTGTFCWWWPJAF-UHFFFAOYSA-N 1-(2,3-diphenyl-1H-tetrazol-5-yl)ethanone Chemical compound N1C(C(=O)C)=NN(C=2C=CC=CC=2)N1C1=CC=CC=C1 WFTGTFCWWWPJAF-UHFFFAOYSA-N 0.000 claims description 3
- QOIRFXTZHVPXLR-UHFFFAOYSA-N 2,3,5-triphenyl-1h-tetrazole Chemical compound N1N(C=2C=CC=CC=2)N(C=2C=CC=CC=2)N=C1C1=CC=CC=C1 QOIRFXTZHVPXLR-UHFFFAOYSA-N 0.000 claims description 3
- OMPBPIPZACGTHR-UHFFFAOYSA-N 2,3-diphenyl-1H-tetrazole Chemical compound N1C=NN(C=2C=CC=CC=2)N1C1=CC=CC=C1 OMPBPIPZACGTHR-UHFFFAOYSA-N 0.000 claims description 3
- KNMZXRUWMYCXSG-UHFFFAOYSA-N 2-[3-(4-methylphenyl)-5-phenyl-1H-tetrazol-2-yl]-1,3-benzothiazole Chemical compound C1=CC(C)=CC=C1N1N(C=2SC3=CC=CC=C3N=2)NC(C=2C=CC=CC=2)=N1 KNMZXRUWMYCXSG-UHFFFAOYSA-N 0.000 claims description 3
- KPXPTOUFIZYILY-UHFFFAOYSA-N 4-(2,3-diphenyl-1H-tetrazol-5-yl)pyridine Chemical compound N1N(C=2C=CC=CC=2)N(C=2C=CC=CC=2)N=C1C1=CC=NC=C1 KPXPTOUFIZYILY-UHFFFAOYSA-N 0.000 claims description 3
- HLQLADJVXUGAKG-UHFFFAOYSA-N 5-ethyl-2,3-diphenyl-1h-tetrazole Chemical compound N1C(CC)=NN(C=2C=CC=CC=2)N1C1=CC=CC=C1 HLQLADJVXUGAKG-UHFFFAOYSA-N 0.000 claims description 3
- NIPMJVLJVGQZRB-UHFFFAOYSA-N Cl[IH]Br Chemical compound Cl[IH]Br NIPMJVLJVGQZRB-UHFFFAOYSA-N 0.000 claims description 3
- 230000001681 protective effect Effects 0.000 claims description 2
- XXWAHKICOZTQOW-UHFFFAOYSA-N 1-[2,3-bis(4-ethoxyphenyl)-1H-tetrazol-5-yl]ethanone Chemical compound C1=CC(OCC)=CC=C1N1N(C=2C=CC(OCC)=CC=2)N=C(C(C)=O)N1 XXWAHKICOZTQOW-UHFFFAOYSA-N 0.000 claims 2
- FJMPZWOQMLJCRS-UHFFFAOYSA-N 2,3-diphenyl-1h-tetrazole-5-carbonitrile Chemical compound N1C(C#N)=NN(C=2C=CC=CC=2)N1C1=CC=CC=C1 FJMPZWOQMLJCRS-UHFFFAOYSA-N 0.000 claims 2
- UBJIPDGISJLPQU-UHFFFAOYSA-N 2,3-diphenyl-5-thiophen-2-yl-1H-tetrazole Chemical compound N1N(C=2C=CC=CC=2)N(C=2C=CC=CC=2)N=C1C1=CC=CS1 UBJIPDGISJLPQU-UHFFFAOYSA-N 0.000 claims 2
- QACDNZQVHQGFAB-UHFFFAOYSA-N 2-(2,3-diphenyl-1H-tetrazol-5-yl)-1,3-benzoxazole Chemical compound N1=C(C=2OC3=CC=CC=C3N=2)NN(C=2C=CC=CC=2)N1C1=CC=CC=C1 QACDNZQVHQGFAB-UHFFFAOYSA-N 0.000 claims 2
- ASJSXUWOFZATJM-UHFFFAOYSA-N 2-(3,5-diphenyl-1h-tetrazol-2-yl)-4,5-dimethyl-1,3-thiazole Chemical compound S1C(C)=C(C)N=C1N1N(C=2C=CC=CC=2)NC(C=2C=CC=CC=2)=N1 ASJSXUWOFZATJM-UHFFFAOYSA-N 0.000 claims 2
- RKOYIQDBENDSSV-UHFFFAOYSA-N 2-(4-iodophenyl)-3,5-diphenyl-1H-tetrazole Chemical compound C1=CC(I)=CC=C1N1N(C=2C=CC=CC=2)N=C(C=2C=CC=CC=2)N1 RKOYIQDBENDSSV-UHFFFAOYSA-N 0.000 claims 2
- IXNKNVCYDIVHSA-UHFFFAOYSA-N 2-(4-methylphenyl)-3,5-diphenyl-1h-tetrazole Chemical compound C1=CC(C)=CC=C1N1N(C=2C=CC=CC=2)N=C(C=2C=CC=CC=2)N1 IXNKNVCYDIVHSA-UHFFFAOYSA-N 0.000 claims 2
- ZNVBVIZZKGKHRB-UHFFFAOYSA-N 2-(5-dodecyl-3-phenyl-1H-tetrazol-2-yl)-1,3-benzothiazole Chemical compound N=1C2=CC=CC=C2SC=1N1NC(CCCCCCCCCCCC)=NN1C1=CC=CC=C1 ZNVBVIZZKGKHRB-UHFFFAOYSA-N 0.000 claims 2
- HWLXUQATWPNSAO-UHFFFAOYSA-N 2-[3-(4-methoxyphenyl)-5-phenyl-1H-tetrazol-2-yl]-1,3-benzothiazole Chemical compound C1=CC(OC)=CC=C1N1N(C=2SC3=CC=CC=C3N=2)NC(C=2C=CC=CC=2)=N1 HWLXUQATWPNSAO-UHFFFAOYSA-N 0.000 claims 2
- RAECFAXTJBDZOD-UHFFFAOYSA-N 2-[5-(2-chlorophenyl)-3-phenyl-1H-tetrazol-2-yl]-1,3-benzothiazole Chemical compound ClC1=CC=CC=C1C1=NN(C=2C=CC=CC=2)N(C=2SC3=CC=CC=C3N=2)N1 RAECFAXTJBDZOD-UHFFFAOYSA-N 0.000 claims 2
- FQYLAHZWZVBJMI-UHFFFAOYSA-N 2-[5-(4-chlorophenyl)-3-(4-nitrophenyl)-1H-tetrazol-2-yl]-1,3-benzothiazole Chemical compound C1=CC([N+](=O)[O-])=CC=C1N1N(C=2SC3=CC=CC=C3N=2)NC(C=2C=CC(Cl)=CC=2)=N1 FQYLAHZWZVBJMI-UHFFFAOYSA-N 0.000 claims 2
- BKFGFBHIORTGEL-UHFFFAOYSA-N 3-[4-[2,3-bis[4-(2-carboxyethyl)phenyl]-1H-tetrazol-5-yl]phenyl]propanoic acid Chemical compound C1=CC(CCC(=O)O)=CC=C1N1N(C=2C=CC(CCC(O)=O)=CC=2)N=C(C=2C=CC(CCC(O)=O)=CC=2)N1 BKFGFBHIORTGEL-UHFFFAOYSA-N 0.000 claims 2
- HTOVSDZGMHMQII-UHFFFAOYSA-N 4-(2,3-diphenyl-1H-tetrazol-5-yl)benzonitrile Chemical compound C1=CC(C#N)=CC=C1C1=NN(C=2C=CC=CC=2)N(C=2C=CC=CC=2)N1 HTOVSDZGMHMQII-UHFFFAOYSA-N 0.000 claims 2
- XKAKMCNHHNUUGN-UHFFFAOYSA-N 4-(5-methyl-3-phenyl-1H-tetrazol-2-yl)phenol Chemical compound N1C(C)=NN(C=2C=CC=CC=2)N1C1=CC=C(O)C=C1 XKAKMCNHHNUUGN-UHFFFAOYSA-N 0.000 claims 2
- DVYWKCIYDKCQGG-UHFFFAOYSA-N 5-(3,4-dimethoxyphenyl)-2-(2-ethoxyphenyl)-3-(4-methoxyphenyl)-1h-tetrazole Chemical compound CCOC1=CC=CC=C1N1N(C=2C=CC(OC)=CC=2)N=C(C=2C=C(OC)C(OC)=CC=2)N1 DVYWKCIYDKCQGG-UHFFFAOYSA-N 0.000 claims 2
- LPNMSTZIECKPKI-UHFFFAOYSA-N 5-(4-bromophenyl)-3-phenyl-2-(2,4,6-trichlorophenyl)-1H-tetrazole Chemical compound ClC1=CC(Cl)=CC(Cl)=C1N1N(C=2C=CC=CC=2)N=C(C=2C=CC(Br)=CC=2)N1 LPNMSTZIECKPKI-UHFFFAOYSA-N 0.000 claims 2
- KWEKLFATGLFLST-UHFFFAOYSA-N 5-(furan-2-yl)-2,3-diphenyl-1H-tetrazole Chemical compound N1N(C=2C=CC=CC=2)N(C=2C=CC=CC=2)N=C1C1=CC=CO1 KWEKLFATGLFLST-UHFFFAOYSA-N 0.000 claims 2
- XHIPMTBCWNNSFM-UHFFFAOYSA-N 5-hexyl-2,3-diphenyl-1H-tetrazole Chemical compound N1C(CCCCCC)=NN(C=2C=CC=CC=2)N1C1=CC=CC=C1 XHIPMTBCWNNSFM-UHFFFAOYSA-N 0.000 claims 2
- TXCKVRLFZFJSDF-UHFFFAOYSA-N 5-methyl-2,3-diphenyl-1h-tetrazole Chemical compound N1C(C)=NN(C=2C=CC=CC=2)N1C1=CC=CC=C1 TXCKVRLFZFJSDF-UHFFFAOYSA-N 0.000 claims 2
- SCRSUBWYUBGSPK-UHFFFAOYSA-N 5-nitro-2,3-diphenyl-1H-tetrazole Chemical compound N1C([N+](=O)[O-])=NN(C=2C=CC=CC=2)N1C1=CC=CC=C1 SCRSUBWYUBGSPK-UHFFFAOYSA-N 0.000 claims 2
- HGMHKDIQDVYKON-UHFFFAOYSA-N N-[4-(3,5-diphenyl-1H-tetrazol-2-yl)phenyl]acetamide Chemical compound C1=CC(NC(=O)C)=CC=C1N1N(C=2C=CC=CC=2)N=C(C=2C=CC=CC=2)N1 HGMHKDIQDVYKON-UHFFFAOYSA-N 0.000 claims 2
