FR2460910A1 - Procede de production de methacroleine par oxydation catalytique d'isobutylene et/ou d'alcool t-butylique, et nouveau produit ainsi obtenu - Google Patents

Procede de production de methacroleine par oxydation catalytique d'isobutylene et/ou d'alcool t-butylique, et nouveau produit ainsi obtenu Download PDF

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Publication number
FR2460910A1
FR2460910A1 FR8014372A FR8014372A FR2460910A1 FR 2460910 A1 FR2460910 A1 FR 2460910A1 FR 8014372 A FR8014372 A FR 8014372A FR 8014372 A FR8014372 A FR 8014372A FR 2460910 A1 FR2460910 A1 FR 2460910A1
Authority
FR
France
Prior art keywords
isobutylene
butyl alcohol
per mole
mixture
gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR8014372A
Other languages
English (en)
French (fr)
Other versions
FR2460910B1 (enExample
Inventor
Shuzo Nakamura
Hiroshi Ichihashi
Yoshihiko Nagaoka
Koichi Nagai
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Publication of FR2460910A1 publication Critical patent/FR2460910A1/fr
Application granted granted Critical
Publication of FR2460910B1 publication Critical patent/FR2460910B1/fr
Granted legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B01J27/192—Molybdenum with bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
FR8014372A 1979-07-09 1980-06-27 Procede de production de methacroleine par oxydation catalytique d'isobutylene et/ou d'alcool t-butylique, et nouveau produit ainsi obtenu Granted FR2460910A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8728179A JPS5612331A (en) 1979-07-09 1979-07-09 Preparation of methacrolein

Publications (2)

Publication Number Publication Date
FR2460910A1 true FR2460910A1 (fr) 1981-01-30
FR2460910B1 FR2460910B1 (enExample) 1984-04-06

Family

ID=13910394

Family Applications (1)

Application Number Title Priority Date Filing Date
FR8014372A Granted FR2460910A1 (fr) 1979-07-09 1980-06-27 Procede de production de methacroleine par oxydation catalytique d'isobutylene et/ou d'alcool t-butylique, et nouveau produit ainsi obtenu

Country Status (8)

Country Link
US (1) US4306088A (enExample)
JP (1) JPS5612331A (enExample)
CA (1) CA1126294A (enExample)
DE (1) DE3024302A1 (enExample)
FR (1) FR2460910A1 (enExample)
GB (1) GB2054569A (enExample)
IT (1) IT1130485B (enExample)
NL (1) NL8003718A (enExample)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5931727A (ja) * 1982-08-17 1984-02-20 Sumitomo Chem Co Ltd メタクロレインの製造方法
JPH0699335B2 (ja) * 1984-02-01 1994-12-07 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸の製造法
JPH0662463B2 (ja) * 1984-02-03 1994-08-17 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸の製造法
JPH0625084B2 (ja) * 1984-07-23 1994-04-06 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸の製造法
JPH0625085B2 (ja) * 1984-07-24 1994-04-06 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸の製造法
US5081314A (en) * 1990-12-07 1992-01-14 Kissel Charles L Process for producing acrolein
JPH04361842A (ja) * 1991-06-07 1992-12-15 Nippon Light Metal Co Ltd パネル用芯素材、パネル及びパネル製造方法
DE60133473T2 (de) 2001-12-14 2009-05-20 Evonik Stockhausen Gmbh Verfahren zur Herstellung von Acrylsäure
US7649111B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
US7851397B2 (en) 2005-07-25 2010-12-14 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649112B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US7732367B2 (en) 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US8921257B2 (en) 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
US8722940B2 (en) 2012-03-01 2014-05-13 Saudi Basic Industries Corporation High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2357512A1 (fr) * 1976-07-07 1978-02-03 Du Pont Preparation d'aldehydes non satures en a, b a partir d'olefines avec un rendement eleve et peu de sous-produits

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3522299A (en) * 1965-11-17 1970-07-28 Nippon Kayaku Kk Process for the oxidation of olefins to aldehydes and acids and catalyst therefor
JPS529121B2 (enExample) * 1972-04-24 1977-03-14
US4111984A (en) * 1973-06-11 1978-09-05 Mitsubishi Rayon Co., Ltd. Process for producing unsaturated aldehydes, and unsaturated fatty acids
JPS5112605A (enExample) * 1974-07-22 1976-01-31 Canon Kk
JPS5163112A (en) * 1974-11-27 1976-06-01 Nippon Kayaku Kk Metakuroreinno seizoho
GB1490683A (en) * 1975-03-12 1977-11-02 Mitsubishi Rayon Co Process and a catalyst for producing unsaturated aldehydes unsaturated carboxylic acids or conjugated diene
US4230639A (en) * 1979-01-19 1980-10-28 Halcon International, Inc. Process for the preparation of methacrolein

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2357512A1 (fr) * 1976-07-07 1978-02-03 Du Pont Preparation d'aldehydes non satures en a, b a partir d'olefines avec un rendement eleve et peu de sous-produits

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
EXBK/71 *

Also Published As

Publication number Publication date
JPS5612331A (en) 1981-02-06
US4306088A (en) 1981-12-15
NL8003718A (nl) 1981-01-13
CA1126294A (en) 1982-06-22
IT1130485B (it) 1986-06-11
DE3024302A1 (de) 1981-01-29
GB2054569A (en) 1981-02-18
FR2460910B1 (enExample) 1984-04-06
IT8068023A0 (it) 1980-06-27

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