FR2830466B1 - Utilisation d'une composition a base de ti02 comme catalyseur pour realiser l'hydrolyse des cos et/ou d'hcn dans un melange gazeux - Google Patents
Utilisation d'une composition a base de ti02 comme catalyseur pour realiser l'hydrolyse des cos et/ou d'hcn dans un melange gazeuxInfo
- Publication number
- FR2830466B1 FR2830466B1 FR0112987A FR0112987A FR2830466B1 FR 2830466 B1 FR2830466 B1 FR 2830466B1 FR 0112987 A FR0112987 A FR 0112987A FR 0112987 A FR0112987 A FR 0112987A FR 2830466 B1 FR2830466 B1 FR 2830466B1
- Authority
- FR
- France
- Prior art keywords
- catalyst
- cos
- realizing
- gaseous mixture
- based composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 2
- 239000008246 gaseous mixture Substances 0.000 title 1
- 230000007062 hydrolysis Effects 0.000 title 1
- 238000006460 hydrolysis reaction Methods 0.000 title 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 239000011575 calcium Substances 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 229910052712 strontium Inorganic materials 0.000 abstract 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8603—Removing sulfur compounds
- B01D53/8606—Removing sulfur compounds only one sulfur compound other than sulfur oxides or hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/053—Sulfates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/308—Carbonoxysulfide COS
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/408—Cyanides, e.g. hydrogen cyanide (HCH)
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0112987A FR2830466B1 (fr) | 2001-10-09 | 2001-10-09 | Utilisation d'une composition a base de ti02 comme catalyseur pour realiser l'hydrolyse des cos et/ou d'hcn dans un melange gazeux |
| US10/492,175 US7374737B2 (en) | 2001-10-09 | 2002-10-08 | Use of a tiO2 composition as catalyst for hydrolyzing COS and/or HCN |
| AT02785532T ATE324942T1 (de) | 2001-10-09 | 2002-10-08 | Verwendung einer auf tio2 basierten zusammensetzung als katalysator zur hydrolyse von cos und/oder hcn |
| CA2461957A CA2461957C (fr) | 2001-10-09 | 2002-10-08 | Utilisation d'une composition a base de tio2 comme catalyseur pour realiser l'hydrolyse des cos et/ou d'hcn dans un melange gazeux |
| PCT/FR2002/003427 WO2003031058A1 (fr) | 2001-10-09 | 2002-10-08 | Utilisation d'une composition a base de tio2 comme catalyseur pour realiser l'hydrolyse des cos et/ou d'hcn |
| ES02785532T ES2263832T5 (es) | 2001-10-09 | 2002-10-08 | Utilizacion de una composicion a base de tio2 como catalizador para realizar la hidrolisis de los cos y/o de hcn. |
| EP02785532A EP1436081B2 (fr) | 2001-10-09 | 2002-10-08 | Utilisation d'une composition a base de tio2 comme catalyseur pour realiser l'hydrolyse des cos et/ou d'hcn |
| JP2003534080A JP4556159B2 (ja) | 2001-10-09 | 2002-10-08 | ガス混合物中のCOSおよび/またはHCNを加水分解するための触媒としてのTiO2系組成物の使用 |
| CNB02819926XA CN1313203C (zh) | 2001-10-09 | 2002-10-08 | 一种基于TiO2的组合物作为气体混合物中COS和/或HCN的水解催化剂的用途 |
| RU2004113661/04A RU2297878C2 (ru) | 2001-10-09 | 2002-10-08 | ПРИМЕНЕНИЕ КОМПОЗИЦИИ НА ОСНОВЕ TiO2 В КАЧЕСТВЕ КАТАЛИЗАТОРА ГИДРОЛИЗА COS И/ИЛИ HCN В ГАЗООБРАЗНОЙ СМЕСИ |
| DE60211193T DE60211193T3 (de) | 2001-10-09 | 2002-10-08 | Verwendung einer auf tio2 basierten zusammensetzung als katalysator zur hydrolyse von cos und/oder hcn |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0112987A FR2830466B1 (fr) | 2001-10-09 | 2001-10-09 | Utilisation d'une composition a base de ti02 comme catalyseur pour realiser l'hydrolyse des cos et/ou d'hcn dans un melange gazeux |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2830466A1 FR2830466A1 (fr) | 2003-04-11 |
| FR2830466B1 true FR2830466B1 (fr) | 2004-02-06 |
