FI960437A - Heteroatom-substituerade metallosenföreningar för katalyter i olefin polymerisation och förfarande för framställning av dem - Google Patents

Heteroatom-substituerade metallosenföreningar för katalyter i olefin polymerisation och förfarande för framställning av dem Download PDF

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Publication number
FI960437A
FI960437A FI960437A FI960437A FI960437A FI 960437 A FI960437 A FI 960437A FI 960437 A FI960437 A FI 960437A FI 960437 A FI960437 A FI 960437A FI 960437 A FI960437 A FI 960437A
Authority
FI
Finland
Prior art keywords
heteroatom
preparation
olefin polymerization
polymerization catalysts
metallocene compounds
Prior art date
Application number
FI960437A
Other languages
English (en)
Finnish (fi)
Other versions
FI960437A0 (sv
FI104826B (sv
Inventor
Reko Leino
Hendrik Luttighedde
Carl-Erik Wilen
Jan Naesman
Original Assignee
Borealis As
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis As filed Critical Borealis As
Publication of FI960437A0 publication Critical patent/FI960437A0/sv
Priority to FI960437A priority Critical patent/FI104826B/sv
Priority to BR9707236A priority patent/BR9707236A/pt
Priority to CA002246061A priority patent/CA2246061C/en
Priority to CN97193331A priority patent/CN1089342C/zh
Priority to ES97901652T priority patent/ES2212070T3/es
Priority to SK1008-98A priority patent/SK285145B6/sk
Priority to JP52733197A priority patent/JP4051089B2/ja
Priority to ARP970100376A priority patent/AR005612A1/es
Priority to HU9902106A priority patent/HUP9902106A3/hu
Priority to ZA9700766A priority patent/ZA97766B/xx
Priority to KR1019980705881A priority patent/KR19990082158A/ko
Priority to EP97901652A priority patent/EP0880534B1/en
Priority to AT97901652T priority patent/ATE256691T1/de
Priority to CZ0229498A priority patent/CZ297674B6/cs
Priority to AU15485/97A priority patent/AU722731B2/en
Priority to US09/117,439 priority patent/US6277778B1/en
Priority to PCT/FI1997/000049 priority patent/WO1997028170A1/en
Priority to IL12554297A priority patent/IL125542A/xx
Priority to MYPI97000351A priority patent/MY120110A/en
Priority to DE69726841T priority patent/DE69726841T2/de
Priority to TW086106655A priority patent/TW442509B/zh
Publication of FI960437A publication Critical patent/FI960437A/sv
Application granted granted Critical
Publication of FI104826B publication Critical patent/FI104826B/sv
Priority to IL13802900A priority patent/IL138029A0/xx

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
FI960437A 1996-01-30 1996-01-30 Heteroatom-substituerade metallosenföreningar för katalytsystem i olefin polymerisation och förfarande för framställning av dem FI104826B (sv)

Priority Applications (22)

