FR3039779B1 - Catalyseur d'hydrodesulfuration d'essence et procede regule de preparation et utilisation de ce dernier - Google Patents

Catalyseur d'hydrodesulfuration d'essence et procede regule de preparation et utilisation de ce dernier Download PDF

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Publication number
FR3039779B1
FR3039779B1 FR1657456A FR1657456A FR3039779B1 FR 3039779 B1 FR3039779 B1 FR 3039779B1 FR 1657456 A FR1657456 A FR 1657456A FR 1657456 A FR1657456 A FR 1657456A FR 3039779 B1 FR3039779 B1 FR 3039779B1
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France
Prior art keywords
catalyst
gasoline
present
solution
hydrodesulfurization
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FR1657456A
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English (en)
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FR3039779A1 (fr
Inventor
Xiaojun Bao
Shufeng Shan
Tinghai Wang
Pei Yuan
Yu Fan
Gang Shi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China University of Petroleum Beijing
China National Petroleum Corp
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China University of Petroleum Beijing
China National Petroleum Corp
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

La présente invention a trait à un catalyseur d'hydrodésulfuration d'essence, à un procédé régulé de préparation de ce dernier et à son utilisation. Le procédé comprend les étapes suivantes : formulation d'une solution aqueuse d'un sel métallique du groupe VIB, en ajoutant un acide inorganique dans la solution aqueuse en vue de son acidification, pour obtenir une solution α ; addition d'une solution aqueuse de sel d'ammonium quaternaire dans la solution α pour obtenir une suspension et agitation minutieuse de la suspension ; mélange de la suspension et d'un support oxyde poreux, puis agitation du mélange dans un réacteur scellé, suivie d'un séchage et d'une calcination pour obtenir un catalyseur constitué d'un seul métal ; imprégnation du catalyseur constitué d'un seul métal avec une solution d'un sel métallique du groupe VIII, suivie d'un séchage et d'une calcination pour obtenir le catalyseur d'hydrodésulfuration d'essence. La présente invention a trait en outre au catalyseur d'hydrodésulfuration d'essence obtenu par le procédé ci-dessus et à son utilisation dans l'hydrodésulfuration d'essence. Dans le procédé de la présente invention, la régulation de la sélectivité du catalyseur dans l'hydrodésulfuration d'essence est obtenue en contrôlant la taille et la morphologie des phases actives du catalyseur. Le catalyseur de la présente invention peut inhiber l'activité de saturation des oléfines du catalyseur et présente une activité d'hydrodésulfuration et une sélectivité de désulfuration élevées.
FR1657456A 2015-08-03 2016-08-01 Catalyseur d'hydrodesulfuration d'essence et procede regule de preparation et utilisation de ce dernier Active FR3039779B1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510468200.4A CN106390989B (zh) 2015-08-03 2015-08-03 一种汽油加氢脱硫催化剂及其调控制备方法与应用

Publications (2)

Publication Number Publication Date
FR3039779A1 FR3039779A1 (fr) 2017-02-10
FR3039779B1 true FR3039779B1 (fr) 2024-01-12

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CN (1) CN106390989B (fr)
FR (1) FR3039779B1 (fr)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10384201B2 (en) 2016-02-17 2019-08-20 Korea Institute Of Energy Research Direct synthesis method of nanostructured catalyst particles on various supports and catalyst structure produced by the same
JP6933906B2 (ja) * 2016-02-17 2021-09-08 韓国エネルギー技術研究院Ｋｏｒｅａ Ｉｎｓｔｉｔｕｔｅ Ｏｆ Ｅｎｅｒｇｙ Ｒｅｓｅａｒｃｈ 多様な支持体の表面にナノ構造の触媒粒子の直接合成方法、これによって製造された触媒構造体
CN107694579B (zh) * 2017-03-14 2021-03-02 中国石油大学(北京) 一种硫化型加氢脱硫催化剂及其制备方法与应用
CN108014786A (zh) * 2017-12-08 2018-05-11 中国石油大学(北京) 一种高金属分散度催化剂及其制备方法与应用
CN110935460B (zh) * 2018-09-21 2023-02-28 中国石油天然气股份有限公司 一种高选择性加氢脱硫催化剂及其制备方法
CN111073688B (zh) * 2018-10-22 2021-10-08 中国石油化工股份有限公司 一种柴油深度脱硫加氢处理方法
CN111073689B (zh) * 2018-10-22 2021-10-08 中国石油化工股份有限公司 一种重质油加氢处理方法
CN111073697B (zh) * 2018-10-22 2021-10-08 中国石油化工股份有限公司 一种加氢裂化处理方法
CN111073699B (zh) * 2018-10-22 2021-10-08 中国石油化工股份有限公司 一种加氢处理方法
CN111151270B (zh) * 2018-11-08 2022-08-12 中国石油化工股份有限公司 一种馏分油加氢处理催化剂及其制备方法
CN111822040B (zh) * 2019-04-18 2022-10-11 中国石油化工股份有限公司 一种体相加氢裂化催化剂及其制备方法
CN112108159B (zh) * 2019-06-19 2022-08-12 中国石油化工股份有限公司 一种馏分油加氢处理催化剂的制备方法
CN113908860B (zh) * 2020-07-07 2024-05-28 中国石油天然气集团有限公司 汽油加氢脱硫催化剂及其制备方法
CN116060032A (zh) * 2021-10-30 2023-05-05 中国石油化工股份有限公司 一种蜡油加氢处理催化剂及其制备方法与应用
CN116060041B (zh) * 2021-10-30 2024-07-02 中国石油化工股份有限公司 一种渣油加氢处理催化剂及其制备方法与应用
CN115011375A (zh) * 2022-07-27 2022-09-06 重庆工商大学 一种废润滑油悬浮床加氢再生方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2843050B1 (fr) * 2002-08-01 2005-04-15 Inst Francais Du Petrole Catalyseur a base de metaux du groupe vi et du groupe viii presents au moins en partie sous la forme d'heteropolyanions dans le precurseur oxyde
EP2102315B1 (fr) * 2006-12-19 2017-08-02 ExxonMobil Research and Engineering Company Méthode pour la preparation des catalyseurs d'hydrocraquage de distillat supportés à haute activité
CN101298047A (zh) * 2007-04-30 2008-11-05 中国石油天然气集团公司 加氢催化剂的制备方法
CN101306374B (zh) * 2007-05-16 2012-01-25 中国石油化工股份有限公司 一种加氢催化剂组合物、制备及其应用
CN101664684B (zh) * 2008-09-04 2012-10-10 中国石油化工股份有限公司 一种加氢催化剂组合物及其应用
CN103143365B (zh) * 2011-12-06 2015-03-11 中国石油天然气集团公司 一种加氢催化剂及其制备方法
CN103785447B (zh) * 2012-11-03 2016-08-17 中国石油化工股份有限公司 加氢裂化催化剂的清洁制备方法

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Publication number Publication date
CN106390989B (zh) 2019-02-19
FR3039779A1 (fr) 2017-02-10
CN106390989A (zh) 2017-02-15

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