Family
ID=8868086
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR0112987A Expired - Lifetime FR2830466B1 (fr) | 2001-10-09 | 2001-10-09 | Utilisation d'une composition a base de ti02 comme catalyseur pour realiser l'hydrolyse des cos et/ou d'hcn dans un melange gazeux |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7374737B2 (enExample) |
| EP (1) | EP1436081B2 (enExample) |
| JP (1) | JP4556159B2 (enExample) |
| CN (1) | CN1313203C (enExample) |
| AT (1) | ATE324942T1 (enExample) |
| CA (1) | CA2461957C (enExample) |
| DE (1) | DE60211193T3 (enExample) |
| ES (1) | ES2263832T5 (enExample) |
| FR (1) | FR2830466B1 (enExample) |
| RU (1) | RU2297878C2 (enExample) |
| WO (1) | WO2003031058A1 (enExample) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100441287C (zh) * | 2002-04-18 | 2008-12-10 | 触媒化成工业株式会社 | 蜂窝状废气处理催化剂用二氧化钛粉末及废气处理催化剂 |
| JP4467872B2 (ja) | 2002-08-09 | 2010-05-26 | 三菱重工業株式会社 | ガス化ガス用のcos処理装置とcos処理方法 |
| CN101108337B (zh) * | 2007-07-06 | 2010-09-22 | 萍乡庞泰实业有限公司 | 氰化氢分解催化剂 |
| FR2922783B1 (fr) * | 2007-10-31 | 2010-11-19 | Inst Francais Du Petrole | Traitements de gaz de queue d'une unite claus sur un enchainement optimise de catalyseurs |
| FR2940920B1 (fr) * | 2009-01-12 | 2011-10-21 | Inst Francais Du Petrole | Procede d'elimination d'impuretes soufrees, azotees et halogenees contenues dans un gaz de synthese |
| FR2940919B1 (fr) | 2009-01-12 | 2011-12-09 | Inst Francais Du Petrole | Utilisation d'une composition a base de tio2 pour la captation de composes halogenes contenus dans un melange gazeux |
| JP5955026B2 (ja) * | 2012-02-24 | 2016-07-20 | 三菱重工業株式会社 | 硫化カルボニルおよびシアン化水素の加水分解用触媒ならびに酸化チタン系組成物の使用 |
| US8691167B2 (en) | 2012-07-19 | 2014-04-08 | Tronox Llc | Process for controlling carbonyl sulfide produced during chlorination of ores |
| KR102144327B1 (ko) | 2013-02-22 | 2020-08-14 | 존슨 맛세이 프로세스 테크놀로지즈 인코퍼레이티드 | 연도 가스로부터 hcn의 제거방법 |
| WO2016103364A1 (ja) * | 2014-12-24 | 2016-06-30 | 三菱重工業株式会社 | 排ガス用触媒、排ガス処理装置および排ガス処理方法 |
| RU2720181C1 (ru) * | 2016-07-13 | 2020-04-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ получения наночастиц дисульфида молибдена на носителе из диоксида титана |
| CN106362759B (zh) * | 2016-08-03 | 2017-11-10 | 荆楚理工学院 | 焚烧危险废物的催化剂、其制备方法和用途 |
| CN106311265B (zh) * | 2016-08-03 | 2018-12-14 | 荆楚理工学院 | 催化焚烧危废的装置及其使用方法 |
| CN107913595B (zh) * | 2016-10-09 | 2019-12-10 | 中国石油化工股份有限公司 | 含氰废气的催化氧化处理方法 |
| JP6789777B2 (ja) * | 2016-11-22 | 2020-11-25 | 三菱重工エンジニアリング株式会社 | ガス精製装置及びガス精製方法 |
| FR3067265B1 (fr) * | 2017-06-13 | 2019-07-26 | IFP Energies Nouvelles | Procede de preparation de solides a partir d'un melange d'au moins une poudre de malachite et une poudre d'oxyde et utilisation de ces solides |
| JP7051451B2 (ja) * | 2018-01-12 | 2022-04-11 | 三菱重工エンジニアリング株式会社 | 硫化カルボニルの加水分解用触媒及びその製造方法 |
| US11441116B2 (en) | 2018-02-12 | 2022-09-13 | Lanzatech, Inc. | Integrated process for filtering constituents from a gas stream |
| CN109248692B (zh) * | 2018-08-22 | 2021-06-18 | 昆明理工大学 | 一种氰化氢水解增效催化剂的制备方法及应用 |
| CN109701542A (zh) * | 2018-12-21 | 2019-05-03 | 昆明理工大学 | 一种低温协同催化净化烟气中NOx和HCN的催化剂制备方法及应用 |
| JP7419058B2 (ja) * | 2019-09-26 | 2024-01-22 | 新コスモス電機株式会社 | 硫化カルボニル分解装置および硫化カルボニル検知装置 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2501532B1 (fr) * | 1981-03-13 | 1985-12-13 | Rhone Poulenc Spec Chim | Catalyseur et procede pour le traitement des gaz residuaires industriels contenant des composes du soufre |
| FR2501662A1 (fr) * | 1981-03-13 | 1982-09-17 | Rhone Poulenc Spec Chim | Catalyseurs et procede d'oxydation de l'hydrogene sulfure et/ou des composes organiques du soufre en anhydride sulfureux |
| FR2518424B1 (fr) * | 1981-12-17 | 1988-03-11 | Elf Aquitaine | Procede de desulfuration catalytique d'un gaz acide renfermant h2s, et eventuellement une quantite globale d'au plus 3 % en volume de cs2 et/ou cos |
| US4511668A (en) * | 1983-10-25 | 1985-04-16 | Catalysts & Chemicals Industries Co., Ltd. | Catalyst for use in hydrolysis of carbonyl sulfide |
| FR2574309B1 (fr) * | 1984-12-12 | 1989-10-06 | Elf Aquitaine | Procede d'elimination des composes cos et cs2 contenus dans un gaz industriel |
| DE3736478A1 (de) † | 1987-10-28 | 1989-05-11 | Huels Chemische Werke Ag | Verfahren zur herstellung eines gegen arsenvergiftung resistenten katalysators zur entfernung von stickoxiden aus abgasen |
| NL185225C (nl) * | 1988-01-13 | 1992-03-16 | Comprimo Bv | Werkwijze voor het omzetten en verwijderen van zwavelverbindingen uit een co-bevattend gas. |
| RU2050194C1 (ru) * | 1990-09-17 | 1995-12-20 | Институт катализа СО РАН | Способ приготовления формованного ванадий-титанового катализатора для очистки газов |
| DE4116364A1 (de) * | 1991-05-18 | 1992-11-19 | Basf Ag | Metalloxide enthaltender katalysator fuer verfahren zum oxidativen abbau von organischen verbindungen aus abgasen von verbrennungsanlagen |
| DE4206913A1 (de) * | 1992-03-05 | 1993-09-09 | Kronos Titan Gmbh | Katalysator fuer die carbonylsulfid-hydrolyse |
| DE4319234A1 (de) * | 1993-06-09 | 1994-12-15 | Linde Ag | Verfahren zur Entfernung von HCN aus Gasgemischen und Katalysator zur Zersetzung von HCN |
| DE4424695A1 (de) † | 1993-07-14 | 1995-01-19 | Cabot Corp | Neue Katalysatoren und Behandlung von Gasen mit denselben |
| DE4431788A1 (de) * | 1994-09-07 | 1996-03-14 | Huels Chemische Werke Ag | Katalysator und Verfahren zur Zersetzung von HCN in Gasen |
| DE69607423T2 (de) † | 1995-08-08 | 2000-08-03 | Exxon Research And Engineering Co., Florham Park | Verfahren zur Beseitigung von Cyanwasserstoff aus Synthesegas |
| CN1048916C (zh) * | 1995-08-16 | 2000-02-02 | 南京化学工业(集团)公司催化剂厂 | 有机硫水解催化剂及其制备 |
-
2001
- 2001-10-09 FR FR0112987A patent/FR2830466B1/fr not_active Expired - Lifetime
-
2002
- 2002-10-08 RU RU2004113661/04A patent/RU2297878C2/ru active
- 2002-10-08 JP JP2003534080A patent/JP4556159B2/ja not_active Expired - Lifetime
- 2002-10-08 CN CNB02819926XA patent/CN1313203C/zh not_active Expired - Lifetime
- 2002-10-08 DE DE60211193T patent/DE60211193T3/de not_active Expired - Lifetime
- 2002-10-08 WO PCT/FR2002/003427 patent/WO2003031058A1/fr not_active Ceased
- 2002-10-08 ES ES02785532T patent/ES2263832T5/es not_active Expired - Lifetime
- 2002-10-08 US US10/492,175 patent/US7374737B2/en not_active Expired - Lifetime
- 2002-10-08 EP EP02785532A patent/EP1436081B2/fr not_active Expired - Lifetime
- 2002-10-08 CA CA2461957A patent/CA2461957C/fr not_active Expired - Lifetime
- 2002-10-08 AT AT02785532T patent/ATE324942T1/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| JP2005504631A (ja) | 2005-02-17 |
| CA2461957A1 (fr) | 2003-04-17 |
| ES2263832T5 (es) | 2010-07-06 |
| ATE324942T1 (de) | 2006-06-15 |
| ES2263832T3 (es) | 2006-12-16 |
| JP4556159B2 (ja) | 2010-10-06 |
| US20040247507A1 (en) | 2004-12-09 |
| CN1313203C (zh) | 2007-05-02 |
| CN1564710A (zh) | 2005-01-12 |
| RU2297878C2 (ru) | 2007-04-27 |
| WO2003031058A1 (fr) | 2003-04-17 |
| RU2004113661A (ru) | 2005-09-10 |
| CA2461957C (fr) | 2011-06-21 |
| DE60211193T2 (de) | 2006-08-31 |
| FR2830466A1 (fr) | 2003-04-11 |
| EP1436081B2 (fr) | 2010-04-28 |
| EP1436081B1 (fr) | 2006-05-03 |
| US7374737B2 (en) | 2008-05-20 |
| EP1436081A1 (fr) | 2004-07-14 |
| DE60211193T3 (de) | 2010-09-16 |
| DE60211193D1 (de) | 2006-06-08 |
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