Application Number Priority Date Filing Date Title
FI960437A FI104826B (sv) 1996-01-30 1996-01-30 Heteroatom-substituerade metallosenföreningar för katalytsystem i olefin polymerisation och förfarande för framställning av dem
KR1019980705881A KR19990082158A (ko) 1996-01-30 1997-01-30 올레핀 중합 촉매계용 헤테로원자 치환 메탈로센 화합물 및 그의 제조방법
AT97901652T ATE256691T1 (de) 1996-01-30 1997-01-30 Heteroatomsubstituierte metallocene für olefipolymerisationkatalysatore un verfahren zu deren herstellung
CN97193331A CN1089342C (zh) 1996-01-30 1997-01-30 用于烯烃聚合催化剂体系的杂原子取代的茂金属化合物及其制备方法
ES97901652T ES2212070T3 (es) 1996-01-30 1997-01-30 Compuesto de metaloceno con un heteroatomo sustituido para sistemas de catalizadores de polimerizacion de olefinas y metodos para prepararlos.
SK1008-98A SK285145B6 (sk) 1996-01-30 1997-01-30 Metalocénové zlúčeniny, medziprodukt na ich prípravu, spôsob ich prípravy a ich použitie ako polymerizačných katalyzátorových zložiek na polymerizáciu a kopolymerizáciu olefínov
JP52733197A JP4051089B2 (ja) 1996-01-30 1997-01-30 オレフィン重合触媒系用ヘテロ原子置換メタロセン化合物およびそれらの調製法
ARP970100376A AR005612A1 (es) 1996-01-30 1997-01-30 Un precursor de catalizador, un metodo para prepararlo y su uso
HU9902106A HUP9902106A3 (en) 1996-01-30 1997-01-30 Heteroatom substituted metallocene compounds for olefin polymerization catalyst systems and methods for preparing them
ZA9700766A ZA97766B (en) 1996-01-30 1997-01-30 Heteroatom substituted metallocene compounds for olefin polymerization catalyst systems and methods for preparing thereof.
BR9707236A BR9707236A (pt) 1996-01-30 1997-01-30 Compostos metaloceno de heteroátomo substituído para sistemas de catalisação de polimerizaç o de olefina e métodos para preparação dos mesmos
EP97901652A EP0880534B1 (en) 1996-01-30 1997-01-30 Heteroatom substituted metallocene compounds for olefin polymerization catalyst systems and methods for preparing them
CA002246061A CA2246061C (en) 1996-01-30 1997-01-30 Heteroatom substituted metallocene compounds for olefin polymerization catalyst systems and methods for preparing them
CZ0229498A CZ297674B6 (cs) 1996-01-30 1997-01-30 Katalyzátorový prekurzor pro olefinické polymeracní katalytické systémy a zpusoby jejich prípravy
AU15485/97A AU722731B2 (en) 1996-01-30 1997-01-30 Heteroatom substituted metallocene compounds for olefin polymerization catalyst systems and methods for preparing them
US09/117,439 US6277778B1 (en) 1996-01-30 1997-01-30 Heteroatom substituted metallocene compounds for olefin polymerization catalyst systems and methods for preparing them
PCT/FI1997/000049 WO1997028170A1 (en) 1996-01-30 1997-01-30 Heteroatom substituted metallocene compounds for olefin polymerization catalyst systems and methods for preparing them
IL12554297A IL125542A (en) 1996-01-30 1997-01-30 Heteroatom substituted metallocene compounds for olefin polymerization catalyst systems and methods for preparing them
MYPI97000351A MY120110A (en) 1996-01-30 1997-01-30 Heteroatom substituted metallocene compounds for olefin polymerization catalyst systems and method for preparing thereof
DE69726841T DE69726841T2 (de) 1996-01-30 1997-01-30 Heteroatomsubstituierte metallocene für olefipolymerisationkatalysatore un verfahren zu deren herstellung
TW086106655A TW442509B (en) 1996-01-30 1997-05-19 Heteroatom substituted metalocene compounds for olefin polymerization catalyst systems and methods for preparing thereof
IL13802900A IL138029A0 (en) 1996-01-30 2000-08-23 Indene derivatives and method for their preparation

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI960437A FI104826B (sv) 1996-01-30 1996-01-30 Heteroatom-substituerade metallosenföreningar för katalytsystem i olefin polymerisation och förfarande för framställning av dem
FI960437 1996-01-30

Publications (3)

Publication Number Publication Date
FI960437A0 FI960437A0 (sv) 1996-01-30
FI960437A true FI960437A (sv) 1997-07-31
FI104826B FI104826B (sv) 2000-04-14

Family

ID=8545178

Family Applications (1)

Application Number Title Priority Date Filing Date
FI960437A FI104826B (sv) 1996-01-30 1996-01-30 Heteroatom-substituerade metallosenföreningar för katalytsystem i olefin polymerisation och förfarande för framställning av dem

Country Status (20)

