FR3036978B1 - Procede de preparation d'un materiau adsorbant comprenant une etape de precipitation de boehmite operant dans des conditions specifiques et procede d'extraction de lithium a partir de solutions salines utilisant ledit materiau - Google Patents

Procede de preparation d'un materiau adsorbant comprenant une etape de precipitation de boehmite operant dans des conditions specifiques et procede d'extraction de lithium a partir de solutions salines utilisant ledit materiau Download PDF

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Publication number
FR3036978B1
FR3036978B1 FR1555157A FR1555157A FR3036978B1 FR 3036978 B1 FR3036978 B1 FR 3036978B1 FR 1555157 A FR1555157 A FR 1555157A FR 1555157 A FR1555157 A FR 1555157A FR 3036978 B1 FR3036978 B1 FR 3036978B1
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Prior art keywords
preparation
under specific
lithium
boehmite
saline solutions
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FR1555157A
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FR3036978A1 (fr
Inventor
Malika Boualleg
Fabien Burdet
Morgan GOHIN
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IFP Energies Nouvelles IFPEN
Eramet SA
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IFP Energies Nouvelles IFPEN
Eramet SA
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Priority to FR1555157A priority Critical patent/FR3036978B1/fr
Application filed by IFP Energies Nouvelles IFPEN, Eramet SA filed Critical IFP Energies Nouvelles IFPEN
Priority to PCT/EP2016/062667 priority patent/WO2016193439A1/fr
Priority to CN201680032816.XA priority patent/CN107787248B/zh
Priority to ARP160101658A priority patent/AR104902A1/es
Priority to EP16730287.6A priority patent/EP3302787A1/fr
Priority to US15/579,811 priority patent/US10786802B2/en
Publication of FR3036978A1 publication Critical patent/FR3036978A1/fr
Priority to CL2017003061A priority patent/CL2017003061A1/es
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Publication of FR3036978B1 publication Critical patent/FR3036978B1/fr
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/043—Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/045—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing sulfur, e.g. sulfates, thiosulfates, gypsum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/046—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing halogens, e.g. halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3007—Moulding, shaping or extruding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3071—Washing or leaching
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3433—Regenerating or reactivating of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
    • B01J20/3475—Regenerating or reactivating using a particular desorbing compound or mixture in the liquid phase
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/10—Oxides or hydroxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/04—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom
    • C01F7/14—Aluminium oxide or hydroxide from alkali metal aluminates
    • C01F7/141—Aluminium oxide or hydroxide from alkali metal aluminates from aqueous aluminate solutions by neutralisation with an acidic agent
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/34—Preparation of aluminium hydroxide by precipitation from solutions containing aluminium salts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/78—Compounds containing aluminium and two or more other elements, with the exception of oxygen and hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/78—Compounds containing aluminium and two or more other elements, with the exception of oxygen and hydrogen
    • C01F7/782—Compounds containing aluminium and two or more other elements, with the exception of oxygen and hydrogen containing carbonate ions, e.g. dawsonite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
    • B01J2220/58—Use in a single column
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

