FR2335526A1 - Perfectionnements aux appareils et procedes pour la polymerisation en phase vapeur d'au moins un monomere polymerisable - Google Patents

Perfectionnements aux appareils et procedes pour la polymerisation en phase vapeur d'au moins un monomere polymerisable

Info

Publication number
FR2335526A1
FR2335526A1 FR7538557A FR7538557A FR2335526A1 FR 2335526 A1 FR2335526 A1 FR 2335526A1 FR 7538557 A FR7538557 A FR 7538557A FR 7538557 A FR7538557 A FR 7538557A FR 2335526 A1 FR2335526 A1 FR 2335526A1
Authority
FR
France
Prior art keywords
methods
vapor phase
phase polymerization
polymerisable monomer
polymerisable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7538557A
Other languages
English (en)
Other versions
FR2335526B1 (fr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Co
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/533,019 external-priority patent/US3957448A/en
Priority claimed from US05/533,021 external-priority patent/US3971768A/en
Application filed by Standard Oil Co filed Critical Standard Oil Co
Publication of FR2335526A1 publication Critical patent/FR2335526A1/fr
Application granted granted Critical
Publication of FR2335526B1 publication Critical patent/FR2335526B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1868—Stationary reactors having moving elements inside resulting in a loop-type movement
    • B01J19/1881—Stationary reactors having moving elements inside resulting in a loop-type movement externally, i.e. the mixture leaving the vessel and subsequently re-entering it
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/08—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
    • B01J8/10—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by stirrers or by rotary drums or rotary receptacles or endless belts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1836—Heating and cooling the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/36—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed through which there is an essentially horizontal flow of particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/38—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it
    • B01J8/382—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it with a rotatable device only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00026—Controlling or regulating the heat exchange system
    • B01J2208/00035—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2208/0007—Pressure measurement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00026—Controlling or regulating the heat exchange system
    • B01J2208/00035—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2208/00088—Flow rate measurement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212—Plates; Jackets; Cylinders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00256—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles in a heat exchanger for the heat exchange medium separate from the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00327—Controlling the temperature by direct heat exchange
    • B01J2208/00336—Controlling the temperature by direct heat exchange adding a temperature modifying medium to the reactants
    • B01J2208/00353—Non-cryogenic fluids
    • B01J2208/00362—Liquid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00389—Controlling the temperature using electric heating or cooling elements
    • B01J2208/00407—Controlling the temperature using electric heating or cooling elements outside the reactor bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/0053—Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00823—Mixing elements
    • B01J2208/00831—Stationary elements
    • B01J2208/0084—Stationary elements inside the bed, e.g. baffles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761—Details of the reactor
    • B01J2219/00763—Baffles
    • B01J2219/00765—Baffles attached to the reactor wall
    • B01J2219/00768—Baffles attached to the reactor wall vertical
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18—Details relating to the spatial orientation of the reactor
    • B01J2219/182—Details relating to the spatial orientation of the reactor horizontal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/19—Details relating to the geometry of the reactor
    • B01J2219/194—Details relating to the geometry of the reactor round
    • B01J2219/1941—Details relating to the geometry of the reactor round circular or disk-shaped
    • B01J2219/1943—Details relating to the geometry of the reactor round circular or disk-shaped cylindrical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
FR7538557A 1974-12-16 1975-12-16 Perfectionnements aux appareils et procedes pour la polymerisation en phase vapeur d'au moins un monomere polymerisable Granted FR2335526A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US53302074A 1974-12-16 1974-12-16
US05/533,019 US3957448A (en) 1974-12-16 1974-12-16 Divided horizontal reactor for the vapor phase polymerization of monomers at different hydrogen levels
US05/533,021 US3971768A (en) 1974-12-16 1974-12-16 Vapor phase reactor off-gas recycle system for use in the vapor state polymerization of monomers

Publications (2)

Publication Number Publication Date
FR2335526A1 true FR2335526A1 (fr) 1977-07-15
FR2335526B1 FR2335526B1 (fr) 1979-07-27

Family

ID=27415110

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7538557A Granted FR2335526A1 (fr) 1974-12-16 1975-12-16 Perfectionnements aux appareils et procedes pour la polymerisation en phase vapeur d'au moins un monomere polymerisable

Country Status (13)

Country Link
JP (1) JPS5921321B2 (fr)
AR (1) AR219479A1 (fr)
AT (1) AT351254B (fr)
BR (1) BR7508335A (fr)
DD (1) DD124882A5 (fr)
DE (1) DE2556418C2 (fr)
ES (1) ES443515A1 (fr)
FR (1) FR2335526A1 (fr)
GB (1) GB1525978A (fr)
IN (1) IN145649B (fr)
IT (1) IT1052588B (fr)
NL (1) NL183891C (fr)
NO (1) NO144570C (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0313756A2 (fr) * 1987-10-27 1989-05-03 Gebr. Lödige Maschinenbau Gesellschaft mbH Réacteurs pour le traitement de matériaux en vrac ou semblables
EP1820810A1 (fr) 2001-11-19 2007-08-22 Ineos Europe Limited Procédé de commande de la polymérisation
WO2014048892A1 (fr) 2012-09-28 2014-04-03 Ineos Europe Ag Procédé de production de polymère
WO2014060231A1 (fr) 2012-10-16 2014-04-24 Ineos Europe Ag Procédé pour la production d'un polymère dans un réacteur à lit fluidisé en phase gazeuse

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS532585A (en) * 1976-06-29 1978-01-11 Sumitomo Chem Co Ltd Preparation of polyethylene
US4130699A (en) * 1977-11-25 1978-12-19 Standard Oil Company (Indiana) Vapor phase polymerization with temporarily inactive titanium catalyst
JPS56129204A (en) * 1980-03-14 1981-10-09 Nippon Oil Co Ltd Apparatus for vapor-phase polymerization of olefin
JPS56159205A (en) * 1980-05-14 1981-12-08 Nippon Oil Co Ltd Equipment for olefin gas-phase polymerization
JPS59124911A (ja) * 1982-12-29 1984-07-19 Chisso Corp ポリプロピレンの製造方法
US4535134A (en) * 1983-03-31 1985-08-13 Standard Oil Company (Indiana) Method and apparatus for controlling the discharge of product from vapor phase polymerization of monomers in a horizontal stirred-bed reactor
DE3475202D1 (en) * 1984-03-15 1988-12-22 Hoxan Kk Apparatus for producing polyacetylene film
DE3514367A1 (de) * 1985-04-20 1986-10-23 Basf Ag, 6700 Ludwigshafen Vorrichtung zur feststoffbettpolymerisation von monomeren
JP2857916B2 (ja) * 1990-07-20 1999-02-17 日本石油化学株式会社 気相重合流動床の触媒供給方法
DE10014046A1 (de) 2000-03-23 2001-09-27 Basell Polypropylen Gmbh Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
DE10016625A1 (de) * 2000-04-04 2001-10-11 Basell Polyolefine Gmbh Gasphasenpolymerisationsverfahren mit Direktkühlsystem
JP5308797B2 (ja) 2007-12-11 2013-10-09 住友化学株式会社 オレフィン重合反応装置、ポリオレフィン製造システム、及び、ポリオレフィン製造方法
JP5427396B2 (ja) 2007-12-11 2014-02-26 住友化学株式会社 粉体移送装置、及び、ポリオレフィンの製造方法
JP5308794B2 (ja) 2007-12-11 2013-10-09 住友化学株式会社 噴流層装置を用いたポリオレフィン製造方法
JP5308795B2 (ja) 2007-12-11 2013-10-09 住友化学株式会社 ポリオレフィン製造方法、並びに、噴流層装置を備えたポリオレフィン製造システム
JP5249730B2 (ja) 2007-12-11 2013-07-31 住友化学株式会社 オレフィン重合反応装置及びポリオレフィン製造方法
US7799866B2 (en) 2007-12-28 2010-09-21 Sumitomo Chemical Company, Limited Method for producing propylene-ethylene block copolymer
KR101686253B1 (ko) * 2008-08-21 2016-12-13 더블유.알. 그레이스 앤드 캄파니-콘. 고 용융 유동 내충격성 프로필렌 공중합체 및 방법
BRPI0919039A2 (pt) 2008-09-25 2017-05-30 Basell Polyolefine Gmbh composicao de lldpe resistente a impacto e peliculas feitas da mesma
EP2361281B1 (fr) 2008-09-25 2012-11-21 Basell Polyolefine GmbH Composition de lldpe à résistance au choc et films fabriqués à partir de ladite composition
RU2517711C2 (ru) * 2009-02-20 2014-05-27 ИНЕОС ЮЭсЭй ЭлЭлСи Способ полимеризации олефинов
JP5545800B2 (ja) 2009-06-08 2014-07-09 住友化学株式会社 噴流−流動層型オレフィン重合反応装置、ポリオレフィン製造システム、及び、ポリオレフィン製造方法
JP6902337B2 (ja) 2016-08-03 2021-07-14 住友化学株式会社 ヘテロファジックプロピレン重合材料の製造方法

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0313756A2 (fr) * 1987-10-27 1989-05-03 Gebr. Lödige Maschinenbau Gesellschaft mbH Réacteurs pour le traitement de matériaux en vrac ou semblables
EP0313756A3 (en) * 1987-10-27 1989-07-26 Gebr. Lodige Maschinenbau Gesellschaft Mbh Reactor for treating bulk material or the like
EP1820810A1 (fr) 2001-11-19 2007-08-22 Ineos Europe Limited Procédé de commande de la polymérisation
WO2014048892A1 (fr) 2012-09-28 2014-04-03 Ineos Europe Ag Procédé de production de polymère
WO2014060231A1 (fr) 2012-10-16 2014-04-24 Ineos Europe Ag Procédé pour la production d'un polymère dans un réacteur à lit fluidisé en phase gazeuse

Also Published As

Publication number Publication date
ATA956475A (de) 1978-12-15
GB1525978A (en) 1978-09-27
IT1052588B (it) 1981-07-20
NL183891C (nl) 1989-02-16
NL183891B (nl) 1988-09-16
AR219479A1 (es) 1980-08-29
AT351254B (de) 1979-07-10
JPS5921321B2 (ja) 1984-05-19
DE2556418A1 (de) 1976-06-24
NL7514637A (nl) 1976-06-18
BR7508335A (pt) 1976-08-24
JPS5186584A (fr) 1976-07-29
NO144570C (no) 1981-09-23
ES443515A1 (es) 1977-08-01
DD124882A5 (fr) 1977-03-16
IN145649B (fr) 1985-01-05
FR2335526B1 (fr) 1979-07-27
NO754245L (fr) 1976-06-17
DE2556418C2 (de) 1985-01-03
NO144570B (no) 1981-06-15

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