Country Link
US (1) US6277778B1 (sv)
EP (1) EP0880534B1 (sv)
JP (1) JP4051089B2 (sv)
KR (1) KR19990082158A (sv)
CN (1) CN1089342C (sv)
AR (1) AR005612A1 (sv)
AT (1) ATE256691T1 (sv)
AU (1) AU722731B2 (sv)
BR (1) BR9707236A (sv)
CZ (1) CZ297674B6 (sv)
DE (1) DE69726841T2 (sv)
ES (1) ES2212070T3 (sv)
FI (1) FI104826B (sv)
HU (1) HUP9902106A3 (sv)
IL (1) IL125542A (sv)
MY (1) MY120110A (sv)
SK (1) SK285145B6 (sv)
TW (1) TW442509B (sv)
WO (1) WO1997028170A1 (sv)
ZA (1) ZA97766B (sv)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001062847A1 (en) 2000-02-21 2001-08-30 Borealis Technology Oy Process for producing a polyethylene coating on a substrate
US6355819B1 (en) 1997-04-14 2002-03-12 Borealis Technology Oy Substituted metallocene compounds for olefin polymerization catalyst systems, their intermediates and methods for preparing them
EP1803747A1 (en) 2005-12-30 2007-07-04 Borealis Technology Oy Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films
WO2011089000A1 (en) 2010-01-21 2011-07-28 Basell Polyolefine Gmbh Process for the preparation of ethylene copolymer compositions in the presence of an oligomerization catalyst
US8003740B2 (en) 2005-07-26 2011-08-23 Basell Polyolefine Gmbh Method of controlling the relative activity of the different active centers of hybrid catalysts

Families Citing this family (203)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1270253B (it) 1994-06-20 1997-04-29 Spherilene Srl Copolimeri dell'etilene e procedimento per la preparazione di polimeri dell'etilene
FI104826B (sv) 1996-01-30 2000-04-14 Borealis As Heteroatom-substituerade metallosenföreningar för katalytsystem i olefin polymerisation och förfarande för framställning av dem
PT839836E (pt) * 1996-10-31 2001-06-29 Repsol Quimica Sa Sistemas cataliticos para a polimerizacao e copolimerizacao de alfa-olefinas
EP0953581B1 (en) * 1998-04-27 2004-01-07 Repsol Quimica S.A. Catalytic systems for the polymerization and copolymerization of alpha-olefins
FI981148A (sv) 1998-05-25 1999-11-26 Borealis As Nytt aktivatorsystem för metallocenföreningar
KR100367463B1 (ko) * 1999-03-03 2003-01-14 주식회사 엘지화학 메탈로센 화합물 및 이를 이용한 올레핀 중합
WO2003000744A1 (en) 2001-06-22 2003-01-03 Borealis Technology Oy Metallocene catalysts containing an idenyl moiety substituted at the 4-, 5-, 6- or 7-position by a siloxy or germyloxy group
GB0118010D0 (en) * 2001-07-24 2001-09-19 Borealis Tech Oy Catalysts
EP1323747A1 (en) 2001-12-19 2003-07-02 Borealis Technology Oy Production of olefin polymerisation catalysts
EP1323746B1 (en) 2001-12-19 2009-02-11 Borealis Technology Oy Production of supported olefin polymerisation catalysts
AU2003261617A1 (en) 2002-08-29 2004-03-19 Lg Chem, Ltd. Fulvene, metallocene catalysts and preparation method thereof, and preparation of polyolefines copolymer using the same
SE0300195D0 (sv) 2003-01-28 2003-01-28 Borealis Tech Oy Coating composition, method of preparation thereofand substrate coated therewith
ES2377948T3 (es) 2003-06-20 2012-04-03 Borealis Polymers Oy Procedimiento para la preparación de una composición de un catalizador para la polimerización de olefinas
EP1616887A1 (en) * 2004-07-13 2006-01-18 Total Petrochemicals Research Feluy Extrusion coating process of polyethylene
GB0423212D0 (en) 2004-10-19 2004-11-24 Borealis Tech Oy Polymer
GB0423555D0 (en) 2004-10-22 2004-11-24 Borealis Tech Oy Process
EP1739103A1 (en) 2005-06-30 2007-01-03 Borealis Technology Oy Catalyst
DE602005013376D1 (de) 2005-08-09 2009-04-30 Borealis Tech Oy Siloxy substituierte Metallocenkatalysatoren
EP1937769B1 (en) 2005-10-21 2010-08-25 Borealis Technology Oy Composition
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ATE461973T1 (de) 2007-01-22 2010-04-15 Borealis Tech Oy Polypropylenzusammensetzung mit niedriger oberflächenenergie
US20100280206A1 (en) 2007-11-09 2010-11-04 Borealis Technology Oy Polyethylene copolymer
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