FR2442850A1 - Procede pour preparer du dibenzydenesorbitol et composition en contenant - Google Patents
Procede pour preparer du dibenzydenesorbitol et composition en contenantInfo
- Publication number
- FR2442850A1 FR2442850A1 FR7928057A FR7928057A FR2442850A1 FR 2442850 A1 FR2442850 A1 FR 2442850A1 FR 7928057 A FR7928057 A FR 7928057A FR 7928057 A FR7928057 A FR 7928057A FR 2442850 A1 FR2442850 A1 FR 2442850A1
- Authority
- FR
- France
- Prior art keywords
- reaction
- preparing
- dibenzylidenesorbitol
- sorbitol
- stage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 title abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 6
- FMZUHGYZWYNSOA-VVBFYGJXSA-N (1r)-1-[(4r,4ar,8as)-2,6-diphenyl-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C([C@@H]1OC(O[C@@H]([C@@H]1O1)[C@H](O)CO)C=2C=CC=CC=2)OC1C1=CC=CC=C1 FMZUHGYZWYNSOA-VVBFYGJXSA-N 0.000 abstract 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 abstract 3
- 229940087101 dibenzylidene sorbitol Drugs 0.000 abstract 3
- 239000000600 sorbitol Substances 0.000 abstract 3
- 239000003377 acid catalyst Substances 0.000 abstract 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 abstract 2
- 239000012431 aqueous reaction media Substances 0.000 abstract 1
- 239000007900 aqueous suspension Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 abstract 1
- 239000002002 slurry Substances 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
- C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
- C07D493/04—Ortho-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/156—Heterocyclic compounds having oxygen in the ring having two oxygen atoms in the ring
- C08K5/1575—Six-membered rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Abstract
Procédé pour préparer du dibenzylidènesorbitol par déshydrocondensation d'une mole de sorbitol avec deux moles de benzaldéhyde en présence d'un catalyseur acide. On effectue la réaction en deux stades, le premier stade de réaction consistant à faire réagir les composés de départ en chauffant à une température de 50 à 70 degrés C, on passe du premier stade de réaction au second stade de réaction par addition d'eau et d'une quantité additionnelle d'un catalyseur acide lorsque la conversion du sorbitol en dibenzylidènesorbitol atteint 10 à 40 %, et le second stade de réaction consiste à faire réagir le mélange en suspension à la température ordinaire dans 2,5 parties en poids ou plus par partie en poids de sorbitol d'un milieu réactionnel aqueux et on recueille le dibenzylidènesorbitol formé sous forme d'une suspension aqueuse
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14658778A JPS5573683A (en) | 1978-11-29 | 1978-11-29 | Preparation of dibenzylidenesorbitol |
JP6603679A JPS55160041A (en) | 1979-05-30 | 1979-05-30 | Polyolefin resin composition |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2442850A1 true FR2442850A1 (fr) | 1980-06-27 |
FR2442850B1 FR2442850B1 (fr) | 1983-03-11 |
Family
ID=26407209
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7928057A Granted FR2442850A1 (fr) | 1978-11-29 | 1979-11-14 | Procede pour preparer du dibenzydenesorbitol et composition en contenant |
Country Status (5)
Country | Link |
---|---|
US (1) | US4267110A (fr) |
CH (1) | CH642372A5 (fr) |
DE (1) | DE2937130C2 (fr) |
FR (1) | FR2442850A1 (fr) |
GB (1) | GB2035299B (fr) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4562265A (en) * | 1979-10-11 | 1985-12-31 | Milliken Research Corporation | Method for producing a di-acetal of sorbitol and an aromatic aldehyde |
US4429140A (en) | 1981-12-29 | 1984-01-31 | New Japan Chemical Co., Ltd. | Process for preparing dibenzylidene sorbitols and dibenzylidene xylitols |
JPS59129239A (ja) * | 1983-01-14 | 1984-07-25 | New Japan Chem Co Ltd | 結晶性ポリオレフイン系樹脂組成物 |
US4434264A (en) * | 1983-03-22 | 1984-02-28 | El Paso Polyolefins Company | High clarity propylene polymer compositions of improved impact strength |
JPS59174382A (ja) * | 1983-03-24 | 1984-10-02 | Canon Inc | 被記録材 |
FR2613713B1 (fr) * | 1987-04-07 | 1989-08-04 | Roquette Freres | Procede de preparation de diacetals d'alditols, notamment du dibenzylidene-sorbitol, en milieu aqueux |
US4845137A (en) * | 1987-11-05 | 1989-07-04 | Becton, Dickinson And Company | Polyolefin compositions of high clarity and resistance to oxidation |
US5216051A (en) * | 1991-10-28 | 1993-06-01 | Allied-Signal Inc. | Polyolefins containing polyol nucleating agents and articles formed therefrom |
US5470898A (en) * | 1993-06-30 | 1995-11-28 | Montell North America Inc. | Sorbitol derivatives as nucleators and clarifiers for polyolefins, and polyolefin compositions obtained therewith |
US6121332A (en) * | 1999-05-28 | 2000-09-19 | Milliken & Company | Monobenzylidene sorbitol gelling agent and method of use thereof |
US6500964B2 (en) * | 2001-03-23 | 2002-12-31 | Milliken & Company | Method of producing high yield alditol acetals with mineral acids and surfactants |
CN101423520B (zh) * | 2008-12-08 | 2010-12-22 | 中国科学院新疆理化技术研究所 | 一种合成二亚苄基山梨醇和二亚苄基木糖醇的方法 |
CN103402960B (zh) | 2011-01-10 | 2015-06-10 | 瑞来斯实业有限公司 | 制备醛醇缩醛的工艺 |
KR20140027093A (ko) | 2011-01-10 | 2014-03-06 | 릴라이언스 인더스트리즈 리미티드 | 알디톨 아세탈의 제조방법 |
SG191886A1 (en) | 2011-01-10 | 2013-08-30 | Reliance Ind Ltd | Process for preparation of acetals |
CN103402959B (zh) | 2011-01-10 | 2016-05-18 | 瑞来斯实业有限公司 | 在含水介质中制成二缩醛化合物的方法 |
CN106317451B (zh) * | 2016-09-05 | 2019-02-12 | 呈和科技股份有限公司 | 一种包含微量芳醛、山梨醇二缩醛和山梨醇三缩醛的成核剂组合物 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5289158A (en) * | 1976-01-21 | 1977-07-26 | New Japan Chem Co Ltd | Thixotrpic polyvinyl choride paste sol compositions |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4843748B1 (fr) * | 1969-10-06 | 1973-12-20 | New Japan Chem Co Ltd | |
JPS4843748A (fr) * | 1971-10-06 | 1973-06-23 | ||
DE2510636A1 (de) * | 1975-03-12 | 1976-09-23 | Basf Ag | Cyclische acetale |
-
1979
- 1979-08-29 US US06/070,833 patent/US4267110A/en not_active Expired - Lifetime
- 1979-08-31 GB GB7930230A patent/GB2035299B/en not_active Expired
- 1979-09-10 CH CH817779A patent/CH642372A5/de not_active IP Right Cessation
- 1979-09-13 DE DE2937130A patent/DE2937130C2/de not_active Expired
- 1979-11-14 FR FR7928057A patent/FR2442850A1/fr active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5289158A (en) * | 1976-01-21 | 1977-07-26 | New Japan Chem Co Ltd | Thixotrpic polyvinyl choride paste sol compositions |
Non-Patent Citations (2)
Title |
---|
CA1978 * |
EXBK/42 * |
Also Published As
Publication number | Publication date |
---|---|
DE2937130C2 (de) | 1982-04-22 |
CH642372A5 (de) | 1984-04-13 |
GB2035299A (en) | 1980-06-18 |
FR2442850B1 (fr) | 1983-03-11 |
US4267110A (en) | 1981-05-12 |
GB2035299B (en) | 1983-04-13 |
DE2937130A1 (de) | 1980-06-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
FR2442850A1 (fr) | Procede pour preparer du dibenzydenesorbitol et composition en contenant | |
FR2432007A1 (fr) | Procede de preparation de methacroleine | |
KR910009628A (ko) | 5-플루오로벤조산류 및 그의 중간물질의 제조방법 | |
FR2385668A1 (fr) | ||
JPH0579055B2 (fr) | ||
FR2379501A1 (fr) | Procede de preparation de l'aldehyde protocatechique et ses derives | |
US2508256A (en) | Production of polar-substituted organic peroxides and products thereof | |
Gregory et al. | Reactions of 3-Thiocyano-2-butanone. I. The Preparation of 2-Substituted-4, 5-dimethylthiazoles | |
SU517252A3 (ru) | Способ получени аминопроизводных бензофенона | |
FR2386531A1 (fr) | Procede de preparation de methylolmelamines etherifiees par des groupes methyles | |
FR2408590A1 (fr) | Procede de preparation de peroxydes | |
Gil | Les organosiliciques comme agents de synthese d'acetals β-halogenes | |
US4347386A (en) | Process for preparing cyclopentenolones | |
Gill et al. | Addition of organomagnesium reagents to cyanohydrin-O-silyl ethers: An efficient and flexible synthesis of unsymmetrically substituted acyloins | |
FR2444057A1 (fr) | Procede de preparation de polymethylene polyphenyl polycarbamates | |
GB2099822A (en) | Process for preparing esters of cyanoacetic acids | |
FR2386478A1 (fr) | Procede de preparation de dithionite de sodium | |
US2169363A (en) | Olefin-sulphur dioxide reaction products | |
FR2439177A1 (fr) | Procede de synthese d'acides et esters cetoniques | |
FR2442825A1 (fr) | Procede de fabrication d'acide methacrylique | |
US3595878A (en) | Methoxyphenyl- and phenyl-dialkyl-alpha-pyrone nitriles | |
US4375562A (en) | Process for the preparation of bis-(amino-phenyl)-disulphides | |
KR860003191A (ko) | 에틸렌 옥사이드 부가물의 제조방법 | |
US2484268A (en) | Allyl thiophenes | |
Nagakawa et al. | A novel method for the preparation of ethers from carbonyl compounds with benzenetellurol catalyzed by ZnI2. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |