GB1388279A - Method for cross-linking rubber - Google Patents

Method for cross-linking rubber

Info

Publication number
GB1388279A
GB1388279A GB5322472A GB5322472A GB1388279A GB 1388279 A GB1388279 A GB 1388279A GB 5322472 A GB5322472 A GB 5322472A GB 5322472 A GB5322472 A GB 5322472A GB 1388279 A GB1388279 A GB 1388279A
Authority
GB
United Kingdom
Prior art keywords
bis
ethane
benzothiazolyldithio
rubber
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5322472A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of GB1388279A publication Critical patent/GB1388279A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/52—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems
    • C07D263/54—Benzoxazoles; Hydrogenated benzoxazoles
    • C07D263/58—Benzoxazoles; Hydrogenated benzoxazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D235/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
    • C07D235/02—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
    • C07D235/04—Benzimidazoles; Hydrogenated benzimidazoles
    • C07D235/24—Benzimidazoles; Hydrogenated benzimidazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
    • C07D235/28—Sulfur atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/32—One oxygen, sulfur or nitrogen atom
    • C07D239/38—One sulfur atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D265/00—Heterocyclic compounds containing six-membered rings having one nitrogen atom and one oxygen atom as the only ring hetero atoms
    • C07D265/28—1,4-Oxazines; Hydrogenated 1,4-oxazines
    • C07D265/30—1,4-Oxazines; Hydrogenated 1,4-oxazines not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/60—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings condensed with carbocyclic rings or ring systems
    • C07D277/62—Benzothiazoles
    • C07D277/68—Benzothiazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
    • C07D277/70—Sulfur atoms
    • C07D277/76—Sulfur atoms attached to a second hetero atom
    • C07D277/78—Sulfur atoms attached to a second hetero atom to a second sulphur atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D285/00—Heterocyclic compounds containing rings having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by groups C07D275/00 - C07D283/00
    • C07D285/01—Five-membered rings
    • C07D285/02—Thiadiazoles; Hydrogenated thiadiazoles
    • C07D285/04—Thiadiazoles; Hydrogenated thiadiazoles not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/16—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
    • C07D295/20—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carbonic acid, or sulfur or nitrogen analogues thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
    • C07F9/165—Esters of thiophosphoric acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/39—Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
GB5322472A 1971-11-19 1972-11-17 Method for cross-linking rubber Expired GB1388279A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US200595A US3869435A (en) 1971-11-19 1971-11-19 Method for cross-linking rubber

Publications (1)

Publication Number Publication Date
GB1388279A true GB1388279A (en) 1975-03-26

Family

ID=22742372

Family Applications (2)

Application Number Title Priority Date Filing Date
GB3203073A Expired GB1388280A (en) 1971-11-19 1972-11-17 Di- and poly-sulphides
GB5322472A Expired GB1388279A (en) 1971-11-19 1972-11-17 Method for cross-linking rubber

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB3203073A Expired GB1388280A (en) 1971-11-19 1972-11-17 Di- and poly-sulphides

Country Status (7)

Country Link
US (1) US3869435A (enExample)
JP (1) JPS554136B2 (enExample)
CA (1) CA987840A (enExample)
DE (2) DE2265382C2 (enExample)
FR (1) FR2186970A5 (enExample)
GB (2) GB1388280A (enExample)
IT (1) IT971005B (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4417012A (en) 1981-07-08 1983-11-22 Monsanto Europe S.A. Organic thiosulphates and thiosulphonates useful as stabilising agents for rubber vulcanisates

