FR3123069B1 - Procede d’extraction et de transformation par transesterification de phtalates contenus dans des plastiques pvc au moyen d’alcool - Google Patents

Procede d’extraction et de transformation par transesterification de phtalates contenus dans des plastiques pvc au moyen d’alcool Download PDF

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Publication number
FR3123069B1
FR3123069B1 FR2105299A FR2105299A FR3123069B1 FR 3123069 B1 FR3123069 B1 FR 3123069B1 FR 2105299 A FR2105299 A FR 2105299A FR 2105299 A FR2105299 A FR 2105299A FR 3123069 B1 FR3123069 B1 FR 3123069B1
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FR
France
Prior art keywords
liquid
phthalate
alcohol
pvc
solid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR2105299A
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English (en)
French (fr)
Other versions
FR3123069A1 (fr
Inventor
Gondim Paiva Mayara Azin
Céline Bertino-Ghera
Alexandra Chaumonnot
Adrien Mekki-Berrada
Mathilde Sibeaud
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IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR2105299A priority Critical patent/FR3123069B1/fr
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to US18/561,498 priority patent/US20240227246A1/en
Priority to PCT/EP2022/062081 priority patent/WO2022243042A1/fr
Priority to KR1020237043999A priority patent/KR20240010497A/ko
Priority to BR112023020608A priority patent/BR112023020608A2/pt
Priority to JP2023571657A priority patent/JP2024518622A/ja
Priority to CA3213701A priority patent/CA3213701A1/fr
Priority to CN202280036043.8A priority patent/CN117355565A/zh
Priority to AU2022279334A priority patent/AU2022279334B2/en
Priority to MX2023013271A priority patent/MX2023013271A/es
Priority to EP22727176.4A priority patent/EP4341331A1/fr
Priority to TW111118538A priority patent/TW202307104A/zh
Publication of FR3123069A1 publication Critical patent/FR3123069A1/fr
Priority to CONC2023/0015456A priority patent/CO2023015456A2/es
Application granted granted Critical
Publication of FR3123069B1 publication Critical patent/FR3123069B1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/02—Recovery or working-up of waste materials of solvents, plasticisers or unreacted monomers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02—Separating plastics from other materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/04—Disintegrating plastics, e.g. by milling
    • B29B17/0412—Disintegrating plastics, e.g. by milling to large particles, e.g. beads, granules, flakes, slices
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/02—Preparation of carboxylic acid esters by interreacting ester groups, i.e. transesterification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02—Separating plastics from other materials
    • B29B2017/0203—Separating plastics from plastics
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02—Separating plastics from other materials
    • B29B2017/0213—Specific separating techniques
    • B29B2017/0217—Mechanical separating techniques; devices therefor
    • B29B2017/0224—Screens, sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02—Separating plastics from other materials
    • B29B2017/0213—Specific separating techniques
    • B29B2017/0217—Mechanical separating techniques; devices therefor
    • B29B2017/0231—Centrifugating, cyclones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02—Separating plastics from other materials
    • B29B2017/0213—Specific separating techniques
    • B29B2017/0262—Specific separating techniques using electrical caracteristics
    • B29B2017/0265—Electrostatic separation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02—Separating plastics from other materials
    • B29B2017/0213—Specific separating techniques
    • B29B2017/0293—Dissolving the materials in gases or liquids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02—Separating plastics from other materials
    • B29B2017/0213—Specific separating techniques
    • B29B2017/0293—Dissolving the materials in gases or liquids
    • B29B2017/0296—Dissolving the materials in aqueous alkaline solutions, e.g. NaOH or KOH
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2027/00—Use of polyvinylhalogenides or derivatives thereof as moulding material
    • B29K2027/06—PVC, i.e. polyvinylchloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0005—Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
    • B29K2105/0038—Plasticisers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/62—Plastics recycling; Rubber recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Sustainable Development (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
FR2105299A 2021-05-20 2021-05-20 Procede d’extraction et de transformation par transesterification de phtalates contenus dans des plastiques pvc au moyen d’alcool Active FR3123069B1 (fr)

Priority Applications (13)

Application Number Priority Date Filing Date Title
FR2105299A FR3123069B1 (fr) 2021-05-20 2021-05-20 Procede d’extraction et de transformation par transesterification de phtalates contenus dans des plastiques pvc au moyen d’alcool
EP22727176.4A EP4341331A1 (fr) 2021-05-20 2022-05-05 Procede d'extraction et de transformation par transesterification de phtalates contenus dans des plastiques pvc au moyen d'alcool
KR1020237043999A KR20240010497A (ko) 2021-05-20 2022-05-05 Pvc 플라스틱에 함유된 프탈레이트를 알코올에 의해 추출 및 변환하는 방법
BR112023020608A BR112023020608A2 (pt) 2021-05-20 2022-05-05 Processo de extração e de transformação por transesterificação de conteúdos de ftalatos em placas pvc por meio de álcool
JP2023571657A JP2024518622A (ja) 2021-05-20 2022-05-05 アルコールによるｐｖｃプラスチック中に含有されるフタラートの抽出および変換方法
CA3213701A CA3213701A1 (fr) 2021-05-20 2022-05-05 Procede d'extraction et de transformation par transesterification de phtalates contenus dans des plastiques pvc au moyen d'alcool
US18/561,498 US20240227246A1 (en) 2021-05-20 2022-05-05 Method for extraction and transformation of phthalates contained in pvc plastics by means of alcohol
AU2022279334A AU2022279334B2 (en) 2021-05-20 2022-05-05 Method for extraction and transformation of phthalates contained in pvc plastics by means of alcohol
MX2023013271A MX2023013271A (es) 2021-05-20 2022-05-05 Metodo de extraccion y transformacion por transesterificacion de los ftalatos contenidos en plasticos de cloruro de polivinilo (pvc) mediante un alcohol.
PCT/EP2022/062081 WO2022243042A1 (fr) 2021-05-20 2022-05-05 Procede d'extraction et de transformation par transesterification de phtalates contenus dans des plastiques pvc au moyen d'alcool
CN202280036043.8A CN117355565A (zh) 2021-05-20 2022-05-05 借助醇提取和转化pvc塑料中所含的邻苯二甲酸酯的方法
TW111118538A TW202307104A (zh) 2021-05-20 2022-05-18 使用醇類對pvc塑料中包含之鄰苯二甲酸酯類進行萃取及轉酯化反應之轉化方法
CONC2023/0015456A CO2023015456A2 (es) 2021-05-20 2023-11-16 Método de extracción y transformación de ftalatos contenidos en plásticos de pvc por medio de alcohol

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2105299 2021-05-20
FR2105299A FR3123069B1 (fr) 2021-05-20 2021-05-20 Procede d’extraction et de transformation par transesterification de phtalates contenus dans des plastiques pvc au moyen d’alcool

Publications (2)

Publication Number Publication Date
FR3123069A1 FR3123069A1 (fr) 2022-11-25
FR3123069B1 true FR3123069B1 (fr) 2024-07-26

Family

ID=76375316

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2105299A Active FR3123069B1 (fr) 2021-05-20 2021-05-20 Procede d’extraction et de transformation par transesterification de phtalates contenus dans des plastiques pvc au moyen d’alcool

Country Status (13)

Country Link
US (1) US20240227246A1 (https=)
EP (1) EP4341331A1 (https=)
JP (1) JP2024518622A (https=)
KR (1) KR20240010497A (https=)
CN (1) CN117355565A (https=)
AU (1) AU2022279334B2 (https=)
BR (1) BR112023020608A2 (https=)
CA (1) CA3213701A1 (https=)
CO (1) CO2023015456A2 (https=)
FR (1) FR3123069B1 (https=)
MX (1) MX2023013271A (https=)
TW (1) TW202307104A (https=)
WO (1) WO2022243042A1 (https=)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024134371A1 (en) * 2022-12-22 2024-06-27 Unilin, Bv Method for manufacturing a polyvinyl chloride products
WO2025120154A1 (en) 2023-12-07 2025-06-12 Inovyn Europe Limited Process for purifying pvc
FR3158512A1 (fr) * 2024-01-24 2025-07-25 Critical Polymers Procédé d’extraction par fluide supercritique d’au moins un plastifiant contenu dans un matériau polymérique solide notamment contenant ou constitué de polychlorure de vinyle – installation associée
JPWO2025192196A1 (https=) * 2024-03-15 2025-09-18

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5022074A (https=) * 1973-06-27 1975-03-08
IT1178901B (it) * 1984-03-22 1987-09-16 Irfin S P A Procedimento per il recupero selettivo dei materiali costituenti cascami di cavi elettrici isolati
FR2776664B1 (fr) 1998-03-26 2000-09-15 Ferrari S Tissage & Enduct Sa Procede de recyclage d'articles a base de polymeres du chlorure de vinyle
FR2806731B1 (fr) 2000-03-23 2002-06-14 Solvay Procede de recyclage d'une matiere plastique
DE10039363A1 (de) 2000-08-11 2002-03-07 Fraunhofer Ges Forschung Verfahren zur Trennung und Rückgewinnung von Zielpolymeren und deren Additiven aus einem polymerhaltigen Material
JP2004359880A (ja) * 2003-06-06 2004-12-24 Is:Kk 軟質ポリ塩化ビニル樹脂成形品からの可塑剤の抽出方法
JP4648213B2 (ja) * 2005-02-14 2011-03-09 日機装株式会社 可塑剤の回収方法
JP4034791B2 (ja) * 2005-03-31 2008-01-16 株式会社神鋼環境ソリューション 塩化ビニル樹脂の再生方法
JP4685728B2 (ja) 2005-08-31 2011-05-18 日機装株式会社 鉛含有軟質ポリ塩化ビニル素材の原料回収方法
JP4473225B2 (ja) 2006-01-19 2010-06-02 株式会社神鋼環境ソリューション 再生ポリ塩化ビニルコンパウンド製造方法。
EP2119741A1 (en) 2008-05-09 2009-11-18 SOLVAY (Société Anonyme) Process for recycling articles based on a fibre reinforced polymer
CN102516586B (zh) * 2011-12-16 2013-07-24 华南理工大学 一种从废弃塑料制品中回收邻苯二甲酸酯类增塑剂的方法

Also Published As

Publication number Publication date
MX2023013271A (es) 2023-11-30
CA3213701A1 (fr) 2022-11-24
CN117355565A (zh) 2024-01-05
EP4341331A1 (fr) 2024-03-27
KR20240010497A (ko) 2024-01-23
WO2022243042A1 (fr) 2022-11-24
JP2024518622A (ja) 2024-05-01
CO2023015456A2 (es) 2023-12-29
FR3123069A1 (fr) 2022-11-25
TW202307104A (zh) 2023-02-16
AU2022279334A1 (en) 2023-10-12
BR112023020608A2 (pt) 2023-12-05
US20240227246A1 (en) 2024-07-11
AU2022279334B2 (en) 2026-03-19

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