- QRIJAXWENLJOBO-UHFFFAOYSA-N N1N(C=2C=CC=CC=2)N(C=2C=CC=CC=2)N=C1C(C(=C1C=2C=CC=CC=2)C=2C=CC=CC=2)=CC=C1C=1N=NNN=1 Chemical compound N1N(C=2C=CC=CC=2)N(C=2C=CC=CC=2)N=C1C(C(=C1C=2C=CC=CC=2)C=2C=CC=CC=2)=CC=C1C=1N=NNN=1 QRIJAXWENLJOBO-UHFFFAOYSA-N 0.000 claims 2
- HLRFVQODVVUZEA-UHFFFAOYSA-N N1N(C=2C=CC=CC=2)N(N2N=CC=CN2)N=C1C1=CC=CC=C1 Chemical compound N1N(C=2C=CC=CC=2)N(N2N=CC=CN2)N=C1C1=CC=CC=C1 HLRFVQODVVUZEA-UHFFFAOYSA-N 0.000 claims 2
- BNIUVQHHCJXGHT-UHFFFAOYSA-N N=1N(C=2C=CC=CC=2)N(C=2C=CC=CC=2)NC=1CC(C=1C=CC=CC=1)C(C=1C=CC=CC=1)CC=1N=NNN=1 Chemical compound N=1N(C=2C=CC=CC=2)N(C=2C=CC=CC=2)NC=1CC(C=1C=CC=CC=1)C(C=1C=CC=CC=1)CC=1N=NNN=1 BNIUVQHHCJXGHT-UHFFFAOYSA-N 0.000 claims 2
- GXNZYSHGDTVEFI-UHFFFAOYSA-N ethyl 2,3-bis(3-nitrophenyl)-1H-tetrazole-5-carboxylate Chemical compound N1C(C(=O)OCC)=NN(C=2C=C(C=CC=2)[N+]([O-])=O)N1C1=CC=CC([N+]([O-])=O)=C1 GXNZYSHGDTVEFI-UHFFFAOYSA-N 0.000 claims 2
- 150000001768 cations Chemical group 0.000 claims 1
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 abstract description 4
- 229940009188 silver Drugs 0.000 description 96
- 239000000243 solution Substances 0.000 description 58
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 43
- 239000000839 emulsion Substances 0.000 description 35
- 229940014259 gelatin Drugs 0.000 description 27
- 230000008569 process Effects 0.000 description 20
- 239000003795 chemical substances by application Substances 0.000 description 17
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 15
- 238000011161 development Methods 0.000 description 12
- 239000011248 coating agent Substances 0.000 description 11
- 238000000576 coating method Methods 0.000 description 11
- 229960004337 hydroquinone Drugs 0.000 description 11
- 230000018109 developmental process Effects 0.000 description 10
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- 150000002500 ions Chemical class 0.000 description 9
- 125000003831 tetrazolyl group Chemical group 0.000 description 9
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 229940105984 diethylhexyl succinate Drugs 0.000 description 7
- WMNULTDOANGXRT-UHFFFAOYSA-N bis(2-ethylhexyl) butanedioate Chemical compound CCCCC(CC)COC(=O)CCC(=O)OCC(CC)CCCC WMNULTDOANGXRT-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- 208000015181 infectious disease Diseases 0.000 description 5
- 230000002458 infectious effect Effects 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000000084 colloidal system Substances 0.000 description 4
- MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 150000004820 halides Chemical class 0.000 description 4
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 229940069002 potassium dichromate Drugs 0.000 description 4
- 238000003672 processing method Methods 0.000 description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 4
- 229910052721 tungsten Inorganic materials 0.000 description 4
- 239000010937 tungsten Substances 0.000 description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 3
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 3
- 239000012964 benzotriazole Substances 0.000 description 3
- 229910052793 cadmium Inorganic materials 0.000 description 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 3
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 150000003283 rhodium Chemical class 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- JZLLHLCEVVEDGF-UHFFFAOYSA-N 1-(2,3-diphenyl-1,3-dihydrotetrazol-3-ium-5-yl)ethanone;chloride Chemical compound [Cl-].[NH2+]1C(C(=O)C)=NN(C=2C=CC=CC=2)N1C1=CC=CC=C1 JZLLHLCEVVEDGF-UHFFFAOYSA-N 0.000 description 2
- GMRATZJUJPHZKS-UHFFFAOYSA-N 2-[2-(4-methylphenyl)-5-phenyl-1,3-dihydrotetrazol-3-ium-3-yl]-1,3-benzothiazole;chloride Chemical compound [Cl-].C1=CC(C)=CC=C1N1[NH+](C=2SC3=CC=CC=C3N=2)N=C(C=2C=CC=CC=2)N1 GMRATZJUJPHZKS-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
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- AFOSIXZFDONLBT-UHFFFAOYSA-N divinyl sulfone Chemical compound C=CS(=O)(=O)C=C AFOSIXZFDONLBT-UHFFFAOYSA-N 0.000 description 1
- 235000010386 dodecyl gallate Nutrition 0.000 description 1
- 239000000555 dodecyl gallate Substances 0.000 description 1
- 229940080643 dodecyl gallate Drugs 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 229960001484 edetic acid Drugs 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 125000006303 iodophenyl group Chemical group 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate Chemical compound [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000468 ketone group Chemical group 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- MYWUZJCMWCOHBA-VIFPVBQESA-N methamphetamine Chemical compound CN[C@@H](C)CC1=CC=CC=C1 MYWUZJCMWCOHBA-VIFPVBQESA-N 0.000 description 1
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000004957 naphthylene group Chemical group 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- HYWYRSMBCFDLJT-UHFFFAOYSA-N nimesulide Chemical compound CS(=O)(=O)NC1=CC=C([N+]([O-])=O)C=C1OC1=CC=CC=C1 HYWYRSMBCFDLJT-UHFFFAOYSA-N 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- IXQGCWUGDFDQMF-UHFFFAOYSA-N o-Hydroxyethylbenzene Natural products CCC1=CC=CC=C1O IXQGCWUGDFDQMF-UHFFFAOYSA-N 0.000 description 1