La présente invention se rapporte au domaine des matériaux solides pour l'adsorption du lithium. En particulier, la présente invention se rapporte à un nouveau procédé de préparation d'un matériau solide cristallisé et mis en forme, de préférence sous forme d'extrudés, de formule LiXx.2Al(OH)3,nH2O avec n étant compris entre 0,01 et 10, x étant égal à 1 quand X est un anion choisi parmi les anions chlorure, hydroxyde et nitrate, et x étant égal à 0,5 quand X est un anion choisi parmi les anions sulfate et carbonate, comprenant une étape a) de précipitation de boehmite dans des conditions de température et de pH spécifiques, au moins une étape de mise en forme, de préférence par extrusion, ledit procédé comprenant également une étape de traitement hydrothermal finale, le tout permettant d'augmenter la capacité d'adsorption du lithium ainsi que la cinétique d'adsorption des matériaux obtenus par rapport aux matériaux de l'art antérieur lorsque celui-ci est utilisé dans un procédé d'extraction du lithium de solutions salines.
FR1555157A 2015-06-05 2015-06-05 Procede de preparation d'un materiau adsorbant comprenant une etape de precipitation de boehmite operant dans des conditions specifiques et procede d'extraction de lithium a partir de solutions salines utilisant ledit materiau Active FR3036978B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1555157A FR3036978B1 (fr) 2015-06-05 2015-06-05 Procede de preparation d'un materiau adsorbant comprenant une etape de precipitation de boehmite operant dans des conditions specifiques et procede d'extraction de lithium a partir de solutions salines utilisant ledit materiau
CN201680032816.XA CN107787248B (zh) 2015-06-05 2016-06-03 包括在特定条件下使勃姆石沉淀的步骤的制备吸附材料的方法以及利用该材料从盐溶液提取锂的方法
ARP160101658A AR104902A1 (es) 2015-06-05 2016-06-03 Procedimiento de preparación de un material absorbente que comprende una etapa de precipitación de boehmita
EP16730287.6A EP3302787A1 (fr) 2015-06-05 2016-06-03 Procede de preparation d'un materiau adsorbant comprenant une etape de precipitation de boehmite operant dans des conditions specifiques et procede d'extraction de lithium a partir de solutions salines utilisant ledit materiau
PCT/EP2016/062667 WO2016193439A1 (fr) 2015-06-05 2016-06-03 Procede de preparation d'un materiau adsorbant comprenant une etape de precipitation de boehmite operant dans des conditions specifiques et procede d'extraction de lithium a partir de solutions salines utilisant ledit materiau
US15/579,811 US10786802B2 (en) 2015-06-05 2016-06-03 Process for preparing an adsorbing material comprising a precipitating step of boehmite according to specific conditions and process for extracting lithium from saline solutions using this material
CL2017003061A CL2017003061A1 (es) 2015-06-05 2017-12-01 Proceso para preparar y adsorber material que comprende una etapa de precipitación de boehmita en condiciones especificas y proceso de extracción de litio desde soluciones salinas utilizando este material

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1555157A FR3036978B1 (fr) 2015-06-05 2015-06-05 Procede de preparation d'un materiau adsorbant comprenant une etape de precipitation de boehmite operant dans des conditions specifiques et procede d'extraction de lithium a partir de solutions salines utilisant ledit materiau
FR1555157 2015-06-05

Publications (2)

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FR3036978A1 FR3036978A1 (fr) 2016-12-09
FR3036978B1 true FR3036978B1 (fr) 2020-02-21

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FR1555157A Active FR3036978B1 (fr) 2015-06-05 2015-06-05 Procede de preparation d'un materiau adsorbant comprenant une etape de precipitation de boehmite operant dans des conditions specifiques et procede d'extraction de lithium a partir de solutions salines utilisant ledit materiau

Country Status (7)

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US (1) US10786802B2 (fr)
EP (1) EP3302787A1 (fr)
CN (1) CN107787248B (fr)
AR (1) AR104902A1 (fr)
CL (1) CL2017003061A1 (fr)
FR (1) FR3036978B1 (fr)
WO (1) WO2016193439A1 (fr)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3051787B1 (fr) * 2016-05-25 2022-07-08 Eramet Procede de preparation d'un materiau adsorbant et procede d'extraction de lithium utilisant ledit materiau
FR3053264B1 (fr) * 2016-06-30 2022-07-29 Eramet Procede de preparation d'un materiau adsorbant et procede d'extraction de lithium a partir de solutions salines utilisant ledit materiau
CN108083301A (zh) * 2017-11-10 2018-05-29 江苏旌凯中科超导高技术有限公司 利用磁性粉体铝系锂吸附剂从卤水中提取锂的方法
WO2020219625A1 (fr) 2019-04-25 2020-10-29 Saint-Gobain Ceramics & Plastics, Inc. Particules adsorbantes et procédés de formation associés
CN111330540A (zh) * 2020-03-06 2020-06-26 旬阳领盛新材料科技有限公司 一种氧化石墨烯复合铝系锂吸附剂的制备方法
CN112691654B (zh) * 2020-12-25 2024-04-02 华东理工大学 一种铝盐锂吸附剂的一步再生方法
CN114558557B (zh) * 2022-03-22 2022-09-09 北京中科顺谷科技发展有限公司 基于分子筛吸附剂的天然卤水中锂提取吸附颗粒及其制备方法
US11904297B1 (en) 2023-01-11 2024-02-20 Iliad Ip Company, Llc Process for manufacturing lithium selective adsorption/separation media

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Publication number Publication date
US10786802B2 (en) 2020-09-29
US20180353932A1 (en) 2018-12-13
CN107787248B (zh) 2021-01-12
CN107787248A (zh) 2018-03-09
AR104902A1 (es) 2017-08-23
FR3036978A1 (fr) 2016-12-09
EP3302787A1 (fr) 2018-04-11
WO2016193439A1 (fr) 2016-12-08
CL2017003061A1 (es) 2018-08-24

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