FR2729090A1 - Catalyseurs de reduction selective des oxydes d'azote en azote en milieu oxydant, procede de preparation et utilisation - Google Patents

Catalyseurs de reduction selective des oxydes d'azote en azote en milieu oxydant, procede de preparation et utilisation Download PDF

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Publication number
FR2729090A1
FR2729090A1 FR9500259A FR9500259A FR2729090A1 FR 2729090 A1 FR2729090 A1 FR 2729090A1 FR 9500259 A FR9500259 A FR 9500259A FR 9500259 A FR9500259 A FR 9500259A FR 2729090 A1 FR2729090 A1 FR 2729090A1
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FR
France
Prior art keywords
metal
belonging
catalyst according
oxide
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR9500259A
Other languages
English (en)
French (fr)
Other versions
FR2729090B1 (en, 2012
Inventor
Daniel Durand
Gil Mabilon
Courtils Nicolas Des
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR9500259A priority Critical patent/FR2729090A1/fr
Priority to DE69627400T priority patent/DE69627400T2/de
Priority to EP96400035A priority patent/EP0721796B1/fr
Priority to ES96400035T priority patent/ES2196127T3/es
Priority to US08/584,125 priority patent/US5801114A/en
Priority to JP8002719A priority patent/JPH08229396A/ja
Publication of FR2729090A1 publication Critical patent/FR2729090A1/fr
Application granted granted Critical
Publication of FR2729090B1 publication Critical patent/FR2729090B1/fr
Granted legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0205Impregnation in several steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404Removing only nitrogen compounds
    • B01D53/9409Nitrogen oxides
    • B01D53/9413Processes characterised by a specific catalyst
    • B01D53/9418Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/208Hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/21Organic compounds not provided for in groups B01D2251/206 or B01D2251/208
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/10Noble metals or compounds thereof
    • B01D2255/102Platinum group metals
    • B01D2255/1021Platinum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/10Noble metals or compounds thereof
    • B01D2255/102Platinum group metals
    • B01D2255/1028Iridium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/10Noble metals or compounds thereof
    • B01D2255/106Gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/204Alkaline earth metals
    • B01D2255/2042Barium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/206Rare earth metals
    • B01D2255/2063Lanthanum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/206Rare earth metals
    • B01D2255/2066Praseodymium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20707Titanium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/50Zeolites
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/10Capture or disposal of greenhouse gases of nitrous oxide (N2O)

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Combustion & Propulsion (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
FR9500259A 1995-01-11 1995-01-11 Catalyseurs de reduction selective des oxydes d'azote en azote en milieu oxydant, procede de preparation et utilisation Granted FR2729090A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR9500259A FR2729090A1 (fr) 1995-01-11 1995-01-11 Catalyseurs de reduction selective des oxydes d'azote en azote en milieu oxydant, procede de preparation et utilisation
DE69627400T DE69627400T2 (de) 1995-01-11 1996-01-08 Katalysator zur selektiven Reduktion von Stichoxiden in einer oxidierenden Umgebung, Verfahren zur Herstellung und Verwendung
EP96400035A EP0721796B1 (fr) 1995-01-11 1996-01-08 Catalyseur de réduction sélective des oxydes d'azote en milieu oxydant, procédé de préparation et utilisation
ES96400035T ES2196127T3 (es) 1995-01-11 1996-01-08 Catalizador de reduccion selectiva de oxido de nitrogeno en medio oxidante, procedimiento de preparacion y utilizacion.
US08/584,125 US5801114A (en) 1995-01-11 1996-01-11 Catalysts selective for the reduction of nitrogen oxides to nitrogen in an oxidizing medium, a process for their preparation and their use
JP8002719A JPH08229396A (ja) 1995-01-11 1996-01-11 酸化性媒質中で窒素酸化物を窒素に選択的に還元する触媒、その調製方法および使用

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9500259A FR2729090A1 (fr) 1995-01-11 1995-01-11 Catalyseurs de reduction selective des oxydes d'azote en azote en milieu oxydant, procede de preparation et utilisation

Publications (2)

Publication Number Publication Date
FR2729090A1 true FR2729090A1 (fr) 1996-07-12
FR2729090B1 FR2729090B1 (en, 2012) 1997-02-14