- COWNFYYYZFRNOY-UHFFFAOYSA-N oxazolidinedione Chemical compound O=C1COC(=O)N1 COWNFYYYZFRNOY-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- NFBAXHOPROOJAW-UHFFFAOYSA-N phenindione Chemical class O=C1C2=CC=CC=C2C(=O)C1C1=CC=CC=C1 NFBAXHOPROOJAW-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
- 235000019252 potassium sulphite Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000005180 public health Effects 0.000 description 1
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical compound O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- KIWUVOGUEXMXSV-UHFFFAOYSA-N rhodanine Chemical compound O=C1CSC(=S)N1 KIWUVOGUEXMXSV-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- IYKVLICPFCEZOF-UHFFFAOYSA-N selenourea Chemical compound NC(N)=[Se] IYKVLICPFCEZOF-UHFFFAOYSA-N 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229940087562 sodium acetate trihydrate Drugs 0.000 description 1
- 229940001593 sodium carbonate Drugs 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- FZHLWVUAICIIPW-UHFFFAOYSA-M sodium gallate Chemical compound [Na+].OC1=CC(C([O-])=O)=CC(O)=C1O FZHLWVUAICIIPW-UHFFFAOYSA-M 0.000 description 1
- 229940001482 sodium sulfite Drugs 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- UCSJYZPVAKXKNQ-HZYVHMACSA-N streptomycin Chemical compound CN[C@H]1[C@H](O)[C@@H](O)[C@H](CO)O[C@H]1O[C@@H]1[C@](C=O)(O)[C@H](C)O[C@H]1O[C@@H]1[C@@H](NC(N)=N)[C@H](O)[C@@H](NC(N)=N)[C@H](O)[C@H]1O UCSJYZPVAKXKNQ-HZYVHMACSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 150000003453 sulfinic acid esters Chemical class 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- CBDKQYKMCICBOF-UHFFFAOYSA-N thiazoline Chemical compound C1CN=CS1 CBDKQYKMCICBOF-UHFFFAOYSA-N 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 125000005323 thioketone group Chemical group 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000004304 visual acuity Effects 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/067—Additives for high contrast images, other than hydrazine compounds
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP91918/76 | 1976-07-31 | ||
| JP51091918A JPS6015936B2 (ja) | 1976-07-31 | 1976-07-31 | ハロゲン化銀写真感光材料 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1110484A true CA1110484A (en) | 1981-10-13 |
Family
ID=14039951
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA283,721A Expired CA1110484A (en) | 1976-07-31 | 1977-07-29 | Light-sensitive silver halide photographic material containing a tetrazolium compound |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS6015936B2 (enExample) |
| AU (1) | AU500387B2 (enExample) |
| CA (1) | CA1110484A (enExample) |
| DE (1) | DE2734336C2 (enExample) |
| FR (1) | FR2360910A1 (enExample) |
| GB (1) | GB1589593A (enExample) |