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4006155A (en) * 1972-06-26 1977-02-01 Monsanto Company Method for preparation of phosphorus polysulfides
JPS5150339A (en) * 1974-10-30 1976-05-01 Yokohama Rubber Co Ltd Gomusoseibutsu
JPS5149238A (en) * 1974-10-25 1976-04-28 Yokohama Rubber Co Ltd Gomusoseibutsu
US4174322A (en) * 1976-09-24 1979-11-13 Exxon Research & Engineering Co. Thiobis(oxazolines)
US4374142A (en) * 1977-02-08 1983-02-15 Thiokol Corporation Bisdithiocarbamate esters of di-lower alkyl formals
SE446184B (sv) * 1979-01-12 1986-08-18 Toyo Jozo Kk Polyfunktionell disulfidforening anvendbar som tverbindande medel
US4482663A (en) * 1982-07-12 1984-11-13 Phillips Petroleum Company Rubber compositions comprising a siliceous filler in combination with an organosulfur substituted pyridine promotor
US4496683A (en) * 1982-08-11 1985-01-29 Monsanto Company Rubber compositions containing a vulcanization system alterative
US4532080A (en) * 1982-10-21 1985-07-30 Monsanto Europe, S.A. Adhesion promoters
US4654271A (en) * 1984-04-10 1987-03-31 Monsanto Europe, S. A. Metal complexes useful as rubber/metal bonding promoters
ES2072924T3 (es) * 1989-02-28 1995-08-01 Huels Chemische Werke Ag Costados de neumaticos de elevada estabilidad, y un procedimiento para su fabricacion.
DE59009262D1 (de) * 1989-02-28 1995-07-27 Huels Chemische Werke Ag Reifenlaufflächen mit erhöhter Laufleistung und Verfahren zu ihrer Herstellung.
DE3941002A1 (de) * 1989-12-12 1991-06-13 Huels Chemische Werke Ag Polysulfidderivate, verfahren zu ihrer herstellung und verwendung zur vernetzung von natur- und synthesekautschuken
ES2066932T3 (es) * 1989-12-13 1995-03-16 Huels Chemische Werke Ag Superficies de rodadura de neumaticos con prestaciones de rodadura mejoradas y procedimiento para su fabricacion.
DE59008849D1 (de) * 1989-12-13 1995-05-11 Huels Chemische Werke Ag Reifenseitenwände mit erhöhter Stabilität und Verfahren zu ihrer Herstellung.
DE59205083D1 (de) * 1991-08-30 1996-02-29 Huels Chemische Werke Ag Verfahren zur Herstellung von Dienkautschuk-Vulkanisaten
US6075096A (en) 1998-02-27 2000-06-13 The Goodyear Tire & Rubber Company Rubber compounds containing aromatic ketone polysulfides
EP1000968A1 (de) 1998-11-16 2000-05-17 Bayer Aktiengesellschaft Styrol-Butadien- und Butadienkautschuke enthaltende vulkanisierbare Kautschukmischungen
JP2003532779A (ja) * 2000-05-12 2003-11-05 ロックタイト （アール アンド ディー） リミテッド シアノアクリレート接着剤用の活性剤組成物
DE102004018193A1 (de) * 2004-04-15 2005-11-03 Bayer Ag Herstellung von Thioschwefelsäurederivaten
EP1600439B1 (de) * 2004-05-26 2016-02-03 LANXESS Deutschland GmbH Herstellung von derivatisierten Dithiolen
JP5065650B2 (ja) * 2006-10-30 2012-11-07 東洋ゴム工業株式会社 タイヤベーストレッド用ゴム組成物
JP5587608B2 (ja) * 2006-12-19 2014-09-10 スティロン ヨーロッパ ゲゼルシャフト ミット ベシュレンクテル ハフツング スルフィド変性弾性ポリマー
US8124206B2 (en) * 2008-10-30 2012-02-28 Momentive Performance Materials, Inc. Sulfur-containing cycloaliphatic compound, filled sulfur-vulcanizable elastomer composition containing sulfur-containing cycloaliphatic compound and articles fabricated therefrom
US8334340B2 (en) * 2008-10-30 2012-12-18 Momentive Performance Materials, Inc. Sulfur-containing cycloaliphatic compound, process for its preparation, filled sulfur-vulcanizable elastomer composition containing same and articles fabricated therefrom
US7674861B1 (en) 2008-10-30 2010-03-09 Momentive Performance Materials Inc. Thiocarbamoyldisufanyl-functional cycloaliphatic compound, process for its preparation, filled sulfur-vulcanizable elastomer composition containing same and articles fabricated therefrom
US8470197B2 (en) 2008-10-30 2013-06-25 Momentive Performance Materials Inc. Crosslinked polysulfide-containing cycloaliphatic compound, process for its preparation, filled sulfur-vulcanizable elastomer composition containing same and articles fabricated therefrom
JP2011012043A (ja) * 2009-07-03 2011-01-20 Kawaguchi Kagaku Kogyo Kk 加硫ゴム組成物に動的耐久性を付与する新規加硫促進剤
EP2517898A1 (de) 2011-04-29 2012-10-31 Lanxess Deutschland GmbH Kieselsäurehaltige Kautschukmischungen mit schwefelhaltigen Additiven
EP3053934A1 (en) * 2015-02-06 2016-08-10 LANXESS Deutschland GmbH Heteroatom containing modified diene polymers
CN105503677B (zh) * 2015-12-04 2017-06-30 山东阳谷华泰化工股份有限公司 一种环保、高效硫化交联剂1,6‑二（n,n‑二苄基氨基甲酰二硫）己烷的制备方法
JP6898250B2 (ja) * 2015-12-08 2021-07-07 住友精化株式会社 ゴム用添加剤
US10875810B2 (en) * 2016-08-15 2020-12-29 Battelle Memorial Institute Self-repairing cement polymer composites and processes of making and using same
CN109233035B (zh) * 2018-08-22 2020-10-23 江苏麒祥高新材料有限公司 一种粒径为40-100μm的橡胶用抗硫化返原剂及其合成新方法
CN111763165B (zh) * 2019-04-02 2022-07-08 康一昕 一种二硫代氨基甲酸类硫化交联剂的制备方法
CN112062701B (zh) * 2020-08-31 2022-05-24 华南理工大学 一种橡胶促进剂二乙基二硫代氨基甲酸砜及其制备方法与应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2422156A (en) * 1943-10-15 1947-06-10 Sharples Chemicals Inc Vulcanization of rubberlike butadiene-1,3 polymerizates with phenol sulfides
US2598407A (en) * 1947-09-25 1952-05-27 Du Pont Cross-linked polymeric materials and method of making same
US2619481A (en) * 1949-04-28 1952-11-25 Standard Oil Dev Co Curing rubbery olefinic copolymers
US2983716A (en) * 1958-03-26 1961-05-09 Standard Oil Co Rubber vulcanization acceleration
NL130667C (enExample) * 1966-10-13
US3705923A (en) * 1969-11-28 1972-12-12 Monsanto Co Method for preparation of organic polysulfides
JPS504375A (enExample) * 1973-05-07 1975-01-17

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4417012A (en) 1981-07-08 1983-11-22 Monsanto Europe S.A. Organic thiosulphates and thiosulphonates useful as stabilising agents for rubber vulcanisates

Also Published As

Publication number Publication date
JPS554136B2 (enExample) 1980-01-29
DE2256511A1 (de) 1973-05-30
JPS4862844A (enExample) 1973-09-01
DE2265382C2 (de) 1984-01-26
DE2256511C3 (de) 1980-06-19
DE2256511B2 (de) 1979-09-27
FR2186970A5 (enExample) 1974-01-11
DE2265382A1 (enExample) 1984-01-26
GB1388280A (en) 1975-03-26
CA987840A (en) 1976-04-20
US3869435A (en) 1975-03-04
IT971005B (it) 1974-04-30

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee