FR3069534B1 - Preparation de nouveaux capteurs et filtres d'aldehydes et/ ou de cetones - Google Patents

Preparation de nouveaux capteurs et filtres d'aldehydes et/ ou de cetones Download PDF

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Publication number
FR3069534B1
FR3069534B1 FR1757251A FR1757251A FR3069534B1 FR 3069534 B1 FR3069534 B1 FR 3069534B1 FR 1757251 A FR1757251 A FR 1757251A FR 1757251 A FR1757251 A FR 1757251A FR 3069534 B1 FR3069534 B1 FR 3069534B1
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France
Prior art keywords
gel
chosen
tertbutylhydroxylamine
methoxyamine
tetramethoxysilane
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FR1757251A
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English (en)
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FR3069534A1 (fr
Inventor
Thu-Hoa Tran-Thi
Ana Borta
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Centre National de la Recherche Scientifique CNRS
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
Centre National de la Recherche Scientifique CNRS
Commissariat a lEnergie Atomique CEA
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
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Priority to FR1757251A priority Critical patent/FR3069534B1/fr
Application filed by Centre National de la Recherche Scientifique CNRS, Commissariat a lEnergie Atomique CEA, Commissariat a lEnergie Atomique et aux Energies Alternatives CEA filed Critical Centre National de la Recherche Scientifique CNRS
Priority to PCT/FR2018/051951 priority patent/WO2019020965A1/fr
Priority to CN201880059411.4A priority patent/CN111094183B/zh
Priority to EP18765694.7A priority patent/EP3658501A1/fr
Priority to KR1020207005491A priority patent/KR102513555B1/ko
Priority to US16/634,633 priority patent/US11571650B2/en
Publication of FR3069534A1 publication Critical patent/FR3069534A1/fr
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Publication of FR3069534B1 publication Critical patent/FR3069534B1/fr
Priority to US18/067,120 priority patent/US11904268B2/en
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
    • C01B33/157—After-treatment of gels
    • C01B33/158—Purification; Drying; Dehydrating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0048—Inorganic membrane manufacture by sol-gel transition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/024—Oxides
    • B01D71/027—Silicium oxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/25—Coated, impregnated or composite adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/306—Surface area, e.g. BET-specific surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/308—Pore size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708—Volatile organic compounds V.O.C.'s
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/06—Polluted air
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/45—Gas separation or purification devices adapted for specific applications
    • B01D2259/4508—Gas separation or purification devices adapted for specific applications for cleaning air in buildings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/02—Details relating to pores or porosity of the membranes
    • B01D2325/0283—Pore size
    • B01D2325/02831—Pore size less than 1 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/02—Details relating to pores or porosity of the membranes
    • B01D2325/0283—Pore size
    • B01D2325/02832—1-10 nm
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/16—Pore diameter

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Dispersion Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Silicon Polymers (AREA)
  • Glass Melting And Manufacturing (AREA)

Abstract

L'invention concerne un procédé de préparation d'une matrice sol-gel silicaté nanoporeuse renfermant au moins un réactif aminé choisi parmi l'hydroxylamine, la méthylhydroxylamine, la tertbutylhydroxylamine, la méthoxyamine, les dihydrazides d'acides dicarboxyliques, notamment le dihydrazide d'acide adipique, et leurs sels, ledit procédé comprenant les étapes suivantes : a) synthèse d'un gel à partir de tétraméthoxysilane ou d'un mélange de tétraméthoxysilane et d'un autre précurseur organosilicé choisi parmi le phényltriméthoxysilane, le phényltriéthoxysilane, un fluoroalkyltriméthoxysilane, un fluoroalkyltriéthoxysilane, un chloroalkylméthoxysilane, un chloroalkyléthoxysilane, un aminopropyltriéthoxysilane et leurs mélanges, la synthèse étant effectuée en milieu aqueux à une température allant de 10 à 70 °C en présence d'au moins un réactif aminé choisi parmi l'hydroxylamine, la méthylhydroxylamine, la tertbutylhydroxylamine, la méthoxyamine, les dihydrazides d'acides dicarboxyliques, notamment le dihydrazide d'acide adipique, et leurs sels ; b) séchage du gel obtenu à l'étape a) de façon à obtenir une matrice sol-gel renfermant au moins un réactif aminé.
FR1757251A 2017-07-28 2017-07-28 Preparation de nouveaux capteurs et filtres d'aldehydes et/ ou de cetones Active FR3069534B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1757251A FR3069534B1 (fr) 2017-07-28 2017-07-28 Preparation de nouveaux capteurs et filtres d'aldehydes et/ ou de cetones
CN201880059411.4A CN111094183B (zh) 2017-07-28 2018-07-27 制备新型醛和/或酮捕集器和过滤器
EP18765694.7A EP3658501A1 (fr) 2017-07-28 2018-07-27 Préparation de nouveaux capteurs et filtres d'aldéhydes et/ ou de cétones
KR1020207005491A KR102513555B1 (ko) 2017-07-28 2018-07-27 새로운 알데히드 및/또는 케톤 트랩과 필터의 제조
PCT/FR2018/051951 WO2019020965A1 (fr) 2017-07-28 2018-07-27 Préparation de nouveaux capteurs et filtres d'aldéhydes et/ ou de cétones
US16/634,633 US11571650B2 (en) 2017-07-28 2018-07-27 Preparation of new aldehyde and/or ketone traps and filters
US18/067,120 US11904268B2 (en) 2017-07-28 2022-12-16 Preparation of new aldehyde and/or ketone traps and filters