| SE (1) | SE7708669L (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5917819B2 (ja) * | 1977-01-27 | 1984-04-24 | コニカ株式会社 | ハロゲン化銀写真感光材料 |
| JPS5950975B2 (ja) * | 1977-02-01 | 1984-12-11 | コニカ株式会社 | 高コントラスト銀画像の形成方法 |
| JPS5919886B2 (ja) * | 1978-02-02 | 1984-05-09 | セントラル硝子株式会社 | フロ−ト法における板ガラス製造方法 |
| JPS58189629A (ja) * | 1982-04-07 | 1983-11-05 | Konishiroku Photo Ind Co Ltd | 銀画像形成方法 |
| JPS5979244A (ja) * | 1982-10-29 | 1984-05-08 | Konishiroku Photo Ind Co Ltd | 銀画像形成方法 |
| JPS60126645A (ja) * | 1983-12-13 | 1985-07-06 | Konishiroku Photo Ind Co Ltd | 明室用直接ポジハロゲン化銀写真感光材料による画像形成方法 |
| EP0181728A3 (en) * | 1984-11-13 | 1988-08-24 | Konishiroku Photo Industry Co. Ltd. | Light-sensitive silver halide photographic material |
| DE3684430D1 (de) | 1985-12-25 | 1992-04-23 | Fuji Photo Film Co Ltd | Verfahren zur herstellung eines bildes. |
| DE3709724C2 (de) * | 1986-03-25 | 1994-12-01 | Fuji Photo Film Co Ltd | Verfahren und Vorrichtung zum Reproduzieren einer Bild- und Schrifteile umfassende Darstellung |
| JPH051571A (ja) * | 1991-06-21 | 1993-01-08 | Kubota Corp | デイーゼルエンジンのガバナ装置 |
| EP4006330A4 (en) | 2019-07-30 | 2022-11-23 | Mitsubishi Jidosha Kogyo Kabushiki Kaisha | Fuel tank system |
| US11698044B2 (en) | 2019-07-30 | 2023-07-11 | Mitsubishi Jidosha Kogyo Kabushtkt Kaisha | Fuel tank system |
| WO2021020488A1 (ja) | 2019-07-30 | 2021-02-04 | 三菱自動車工業株式会社 | 燃料タンクシステム |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE615097A (enExample) * | 1961-03-14 | |||
| IT984942B (it) * | 1973-05-07 | 1974-11-20 | Minnesota Mining & Mfg | C ossi betaine di tetrazolio come agenti antivelo per emulsioni foto grafiche agli alogenuri d argento |
| JPS5917825B2 (ja) * | 1975-08-02 | 1984-04-24 | コニカ株式会社 | 高コントラスト銀画像の形成方法 |
-
1976
- 1976-07-31 JP JP51091918A patent/JPS6015936B2/ja not_active Expired
-
1977
- 1977-07-26 AU AU27318/77A patent/AU500387B2/en not_active Expired
- 1977-07-27 GB GB3145077A patent/GB1589593A/en not_active Expired
- 1977-07-28 SE SE7708669A patent/SE7708669L/ not_active Application Discontinuation
- 1977-07-29 DE DE19772734336 patent/DE2734336C2/de not_active Expired
- 1977-07-29 CA CA283,721A patent/CA1110484A/en not_active Expired
- 1977-08-01 FR FR7723667A patent/FR2360910A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| AU500387B2 (en) | 1979-05-17 |
| GB1589593A (en) | 1981-05-13 |
| DE2734336C2 (de) | 1985-12-05 |
| JPS5317719A (en) | 1978-02-18 |
| DE2734336A1 (de) | 1978-02-02 |
| SE7708669L (sv) | 1978-02-01 |
| AU2731877A (en) | 1979-02-01 |
| JPS6015936B2 (ja) | 1985-04-23 |
| FR2360910B1 (enExample) | 1980-04-18 |
| FR2360910A1 (fr) | 1978-03-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |