FR2445817A1 - Procede de fabrication de zeolithes a, x ou y et zeolithes ainsi obtenues - Google Patents

Procede de fabrication de zeolithes a, x ou y et zeolithes ainsi obtenues

Info

Publication number
FR2445817A1
FR2445817A1 FR7931155A FR7931155A FR2445817A1 FR 2445817 A1 FR2445817 A1 FR 2445817A1 FR 7931155 A FR7931155 A FR 7931155A FR 7931155 A FR7931155 A FR 7931155A FR 2445817 A1 FR2445817 A1 FR 2445817A1
Authority
FR
France
Prior art keywords
sodium
reaction
zeoliths
silica
aqueous solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7931155A
Other languages
English (en)
Other versions
FR2445817B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JM Huber Corp
Original Assignee
JM Huber Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JM Huber Corp filed Critical JM Huber Corp
Publication of FR2445817A1 publication Critical patent/FR2445817A1/fr
Application granted granted Critical
Publication of FR2445817B1 publication Critical patent/FR2445817B1/fr
Granted legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/14—Type A
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K1/00—Housing animals; Equipment therefor
    • A01K1/015—Floor coverings, e.g. bedding-down sheets ; Stable floors
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
    • C01B33/28—Base exchange silicates, e.g. zeolites
    • C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
    • C01B33/2815—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of type A (UNION CARBIDE trade name; corresponds to GRACE's types Z-12 or Z-12L)
    • C01B33/2823—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of type A (UNION CARBIDE trade name; corresponds to GRACE's types Z-12 or Z-12L) from aqueous solutions of an alkali metal aluminate and an alkali metal silicate excluding any other source of alumina or silica
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/32—Alkali metal silicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/128—Aluminium silicates, e.g. zeolites
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/21—Faujasite, e.g. X, Y, CZS-3, ECR-4, Z-14HS, VHP-R
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/24—LTA, e.g. A, alpha, ZK-4, ZK-21, ZK-22

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Dispersion Chemistry (AREA)
  • Environmental Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Materials Engineering (AREA)
  • Animal Husbandry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Polymers & Plastics (AREA)
  • Zoology (AREA)
  • Birds (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Epidemiology (AREA)
  • Medicinal Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Detergent Compositions (AREA)
  • Paper (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

Le procédé de fabrication des zéolithes A, X, A et X, de silicate alumino sodium par réaction d'aluminate de sodium et de silicate de sodium est caractérisé par les étapes suivantes : formation d'une solution aqueuse d'aluminate de sodium; formation d'une solution aqueuse de silicate de sodium; réaction des solutions précédentes à une température de 40 à 120 degrés C; mélange réactif ayant les rapports de masse suivants : 1) eau/oxyde de sodium 10 : 1 à 35 : 1, 2) oxyde de sodium/silice 1 : 1 à 4 : 1, 3) silice/alumine 1 : 1 à 10 : 1, la réaction étant poursuivie avec contrôle de ces rapports et de sa durée afin d'obtenir une zéolite ayant un diamètre moyen de particule inférieur à 2 microns.
FR7931155A 1978-12-20 1979-12-19 Procede de fabrication de zeolithes a, x ou y et zeolithes ainsi obtenues Granted FR2445817A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/971,584 US4235856A (en) 1978-12-20 1978-12-20 Method of producing a zeolite of controlled particle size

Publications (2)

Publication Number Publication Date
FR2445817A1 true FR2445817A1 (fr) 1980-08-01
FR2445817B1 FR2445817B1 (fr) 1983-08-05

Family

ID=25518574

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7931155A Granted FR2445817A1 (fr) 1978-12-20 1979-12-19 Procede de fabrication de zeolithes a, x ou y et zeolithes ainsi obtenues

Country Status (14)

Country Link
US (1) US4235856A (fr)
JP (2) JPS5590417A (fr)
KR (1) KR830002304B1 (fr)
AR (1) AR222682A1 (fr)
BE (1) BE880775A (fr)
BR (1) BR7908286A (fr)
CH (1) CH645322A5 (fr)
ES (1) ES487117A0 (fr)
FR (1) FR2445817A1 (fr)
IT (1) IT1207904B (fr)
NL (1) NL7909102A (fr)
SE (1) SE439297B (fr)
YU (1) YU313579A (fr)
ZA (1) ZA796642B (fr)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4576986A (en) * 1978-01-31 1986-03-18 J. M. Huber Corporation Rubber compositions containing small particle size zeolites and mixtures
US4612342A (en) * 1978-12-20 1986-09-16 J. M. Huber Corporation Rubber compositions containing small particle size zeolites
US4443422A (en) * 1978-12-20 1984-04-17 J. M. Huber Corporation Synthesis of zeolites of small and uniform size having a high magnesium exchange capacity
US4330518A (en) * 1978-12-20 1982-05-18 J. M. Huber Corporation Removal of contaminants from zeolite mother liquors
US4416805A (en) * 1978-12-20 1983-11-22 J. M. Huber Corporation Synthesis of zeolites of small and uniform size having a high magnesium exchange capacity
US4888378A (en) * 1978-12-20 1989-12-19 J. M. Huber Corporation Plastic compositions containing small particle size zeolites and mixtures
US4539191A (en) * 1980-11-04 1985-09-03 J. M. Huber Corporation Preparation of sodium silicate solutions
US4348369A (en) * 1981-07-06 1982-09-07 Union Carbide Corporation Zeolite LZ-200
US4406823A (en) * 1981-10-05 1983-09-27 Ethyl Corporation Method of making zeolites
US4406822A (en) * 1981-10-05 1983-09-27 Ethyl Corporation Method of making zeolites
JPS58180696A (ja) * 1982-04-19 1983-10-22 王子製紙株式会社 紙の製造方法
JPS59133235A (ja) * 1983-01-21 1984-07-31 Kanebo Ltd 殺菌性ポリマー組成物及びその製造法
JPS61236610A (ja) * 1985-04-15 1986-10-21 Zenji Hagiwara 均質なｘ型ゼオライトを製造する方法
US5223235A (en) * 1986-06-17 1993-06-29 J. M. Huber Corporation Synthetic alkali metal alumino-silicates compounds and their methods of preparation
DE3739655A1 (de) * 1987-11-23 1989-06-01 Sued Chemie Ag Bleichmittelzusatz
JPS63260810A (ja) * 1988-03-18 1988-10-27 Kanebo Ltd 殺菌性ゼオライト組成物及びその製造法
US5393507A (en) * 1990-03-01 1995-02-28 Unilever Patent Holdings B.V. Silicate products
IT1284078B1 (it) * 1996-06-27 1998-05-08 Condea Augusta Spa Materiale cristallino microporoso, procedimento per la preparazione e uso in composizioni detergenti
KR100488611B1 (ko) * 2000-03-17 2005-05-11 피큐 홀딩, 인코포레이티드 양이온 교환 성질이 향상된 제올라이트 및 제올라이트혼합물의 제조 방법, 이에 의해 제조된 생성물 및이것으로 제형화된 세척 조성물
US6416569B1 (en) 2000-08-28 2002-07-09 The Boc Group, Inc. Temperature swing adsorption process
ES2392981T3 (es) 2004-07-08 2012-12-17 Hyosung Corporation Procedimiento para refinar gas de trifluoruro de nitrógeno usando zeolita intercambiada iónicamente con un metal alcalinotérreo
JP2008505831A (ja) * 2004-07-08 2008-02-28 ヒョスン・コーポレーション アルカリ土類金属でイオン交換および含浸されたゼオライトを用いた三フッ化窒素ガスの精製方法
KR100919128B1 (ko) * 2007-12-27 2009-09-25 한국건설기술연구원 고온소성 제올라이트 합성물질 제조방법 및 상기제조방법에 의해 제조된 제올라이트 합성물질
JP2009186112A (ja) * 2008-02-07 2009-08-20 Daikin Ind Ltd 給排気用グリル
WO2016044615A1 (fr) 2014-09-17 2016-03-24 University Of Houston System Procede en une etape pour la synthese de zeolites a forte teneur en silice dans des milieux exempts de matieres organiques
CN113426405A (zh) * 2021-06-21 2021-09-24 碳峰环保科技南通有限公司 一种分子筛玻璃纤维voc吸附材料

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1536947A (fr) * 1967-03-01 1968-09-02 Mines Domaniales De Potasse Zéolites synthétiques et leur procédé de fabrication
FR2235083A1 (fr) * 1973-06-29 1975-01-24 Degussa
FR2241493A1 (en) * 1973-07-12 1975-03-21 Inst Francais Du Petrole Sodium silicate for zeolite prepn - by reacting silicon dioxide-aluminium oxide gel with sodium carbonate
FR2318823A1 (fr) * 1975-07-25 1977-02-18 Huber Corp J M Matiere minerale cristalline d'echange de bases et son procede de production
DE2744784B1 (de) * 1977-10-05 1978-08-17 Basf Ag Verfahren zur Herstellung von Zeolith A und seine Verwendung
FR2379479A1 (fr) * 1977-02-08 1978-09-01 Kali Chemie Ag Procede de fabrication de silicates de sodium et d'aluminium a predominance cristalline ainsi que les produits ainsi obtenus

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2882243A (en) * 1953-12-24 1959-04-14 Union Carbide Corp Molecular sieve adsorbents
US2882244A (en) * 1953-12-24 1959-04-14 Union Carbide Corp Molecular sieve adsorbents
US3058805A (en) * 1958-10-03 1962-10-16 Bayer Ag Process for the production of sodium zeolite a
US2982612A (en) * 1959-01-26 1961-05-02 Union Carbide Corp Process for producing sodium zeolite a

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1536947A (fr) * 1967-03-01 1968-09-02 Mines Domaniales De Potasse Zéolites synthétiques et leur procédé de fabrication
FR2235083A1 (fr) * 1973-06-29 1975-01-24 Degussa
FR2241493A1 (en) * 1973-07-12 1975-03-21 Inst Francais Du Petrole Sodium silicate for zeolite prepn - by reacting silicon dioxide-aluminium oxide gel with sodium carbonate
FR2318823A1 (fr) * 1975-07-25 1977-02-18 Huber Corp J M Matiere minerale cristalline d'echange de bases et son procede de production
US4041135A (en) * 1975-07-25 1977-08-09 J. M. Huber Corporation Production of high capacity inorganic crystalline base exchange materials
FR2379479A1 (fr) * 1977-02-08 1978-09-01 Kali Chemie Ag Procede de fabrication de silicates de sodium et d'aluminium a predominance cristalline ainsi que les produits ainsi obtenus
DE2744784B1 (de) * 1977-10-05 1978-08-17 Basf Ag Verfahren zur Herstellung von Zeolith A und seine Verwendung

Also Published As

Publication number Publication date
JPS5590417A (en) 1980-07-09
BE880775A (fr) 1980-06-20
SE439297B (sv) 1985-06-10
ZA796642B (en) 1981-03-25
CH645322A5 (de) 1984-09-28
KR830001132A (ko) 1983-04-29
IT1207904B (it) 1989-06-01
ES8100223A1 (es) 1980-11-01
KR830002304B1 (ko) 1983-10-22
JPS60127218A (ja) 1985-07-06
ES487117A0 (es) 1980-11-01
SE7910419L (sv) 1980-06-21
AR222682A1 (es) 1981-06-15
YU313579A (en) 1983-01-21
US4235856A (en) 1980-11-25
NL7909102A (nl) 1980-06-24
BR7908286A (pt) 1980-10-07
FR2445817B1 (fr) 1983-08-05
IT7912870A0 (it) 1979-12-20

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