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1757251 2017-07-28
FR1757251A FR3069534B1 (fr) 2017-07-28 2017-07-28 Preparation de nouveaux capteurs et filtres d'aldehydes et/ ou de cetones

Publications (2)

Publication Number Publication Date
FR3069534A1 FR3069534A1 (fr) 2019-02-01
FR3069534B1 true FR3069534B1 (fr) 2020-10-16

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FR1757251A Active FR3069534B1 (fr) 2017-07-28 2017-07-28 Preparation de nouveaux capteurs et filtres d'aldehydes et/ ou de cetones

Country Status (6)

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US (2) US11571650B2 (fr)
EP (1) EP3658501A1 (fr)
KR (1) KR102513555B1 (fr)
CN (1) CN111094183B (fr)
FR (1) FR3069534B1 (fr)
WO (1) WO2019020965A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3098128B1 (fr) 2019-07-05 2023-11-17 Commissariat Energie Atomique Dispositif microfluidique comportant une microgoutte présentant une matrice sol-gel.
CN114146690B (zh) * 2021-12-02 2023-10-10 湖北中烟工业有限责任公司 羰基化合物捕集剂、呼出烟气中羰基化合物的捕集装置和检测方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6576568B2 (en) * 2000-04-04 2003-06-10 Applied Materials, Inc. Ionic additives for extreme low dielectric constant chemical formulations
US20030054562A1 (en) * 2001-03-16 2003-03-20 Peter Zhu Method and apparatus for rapidly assaying aldehyde-containing disinfectant
FR2890745B1 (fr) 2005-09-15 2007-11-30 Commissariat Energie Atomique Materiau nanoporeux d'aldehydes a transduction optique directe
CN101495409B (zh) * 2006-07-31 2011-07-27 扶桑化学工业股份有限公司 硅溶胶及其制造方法
JP2008178788A (ja) * 2007-01-24 2008-08-07 Toray Ind Inc 吸着剤
FR2933703B1 (fr) * 2008-07-11 2012-08-17 Commissariat Energie Atomique Detecteurs nanoporeux de composes aromatiques monocycliques et autres polluants
KR101155678B1 (ko) * 2010-07-30 2012-06-13 부산대학교 산학협력단 금속 이온의 선택적 흡착을 위한 유기-무기 하이브리드 중간세공 분자체 및 그 제조 방법
JP2014521809A (ja) * 2011-08-02 2014-08-28 エイビーエス マテリアルズ インコーポレイテッド ゾル−ゲル誘導組成物
EP2958985B1 (fr) * 2013-02-20 2021-03-31 Jian Chen Procédés et dispositifs d'électroporation
KR102270598B1 (ko) * 2013-12-24 2021-06-28 도아고세이가부시키가이샤 알데히드계 가스 흡착액 및 그것을 사용한 가스 흡착성 가공품
FR3026020B1 (fr) * 2014-09-24 2016-12-02 Seb Sa Dispositif de filtration pour appareil de purification d’air
CN105619558B (zh) * 2016-03-01 2017-03-22 山东农业大学 有机‑无机杂化超疏水疏油防霉杀菌阻燃耐候木材改性剂的制备方法

Also Published As

Publication number Publication date
WO2019020965A1 (fr) 2019-01-31
US11571650B2 (en) 2023-02-07
KR102513555B1 (ko) 2023-03-24
US11904268B2 (en) 2024-02-20
CN111094183A (zh) 2020-05-01
EP3658501A1 (fr) 2020-06-03
US20230121377A1 (en) 2023-04-20
US20200230542A1 (en) 2020-07-23
CN111094183B (zh) 2023-07-07
KR20200033931A (ko) 2020-03-30
FR3069534A1 (fr) 2019-02-01

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