Family

ID=9475031

Family Applications (1)

Application Number Title Priority Date Filing Date
FR9500259A Granted FR2729090A1 (fr) 1995-01-11 1995-01-11 Catalyseurs de reduction selective des oxydes d'azote en azote en milieu oxydant, procede de preparation et utilisation

Country Status (6)

Country Link
US (1) US5801114A (en, 2012)
EP (1) EP0721796B1 (en, 2012)
JP (1) JPH08229396A (en, 2012)
DE (1) DE69627400T2 (en, 2012)
ES (1) ES2196127T3 (en, 2012)
FR (1) FR2729090A1 (en, 2012)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU718321B2 (en) * 1995-05-05 2000-04-13 W.R. Grace & Co.-Conn. Compositions for reduced NOx and combustion promotion in FCC processes
US5905180A (en) 1996-01-22 1999-05-18 Regents Of The University Of Minnesota Catalytic oxidative dehydrogenation process and catalyst
DE19636066A1 (de) * 1996-09-05 1998-03-12 Basf Ag Verfahren zur Dehydrierung von 1,4-Butandiol zu gamma-Butyrolacton
JP4092441B2 (ja) * 1997-02-24 2008-05-28 日産自動車株式会社 排ガス浄化用触媒
JP3749391B2 (ja) * 1998-03-04 2006-02-22 トヨタ自動車株式会社 排ガス浄化用触媒及びその製造方法
KR100326747B1 (ko) * 1998-03-09 2002-03-13 하나와 요시카즈 산소 과잉 배기 가스의 정화 장치
AR019182A1 (es) * 1998-07-04 2001-12-26 Degussa Huls Aktiengesellscahft Catalizador para reduccion de oxidos de nitrogeno en atmosfera oxidante y reductora, procedimiento para la preparacion de un catalizador , y empleo delcatalizador.
JP2000027625A (ja) * 1998-07-09 2000-01-25 Honda Motor Co Ltd 内燃機関の排気ガス浄化装置
FR2784309B1 (fr) * 1998-10-12 2000-11-17 Inst Francais Du Petrole Procede de diminution des emissions d'oxydes d'azote dans un milieu surstoechiometrique en oxydants
US6719955B1 (en) 1998-11-12 2004-04-13 Clemson University Salt-templated microporous solids
DE19908394A1 (de) 1999-02-26 2000-08-31 Degussa Katalysatormaterial und Verfahren zu seiner Herstellung
US20070066480A1 (en) * 1999-10-25 2007-03-22 Moser William R Method of preparing compounds using cavitation and compounds formed therefrom
MXPA02006924A (es) * 2000-01-14 2004-11-12 Worcester Polytech Inst Metodo de preparacion de compuestos utilizando la cavitacion y compuestos preparados a partir del mismo.
EP1250952A1 (de) * 2001-04-18 2002-10-23 OMG AG & Co. KG Katalysator sowie Filter und Verfahren zur Beseitigung von Russpartikeln aus dem Abgas eines Dieselmotors
US7067453B1 (en) * 2001-07-13 2006-06-27 Innovatek, Inc. Hydrocarbon fuel reforming catalyst and use thereof
EP1354626B1 (en) * 2002-04-04 2005-07-13 Nippon Shokubai Co., Ltd. Alumina-silica supported silver catalyst and use thereof in the production of epoxide
JP5031168B2 (ja) * 2002-08-22 2012-09-19 株式会社デンソー 触媒体
JP3843090B2 (ja) * 2003-09-12 2006-11-08 本田技研工業株式会社 排ガス浄化触媒およびその製造方法、ならびに車用排ガス浄化触媒装置
US20050153836A1 (en) * 2004-01-13 2005-07-14 Yuichi Matsuo Purification catalyst for exhaust gas, production method therefor, and purification catalyst device for exhaust gas
JP4429756B2 (ja) * 2004-02-10 2010-03-10 株式会社キャタラー フィルタ触媒
JP4778724B2 (ja) * 2005-05-02 2011-09-21 株式会社キャタラー 硫化水素発生抑制触媒
KR100741788B1 (ko) * 2005-11-10 2007-07-24 엘지전자 주식회사 연료 전지의 수성 전이 반응용 촉매 및 그 제조 방법
US8173574B2 (en) * 2006-09-20 2012-05-08 Basf Corporation Catalysts to reduce NOx in an exhaust gas stream and methods of preparation
US7943548B2 (en) * 2006-09-20 2011-05-17 Basf Corporation Catalysts to reduce NOx in an exhaust gas stream and methods of preparation
US8071504B2 (en) * 2008-12-19 2011-12-06 Caterpillar Inc. Exhaust system having a gold-platinum group metal catalyst
FR2970881B1 (fr) * 2011-01-31 2015-03-20 IFP Energies Nouvelles Catalyseur thioresistant, procede de fabrication et utilisation en hydrogenation selective
JP5576420B2 (ja) * 2012-03-21 2014-08-20 トヨタ自動車株式会社 排ガス浄化触媒

