FR2945044B1 - Procede ameliore de production d'un (co) polymere d'ester acrylique - Google Patents
Procede ameliore de production d'un (co) polymere d'ester acryliqueInfo
- Publication number
- FR2945044B1 FR2945044B1 FR0952880A FR0952880A FR2945044B1 FR 2945044 B1 FR2945044 B1 FR 2945044B1 FR 0952880 A FR0952880 A FR 0952880A FR 0952880 A FR0952880 A FR 0952880A FR 2945044 B1 FR2945044 B1 FR 2945044B1
- Authority
- FR
- France
- Prior art keywords
- polymer
- reaction medium
- acrylic ester
- step consisting
- acrylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
L'invention a trait à un procédé de production d'un (co)polymère d'ester acrylique comprenant une première étape consistant à estérifier un acide acrylique technique, une deuxième étape consistant à polymériser en phase liquide ledit ester selon un processus choisi parmi les polymérisations en émulsion ou en solution dans des conditions telles que le polymère formé au sein du milieu réactionnel soit sous la forme d'un liquide plus ou moins visqueux au sein du milieu réactionnel, enfin une troisième étape consistant à soumettre la fraction de polymère formé, après le cas échéant sa séparation de l'essentiel du milieu réactionnel, à un traitement de séparation utilisant la technique des films minces. Le procédé selon l'invention permet de limiter les phases fort contraignantes de purification par distillation et/ou cristallisation de l'acide acrylique mises en oeuvre en amont de l'estérification et de la polymérisation proprement dite, et il est particulièrment adapté pour la fabrication de (co)polymères d'ester acrylique contenant du carbone d'origine renouvelable.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0952880A FR2945044B1 (fr) | 2009-04-30 | 2009-04-30 | Procede ameliore de production d'un (co) polymere d'ester acrylique |
EP10723681A EP2424832A1 (fr) | 2009-04-30 | 2010-04-15 | Procede ameliore de production d'un (co)polymere d'ester acrylique |
PCT/FR2010/050727 WO2010125276A1 (fr) | 2009-04-30 | 2010-04-15 | Procede ameliore de production d'un (co)polymere d'ester acrylique |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0952880A FR2945044B1 (fr) | 2009-04-30 | 2009-04-30 | Procede ameliore de production d'un (co) polymere d'ester acrylique |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2945044A1 FR2945044A1 (fr) | 2010-11-05 |
FR2945044B1 true FR2945044B1 (fr) | 2012-12-28 |
Family
ID=41055137
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR0952880A Expired - Fee Related FR2945044B1 (fr) | 2009-04-30 | 2009-04-30 | Procede ameliore de production d'un (co) polymere d'ester acrylique |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP2424832A1 (fr) |
FR (1) | FR2945044B1 (fr) |
WO (1) | WO2010125276A1 (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2529671T3 (es) | 2010-12-20 | 2015-02-24 | Dsm Ip Assets B.V. | Composición acuosa bio-renovable de polímero vinílico |
US11661536B2 (en) * | 2018-02-28 | 2023-05-30 | 3M Innovative Properties Company | Adhesives comprising polymerized units of secondary hexyl (meth)acrylates |
BR102020022314A2 (pt) * | 2020-10-30 | 2022-05-10 | Oxiteno S.A. Indústria E Comércio | Processo para a preparação de poliacrilatos alcoxilados funcionais, poliacrilatos alcoxilados funcionais, e, uso dos mesmos |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19716373A1 (de) * | 1997-04-18 | 1998-10-22 | Basf Ag | Kolonne und Verfahren zur Desodorierung von Dispersionen |
DE60015672T2 (de) * | 1999-08-27 | 2005-12-01 | Rohm And Haas Co. | Verfahren zum Abstrippen von Polymerdispersionen oder Polymerlösungen |
WO2002055472A1 (fr) * | 2000-12-18 | 2002-07-18 | Basf Aktiengesellschaft | Procede de preparation d'esters d'acide (meth)acrylique superieurs |
DE10138630A1 (de) * | 2001-08-13 | 2003-02-27 | Basf Ag | Verfahren zur Herstellung von Rein-(Meth)acrylsäure und Methacrylsäureestern |
US6884401B2 (en) * | 2002-07-17 | 2005-04-26 | Industiral Technology Research Institute | Method for removing volatile components from a high viscosity liquid by using rotation pack bed |
JP5006507B2 (ja) * | 2004-01-30 | 2012-08-22 | 株式会社日本触媒 | アクリル酸の製造方法 |
FR2920767B1 (fr) * | 2007-09-06 | 2009-12-18 | Arkema France | Procede de vaporisation reactive de glycerol |
-
2009
- 2009-04-30 FR FR0952880A patent/FR2945044B1/fr not_active Expired - Fee Related
-
2010
- 2010-04-15 WO PCT/FR2010/050727 patent/WO2010125276A1/fr active Application Filing
- 2010-04-15 EP EP10723681A patent/EP2424832A1/fr not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
WO2010125276A1 (fr) | 2010-11-04 |
EP2424832A1 (fr) | 2012-03-07 |
FR2945044A1 (fr) | 2010-11-05 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PLFP | Fee payment |
Year of fee payment: 7 |
|
ST | Notification of lapse |
Effective date: 20161230 |