GB1361246A - Process for producing unsaturated carboxylic acid and catalyst for use therein - Google Patents
Process for producing unsaturated carboxylic acid and catalyst for use thereinInfo
- Publication number
- GB1361246A GB1361246A GB4900971A GB4900971A GB1361246A GB 1361246 A GB1361246 A GB 1361246A GB 4900971 A GB4900971 A GB 4900971A GB 4900971 A GB4900971 A GB 4900971A GB 1361246 A GB1361246 A GB 1361246A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- unsaturated carboxylic
- oct
- aqueous solution
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 239000011651 chromium Substances 0.000 abstract 2
- 239000010949 copper Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- 239000011148 porous material Substances 0.000 abstract 2
- 238000002360 preparation method Methods 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 abstract 1
- 229940010552 ammonium molybdate Drugs 0.000 abstract 1
- 235000018660 ammonium molybdate Nutrition 0.000 abstract 1
- 239000011609 ammonium molybdate Substances 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 239000000969 carrier Substances 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 abstract 1
- XAYGUHUYDMLJJV-UHFFFAOYSA-Z decaazanium;dioxido(dioxo)tungsten;hydron;trioxotungsten Chemical compound [H+].[H+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O XAYGUHUYDMLJJV-UHFFFAOYSA-Z 0.000 abstract 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- ALTWGIIQPLQAAM-UHFFFAOYSA-N metavanadate Chemical compound [O-][V](=O)=O ALTWGIIQPLQAAM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 239000011733 molybdenum Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000008262 pumice Substances 0.000 abstract 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 abstract 1
- 229910010271 silicon carbide Inorganic materials 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 239000010937 tungsten Substances 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/86—Chromium
- B01J23/868—Chromium copper and chromium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP45092759A JPS4911371B1 (enrdf_load_stackoverflow) | 1970-10-23 | 1970-10-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1361246A true GB1361246A (en) | 1974-07-24 |
Family
ID=14063343
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4900971A Expired GB1361246A (en) | 1970-10-23 | 1971-10-21 | Process for producing unsaturated carboxylic acid and catalyst for use therein |
Country Status (12)
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0034442A3 (en) * | 1980-02-08 | 1981-11-04 | The Standard Oil Company | Process for the preparation of unsaturated aldehydes and unsaturated acids |
| CN109305903A (zh) * | 2017-07-28 | 2019-02-05 | 中国石油化工股份有限公司 | 用于生产丙烯酸的方法 |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5129124B1 (enrdf_load_stackoverflow) * | 1971-04-27 | 1976-08-24 | ||
| DE2243584C3 (de) * | 1972-09-05 | 1980-10-09 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von Acrylsäure |
| US4077912A (en) * | 1972-10-12 | 1978-03-07 | Standard Oil Company | Catalysts useful for exothermic reactions |
| JPS5246208B2 (enrdf_load_stackoverflow) * | 1973-03-22 | 1977-11-22 | ||
| JPS533369B2 (enrdf_load_stackoverflow) * | 1973-03-30 | 1978-02-06 | ||
| GB1421956A (en) * | 1973-04-16 | 1976-01-21 | Standard Oil Co | Catalysts for the conversion of unsaturated aldehydes to acids |
| US4170572A (en) * | 1973-10-18 | 1979-10-09 | Union Carbide Corporation | Oxidation catalyst prepared with NH3 |
| US4111983A (en) * | 1973-10-18 | 1978-09-05 | Union Carbide Corporation | Oxidation of unsaturated aldehydes to unsaturated acids |
| US4051180A (en) * | 1976-01-02 | 1977-09-27 | The Standard Oil Company | Preparation of acrylic acid and methacrylic acid |
| JPS63189496U (enrdf_load_stackoverflow) * | 1987-05-28 | 1988-12-06 | ||
| EP1464393A1 (en) * | 1999-02-19 | 2004-10-06 | Nippon Shokubai Co., Ltd. | Catalyst for producing phthalic anhydride |
| WO2001042184A1 (fr) * | 1999-12-10 | 2001-06-14 | Mitsubishi Rayon Co., Ltd. | Methode de preparation d'acide methacrylique |
| WO2010001732A1 (ja) | 2008-06-30 | 2010-01-07 | 株式会社日本触媒 | 固定床多管式反応器への固体粒状物の充填方法 |
| JP2011121048A (ja) * | 2009-12-09 | 2011-06-23 | Rohm & Haas Co | 固体触媒物質をブレンドし、管状構造物に装填する方法 |
| WO2012073584A1 (ja) | 2010-12-03 | 2012-06-07 | 株式会社日本触媒 | 不飽和カルボン酸製造用触媒および該触媒を用いる不飽和カルボン酸の製造方法 |
| JP5845337B2 (ja) | 2012-03-29 | 2016-01-20 | 株式会社日本触媒 | 固定床多管式反応器を用いてのアクリル酸の製造方法 |
| US10479759B2 (en) | 2017-02-08 | 2019-11-19 | Clariant Corporation | Synthetic methods for the preparation of propylene ammoxidation catalysts |
| US10479760B2 (en) | 2017-02-08 | 2019-11-19 | Clariant Corporation | Synthetic methods for the preparation of propylene ammoxidation catalysts |
| CN116102421B (zh) * | 2023-02-10 | 2024-03-26 | 山东兴鲁承宏新材料科技有限公司 | 一种高产率丙烯酸烃基酯的连续化生产工艺 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3567772A (en) * | 1966-03-30 | 1971-03-02 | Toa Gosei Chem Ind | Process for the production of acrylic acid |
-
1970
- 1970-10-23 JP JP45092759A patent/JPS4911371B1/ja active Pending
-
1971
- 1971-10-19 DE DE2152037A patent/DE2152037C3/de not_active Expired
- 1971-10-19 US US00190661A patent/US3833649A/en not_active Expired - Lifetime
- 1971-10-21 NL NL717114523A patent/NL149781B/xx not_active IP Right Cessation
- 1971-10-21 GB GB4900971A patent/GB1361246A/en not_active Expired
- 1971-10-22 PL PL1971151174A patent/PL78378B1/pl unknown
- 1971-10-22 SU SU1709252A patent/SU436486A3/ru active
- 1971-10-22 DD DD15850071A patent/DD91810A5/xx unknown
- 1971-10-22 FR FR7138017A patent/FR2110044A5/fr not_active Expired
- 1971-10-22 CA CA125,897A patent/CA941384A/en not_active Expired
- 1971-10-22 BE BE774329A patent/BE774329A/xx not_active IP Right Cessation
- 1971-10-24 CS CS7457A patent/CS169826B2/cs unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0034442A3 (en) * | 1980-02-08 | 1981-11-04 | The Standard Oil Company | Process for the preparation of unsaturated aldehydes and unsaturated acids |
| CN109305903A (zh) * | 2017-07-28 | 2019-02-05 | 中国石油化工股份有限公司 | 用于生产丙烯酸的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA941384A (en) | 1974-02-05 |
| FR2110044A5 (enrdf_load_stackoverflow) | 1972-05-26 |
| US3833649A (en) | 1974-09-03 |
| BE774329A (fr) | 1972-02-14 |
| DE2152037A1 (de) | 1972-05-25 |
| DE2152037B2 (enrdf_load_stackoverflow) | 1974-02-14 |
| NL149781B (nl) | 1976-06-15 |
| SU436486A3 (ru) | 1974-07-15 |
| DD91810A5 (enrdf_load_stackoverflow) | 1972-08-12 |
| PL78378B1 (enrdf_load_stackoverflow) | 1975-06-30 |
| CS169826B2 (enrdf_load_stackoverflow) | 1976-07-29 |
| NL7114523A (enrdf_load_stackoverflow) | 1972-04-25 |
| DE2152037C3 (de) | 1984-02-02 |
| JPS4911371B1 (enrdf_load_stackoverflow) | 1974-03-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PE20 | Patent expired after termination of 20 years |