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2440433A1 (de) * 1973-08-27 1975-03-13 Hitachi Maxell Katalysatoren fuer die reduktion von stickstoffoxyden
DE4008371A1 (de) * 1989-03-15 1990-09-20 Riken Kk Abgasreiniger und verfahren zum reinigen von abgasen
EP0577438A2 (en) * 1992-07-03 1994-01-05 Kabushiki Kaisha Riken Exhaust gas cleaner and method of cleaning exhaust gas
EP0602602A1 (en) * 1992-12-14 1994-06-22 Sakai Chemical Industry Co., Ltd., Catalyst for catalytic reduction of nitrogen oxides
EP0605251A1 (en) * 1992-12-28 1994-07-06 Kabushiki Kaisha Riken Exhaust gas cleaner

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US4624940A (en) 1985-04-12 1986-11-25 Engelhard Corporation High temperature catalyst compositions for internal combustion engine
SE462143C (sv) * 1988-03-07 1996-02-19 Heraeus Gmbh W C Katalysator för bilavgasrening, förfarande för framställning därav samt användning därav
EP0614692A1 (en) 1990-05-03 1994-09-14 Sakai Chemical Industry Co., Ltd., Catalysts and methods for denitrization
CA2064977C (en) 1991-04-05 1998-09-22 Eiichi Shiraishi Catalyst for purifying exhaust gas
EP0525677B1 (en) 1991-07-29 1995-12-13 Daihatsu Motor Company, Ltd. Exhaust gas purifying catalyst and method of preparing the same
JP3330623B2 (ja) 1991-12-20 2002-09-30 マツダ株式会社 排気ガス浄化用触媒
JP2755513B2 (ja) 1992-02-28 1998-05-20 株式会社日本触媒 排気ガス浄化用触媒
JP3311012B2 (ja) 1992-03-23 2002-08-05 株式会社豊田中央研究所 排気ガス浄化用触媒および排気ガス浄化方法
JP3300027B2 (ja) 1992-05-20 2002-07-08 マツダ株式会社 排気ガス浄化用触媒

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2440433A1 (de) * 1973-08-27 1975-03-13 Hitachi Maxell Katalysatoren fuer die reduktion von stickstoffoxyden
DE4008371A1 (de) * 1989-03-15 1990-09-20 Riken Kk Abgasreiniger und verfahren zum reinigen von abgasen
EP0577438A2 (en) * 1992-07-03 1994-01-05 Kabushiki Kaisha Riken Exhaust gas cleaner and method of cleaning exhaust gas
EP0602602A1 (en) * 1992-12-14 1994-06-22 Sakai Chemical Industry Co., Ltd., Catalyst for catalytic reduction of nitrogen oxides
EP0605251A1 (en) * 1992-12-28 1994-07-06 Kabushiki Kaisha Riken Exhaust gas cleaner

Also Published As

Publication number Publication date
ES2196127T3 (es) 2003-12-16
DE69627400T2 (de) 2003-12-18
DE69627400D1 (de) 2003-05-22
JPH08229396A (ja) 1996-09-10
EP0721796B1 (fr) 2003-04-16
EP0721796A1 (fr) 1996-07-17
US5801114A (en) 1998-09-01
FR2729090B1 (en, 2012) 1997-02-14

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Effective date: 20120928